公开(公告)号：US09570211B2

公开(公告)日：2017-02-14

申请号：US12199056

申请日：2008-08-27

Applicant: Xiangyang Li ,  James P. Mason

Inventor： Xiangyang Li ,  James P. Mason

IPC: H01B1/12 ,  C08K5/103 ,  C08K5/42

CPC classification number: H01B1/122 ,  C08K5/103 ,  C08K5/42

Abstract: The present invention provides a transparent thermoplastic molding composition made from a transparent blend of a polycarbonate resin with a polyester resin, 0.005 to 2 weight percent, based on the weight of the composition, of a perfluoroalkylsulfonic acid salt of the formula (I): (RA—SO3−)nXn+ (I), wherein R denotes perfluorinated linear or branched carbon chain having 1 to 30 carbon atoms, A denotes a direct bond or an aromatic nucleus, n denotes an integer of 1 or 2, and X denotes a metal element selected from the first or the second column in the Periodic Table of the Elements, and 0 to 5 weight percent, based on the weight of the composition, of a glycerol monostearate. The inventive composition has a total transmittance according to ASTM D-1003 of greater than 84% and an electric resistivity according to ASTM D-257 of less than about 2.5E+06 ohm-m.

Abstract translation: 本发明提供一种由聚碳酸酯树脂与聚酯树脂的透明共混物制成的透明热塑性模塑组合物，基于组合物重量的0.005-2重量％的式（I）的全氟烷基磺酸盐：（ RA-SO3-）nXn +（I），其中R表示具有1至30个碳原子的全氟化直链或支链碳链，A表示直接键或芳香核，n表示1或2的整数，X表示金属 选自元素周期表中的第一列或第二列的元素，基于组合物重量的0至5重量％的单硬脂酸甘油酯。 本发明的组合物根据ASTM D-1003的总透射率大于84％，并且根据ASTM D-257的电阻率小于约2.5E + 06欧姆 - 米。

公开(公告)号：US09193860B2

公开(公告)日：2015-11-24

申请号：US11713484

申请日：2007-03-02

Applicant: Marina Rogunova ,  James P. Mason ,  James Y. J. Chung

Inventor： Marina Rogunova ,  James P. Mason ,  James Y. J. Chung

IPC: C08L51/04 ,  C08L51/06 ,  C08L55/02 ,  C08L69/00 ,  C08L25/08

CPC classification number: C08L55/02 ,  C08L25/08 ,  C08L51/04 ,  C08L69/00 ,  C08L69/005 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/14 ,  C08L2666/24

Abstract: A thermoplastic composition suitable for making articles having low gloss and good impact properties is disclosed. The composition contains (A) 20 to 94.5 percent relative to the weight of the composition (pbw) of an aromatic (co)poly(ester)carbonate, (B) 5 to 40 pbw of a graft (co)polymer that includes an EPDM graft base and a grafted phase that is compatible with the aromatic (co)poly(ester)carbonate, and (C) 0.5 to 20 pbw of a linear copolymer containing at least one unit derived from a glycidyl ester monomer, and (D) 0 to 40 pbw of a vinyl copolymer. The gloss of the composition is lower than that of a corresponding composition that contains none of component (C).

Abstract translation: 公开了一种适于制备具有低光泽和良好冲击性能的制品的热塑性组合物。 组合物含有（A）相对于芳族（共）聚（酯）碳酸酯的组合物（pbw）的重量为20至94.5％，（B）5至40pbw的包含EPDM的接枝（共）聚合物 接枝基和与芳族（共）聚（酯）碳酸酯相容的接枝相，和（C）0.5至20pbw的含至少一个衍生自缩水甘油酯单体的单元的线性共聚物，和（D）0 至40pbw的乙烯基共聚物。 组合物的光泽度低于不含组分（C）的相应组合物的光泽度。

公开(公告)号：US20130090419A1

公开(公告)日：2013-04-11

申请号：US13253213

申请日：2011-10-05

Applicant: Rick L. Archey ,  James P. Mason ,  Pierre Moulinie ,  Richard Peterman ,  Mary Ann Wittig

Inventor： Rick L. Archey ,  James P. Mason ,  Pierre Moulinie ,  Richard Peterman ,  Mary Ann Wittig

IPC: C08L69/00 ,  C08K5/107 ,  C08J3/20 ,  C08K5/103

CPC classification number: C08K5/109 ,  C08L69/00

Abstract: The present invention relates to compositions containing a polycarbonate including a bisphenol compound and an effective amount of a bishaloformate component present in an amount sufficient to reduce the average unbound bisphenol compound level found in water after immersion in deionized water for two weeks at 40° C. of the composition to less than about 20 ppb. Also provided are methods for increasing the water resistance of a polycarbonate composition. The method involves adding an effective amount of a bishaloformate component to the polycarbonate composition such that the polycarbonate composition has an average unbound bisphenol compound level found in water after immersion in deionized water for two weeks at 40° C. of less than about 20 ppb.

Abstract translation: 本发明涉及包含双酚化合物的聚碳酸酯和有效量的双卤代甲酸酯组分的组合物，其量足以降低在40℃下浸入去离子水中2周后在水中发现的平均未结合双酚化合物水平。 的组成小于约20ppb。 还提供了增加聚碳酸酯组合物的耐水性的方法。 该方法包括向聚碳酸酯组合物中加入有效量的双卤代甲酸酯组分，使得聚碳酸酯组合物在40℃下浸入去离子水中两周后，在水中发现的平均未结合双酚化合物水平小于约20ppb。

公开(公告)号：US07799868B2

公开(公告)日：2010-09-21

申请号：US11359057

申请日：2006-02-22

Applicant: Xiangyang Li ,  James P. Mason

Inventor： Xiangyang Li ,  James P. Mason

IPC: C08G63/91

CPC classification number: C08L51/06 ,  C08K5/49 ,  C08L27/18 ,  C08L33/14 ,  C08L51/04 ,  C08L67/02 ,  C08L69/00 ,  C08L2666/14 ,  C08L2666/02 ,  C08L2666/04

Abstract: A thermoplastic molding composition characterized in improved impact performance and flame resistance is disclosed. The composition contains (a) aromatic polycarbonate, (b) thermoplastic polyester and (c) halogenated acrylate containing repeat structural units conforming to wherein R1, R2, R3, R4, and R5 independently one of the others denote hydrogen an alkyl or aryl group, n is 0 to 5, m is 10 to 10000, and R denotes halogen, (d) an impact modifier, (e) a phosphorous-containing compound, and (f) fluorinated polyolefin.

Abstract translation: 公开了一种以改进的冲击性能和阻燃性为特征的热塑性模塑组合物。 组合物包含（a）芳族聚碳酸酯，（b）热塑性聚酯和（c）含有符合其中R1，R2，R3，R4和R5的重复结构单元的卤代丙烯酸酯，其中一个独立地表示氢，烷基或芳基， n为0〜5，m为10〜10000，R为卤素，（d）抗冲改性剂，（e）含磷化合物和（f）氟化聚烯烃。

公开(公告)号：US20100041831A1

公开(公告)日：2010-02-18

申请号：US12192476

申请日：2008-08-15

Applicant: JAMES Y.J. CHUNG ,  James P. Mason

Inventor： JAMES Y.J. CHUNG ,  James P. Mason

IPC: C08G63/08

CPC classification number: C08L67/04 ,  C08L23/0869 ,  C08L69/00 ,  C08L2666/02

Abstract: The present invention relates to a thermoplastic molding composition containing an aromatic polycarbonate, a polylactic acid and an impact modifying amount of a non-functionalized ethylene/(meth)acrylate copolymer. The inventive composition is characterized by its higher impact resistance, flexural and tensile properties than those of corresponding compositions where the copolymer is functionalized.

Abstract translation: 本发明涉及含有芳族聚碳酸酯，聚乳酸和抗冲击改性量的非官能化乙烯/（甲基）丙烯酸酯共聚物的热塑性模塑组合物。 本发明的组合物的特征在于其具有比共聚物官能化的相应组合物更高的抗冲击性，弯曲和拉伸性能。

公开(公告)号：US07541418B2

公开(公告)日：2009-06-02

申请号：US11318961

申请日：2005-12-27

Applicant: Michael A. Gerace ,  James P. Mason ,  John J. Charles

Inventor： Michael A. Gerace ,  James P. Mason ,  John J. Charles

IPC: C08G64/00 ,  B32B9/04

CPC classification number: A01N59/16 ,  C08K3/015 ,  C08K3/32 ,  Y10T428/31504 ,  Y10T428/31507 ,  A01N25/10 ,  A01N2300/00 ,  C08L69/00

Abstract: A transparent antimicrobial thermoplastic molding composition is disclosed. The composition contains aromatic polycarbonate resin and 0.01 to 3.8 of an antimicrobial compound conforming to formula (I) AgaM1bM22(PO4)3  (I) wherein M1 is at least one ion selected from the group consisting of alkali metal ion, alkaline earth metal ion, ammonium ion and hydrogen ion, M2 a tetravalent metal selected from the group consisting of Ti, Zr and Sn, and where a and b are positive numbers where a+mb=1 where m is a valence of M1, the percent being relative to the weight of the polycarbonate. The composition is suitable for molding articles having good appearance and surface qualities.

Abstract translation: 公开了一种透明的抗微生物热塑性模塑组合物。 组合物含有芳香族聚碳酸酯树脂和0.01〜3.8份符合式（I）的抗微生物化合物<？in-line-formula description =“In-line Formulas”end =“lead”→> AgaM1bM22（PO4）3（I） 其中M1是选自碱金属离子，碱土金属离子，铵离子和氢离子中的至少一种离子，其中M1是线性公式描述=“In-line formula”end =“tail” M2是选自Ti，Zr和Sn的四价金属，其中a和b是正数，其中a + mb = 1，其中m是M1的化合价，其百分比相对于聚碳酸酯的重量。 该组合物适合于具有良好外观和表面质量的模制品。

公开(公告)号：US20080214720A1

公开(公告)日：2008-09-04

申请号：US11713484

申请日：2007-03-02

Applicant: Marina Rogunova ,  James P. Mason ,  James Y.J. Chung

Inventor： Marina Rogunova ,  James P. Mason ,  James Y.J. Chung

IPC: C08F290/04

CPC classification number: C08L55/02 ,  C08L25/08 ,  C08L51/04 ,  C08L69/00 ,  C08L69/005 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/14 ,  C08L2666/24

Abstract: A thermoplastic composition suitable for making articles having low gloss and good impact properties is disclosed. The composition contains (A) 20 to 94.5 percent relative to the weight of the composition (pbw) of an aromatic (co)poly(ester)carbonate, (B) 5 to 40 pbw of a graft (co)polymer that includes an EPDM graft base and a grafted phase that is compatible with the aromatic (co)poly(ester)carbonate, and (C) 0.5 to 20 pbw of a linear copolymer containing at least one unit derived from a glycidyl ester monomer, and (D) 0 to 40 pbw of a vinyl copolymer. The gloss of the composition is lower than that of a corresponding composition that contains none of component (C).

Abstract translation: 公开了一种适于制备具有低光泽和良好冲击性能的制品的热塑性组合物。 组合物含有（A）相对于芳族（共）聚（酯）碳酸酯的组合物（pbw）的重量为20至94.5％，（B）5至40pbw的包含EPDM的接枝（共）聚合物 接枝基和与芳族（共）聚（酯）碳酸酯相容的接枝相，和（C）0.5至20pbw的含至少一个衍生自缩水甘油酯单体的单元的线性共聚物，和（D）0 至40pbw的乙烯基共聚物。 组合物的光泽度低于不含组分（C）的相应组合物的光泽度。

公开(公告)号：US20080090961A1

公开(公告)日：2008-04-17

申请号：US11580502

申请日：2006-10-13

Applicant: Xiangyang Li ,  James P. Mason ,  Marty Boykin

Inventor： Xiangyang Li ,  James P. Mason ,  Marty Boykin

IPC: C08L51/08

CPC classification number: C08L69/00 ,  C08K5/523 ,  C08L27/18 ,  C08L51/003 ,  C08L51/06 ,  C08L51/08 ,  C08L51/085 ,  C08L67/02 ,  C08L69/005 ,  C08L2666/02

Abstract: A thermoplastic molding composition characterized by its flame retardance and impact strength is disclosed. The composition contains A) 70 to 99 parts by weight of aromatic poly(ester) carbonate B) 1 to 30 parts by weight of polyalkylene terephthalate, the total weight of A) and B) being 100 parts resin, and C) 1 to 20 parts per hundred parts resin (phr) of graft (co)polymer having a core-shell morphology, including a grafted shell that contains polymerized alkyl(meth)acrylate and a composite rubber core that contains interpenetrated and inseparable polyorganosiloxane and poly(meth)alkyl acrylate components, D) 2 to 20 phr of a phosphorous-containing compound, and E) 0.1 to 2 part by weight of fluorinated polyolefin.

Abstract translation: 公开了一种其阻燃性和冲击强度特征的热塑性模塑组合物。 该组合物含有A）70〜99重量份芳香族聚（酯）碳酸酯B）1〜30重量份聚对苯二甲酸亚烷基酯，总重量A），B）为100份树脂，C）1〜20 包含含有聚合的（甲基）丙烯酸烷基酯的接枝壳和包含互穿和不可分离的聚有机硅氧烷和聚（甲基）丙烯酸烷基酯的复合橡胶芯的具有核 - 壳形态的接枝（共）聚合物的每百份树脂（phr） 丙烯酸酯组分，D）2〜20phr含磷化合物，E）0.1〜2重量份氟化聚烯烃。

公开(公告)号：US5986019A

公开(公告)日：1999-11-16

申请号：US926271

申请日：1997-09-05

Applicant: Rick L. Archey ,  James P. Mason ,  Leslie J. Vescio

Inventor： Rick L. Archey ,  James P. Mason ,  Leslie J. Vescio

IPC: C08G64/18 ,  C08G77/448 ,  C08G81/00

CPC classification number: C08G77/448 ,  C08G64/18

Abstract: A process for making a copolymeric resin is disclosed. Accordingly, component (a) and component (b) are introduced into an extruder under conditions designed to promote reactive blending therebetween in the presence of a transesterification catalyst. Component (a) is a wet aromatic polycarbonate resin containing moisture in an amount greater than 0.02 weight percent and having units conforming to ##STR1## wherein D is a divalent residue of a dihydroxy compound. Component (b) is a lactone-siloxane block copolymer having structural units conforming to ##STR2## wherein m is 1-90, n is 60-150, R is an alkyl or a phenyl radical, p is 2-12 and q is 2-20. Surprisingly, use of moisture-containing polycarbonate in the process yields a copolymer having good properties, although a corresponding process where the lactone-siloxane block copolymer reactant has a smaller number of repeating units yields inferior product.

Abstract translation: 公开了制备共聚树脂的方法。 因此，在酯交换催化剂存在下，在设计为促进其间的反应性共混的条件下，将组分（a）和组分（b）引入挤出机中。 组分（a）是含有大于0.02重量％的水分并且具有符合其中D是二羟基化合物的二价残基的单元的湿芳族聚碳酸酯树脂。 组分（b）是具有符合其结构单元的内酯 - 硅氧烷嵌段共聚物，其中m为1-90，n为60-150，R为烷基或苯基，p为2-12，q为2-20。 令人惊奇的是，在该方法中使用含水分的聚碳酸酯产生具有良好性能的共聚物，尽管内酯 - 硅氧烷嵌段共聚物反应物具有较少数量的重复单元的相应方法产生较差的产物。

公开(公告)号：US5709941A

公开(公告)日：1998-01-20

申请号：US743510

申请日：1996-11-04

Applicant: James P. Mason

Inventor： James P. Mason

IPC: B29B9/06 ,  B29B13/08 ,  B29C35/08

CPC classification number: B29B13/08 ,  B29B9/06 ,  B29C2035/0822 ,  B29K2067/00 ,  Y10T428/2913 ,  Y10T428/2978

Abstract: A process for rapidly improving the flowability, in pellet form, of a molding composition is disclosed. Accordingly, the crystalline content of an amorphous or a semi-amorphous version of a crystallizable thermoplastic resin is increased by subjecting the resin to infra-red radiation to an extent which induces the formation of crystals in the irradiated amorphous resin or the increase of the level of crystals in the semi-amorphous irradiated resins. The resin modified by the inventive process is rendered more suitable for processing: in dried, pellet-form, the modified resin is characterized by its improved flowability. An article molded from the thus modified resin exhibits better properties than does a corresponding article made from a unmodified resins which has been subjected to similar drying conditions.

Abstract translation: 公开了一种用于快速提高成型组合物的颗粒形式的流动性的方法。 因此，可结晶热塑性树脂的无定形或半非晶形式的结晶含量通过使树脂经受红外辐射到引起在被照射的无定形树脂中形成晶体的程度或水平的增加而增加 的半无定形辐射树脂中的晶体。 通过本发明方法改性的树脂更适合于加工：在干燥的颗粒形式中，改性树脂的特征在于其改进的流动性。 由这样改性的树脂成型的制品比由经过类似干燥条件的未改性树脂制成的相应制品表现出更好的性能。