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公开(公告)号：US20240092965A1
公开(公告)日：2024-03-21
申请号：US18366977
申请日：2023-08-08
Applicant: Jason D. Azoulay , Lifeng Huang , Alexander E. London , Naresh Eedugurala
Inventor： Jason D. Azoulay , Lifeng Huang , Alexander E. London , Naresh Eedugurala
CPC classification number: C08G61/126 , C08J5/18 , C08K3/041 , H01B1/16 , H01B1/18 , C08G2261/122 , C08G2261/148 , C08G2261/1646 , C08G2261/18 , C08G2261/3223 , C08G2261/3225 , C08G2261/3241 , C08G2261/3243 , C08G2261/3246 , C08G2261/414 , C08G2261/514 , C08J2365/00 , C08K2201/001 , C08K2201/011
Abstract: The invention provides for polymer structures and their preparation and resulting novel functionalities including open-shell character and high intrinsic conductivity with wide-range tenability. Electrical conductivity can be further modulated by introducing or blending with materials, fillers, dopants, and/or additives. The materials or resultant composites of the invention can be processed by various techniques into different forms to realize multiple applications.
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公开(公告)号：US20200095371A1
公开(公告)日：2020-03-26
申请号：US16579694
申请日：2019-09-23
Applicant: Joshua Tropp , Douglas V. Amato , Derek L. Patton , Jason D. Azoulay
Inventor： Joshua Tropp , Douglas V. Amato , Derek L. Patton , Jason D. Azoulay
Abstract: The present invention provides novel polymer compounds and methods and processes for polymerizing and synthesizing the new polymers by post-modifying conjugated polymers bearing unsaturated functionalities. The post-modifications are facilitated by light-mediated initiators, thermal initiators, redox-based initiators, small molecule-based initiators, or a combination thereof. Syntheses and post-modifications are carried out to high conversion via thiol-ene “click” chemistry-based mechanisms. The products comprise monomeric, oligomeric, and polymeric materials with easily-accessible pendant functionalities which impart new, distinct, and/or improved properties.
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公开(公告)号：US20240327568A1
公开(公告)日：2024-10-03
申请号：US18740165
申请日：2024-06-11
Applicant: Jason D. Azoulay , Lifeng Huang , Alexander E. London , Naresh Eedugurala
Inventor： Jason D. Azoulay , Lifeng Huang , Alexander E. London , Naresh Eedugurala
CPC classification number: C08G61/126 , C08J5/18 , C08K3/041 , H01B1/16 , H01B1/18 , C08G2261/122 , C08G2261/148 , C08G2261/1646 , C08G2261/18 , C08G2261/3223 , C08G2261/3225 , C08G2261/3241 , C08G2261/3243 , C08G2261/3246 , C08G2261/414 , C08G2261/514 , C08J2365/00 , C08K2201/001 , C08K2201/011
Abstract: The invention provides for polymer structures and their preparation and resulting novel functionalities including open-shell character and high intrinsic conductivity with wide-range tenability. Electrical conductivity can be further modulated by introducing or blending with materials, fillers, dopants, and/or additives. The materials or resultant composites of the invention can be processed by various techniques into different forms to realize multiple applications.
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公开(公告)号：US20190085119A1
公开(公告)日：2019-03-21
申请号：US16138162
申请日：2018-09-21
Applicant: Jason D. Azoulay , Joshua Tropp , Eric King
Inventor： Jason D. Azoulay , Joshua Tropp , Eric King
CPC classification number: C08G61/10 , C08G61/02 , C08G61/126 , C08G2261/1412 , C08G2261/1414 , C08G2261/1426 , C08G2261/143 , C08G2261/146 , C08G2261/149 , C08G2261/228 , C08G2261/312 , C08G2261/3223 , C08G2261/3328 , C08G2261/3422 , C08G2261/41
Abstract: The present invention provides novel methods and processes for polymerizing unsaturated substrates, such as alkyne bearing monomers, with arenes. The polymerizations are catalyzed by gold (Au) catalysts/complexes and/or other cocatalysts. The invention further provides novel structurally complex polymers prepared in high yield via an intermolecular polyhydroarylation mechanism. Such resulting products comprise oligomeric and polymeric materials with novel molecular architectures and microstructures, which subsequently impart unique properties. The invention includes both the synthesis methods and processes and the resulting compounds and compositions of matter.
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公开(公告)号：US12043698B2
公开(公告)日：2024-07-23
申请号：US18366977
申请日：2023-08-08
Applicant: Jason D. Azoulay , Lifeng Huang , Alexander E. London , Naresh Eedugurala
Inventor： Jason D. Azoulay , Lifeng Huang , Alexander E. London , Naresh Eedugurala
CPC classification number: C08G61/126 , C08J5/18 , C08K3/041 , H01B1/16 , H01B1/18 , C08G2261/122 , C08G2261/148 , C08G2261/1646 , C08G2261/18 , C08G2261/3223 , C08G2261/3225 , C08G2261/3241 , C08G2261/3243 , C08G2261/3246 , C08G2261/414 , C08G2261/514 , C08J2365/00 , C08K2201/001 , C08K2201/011
Abstract: The invention provides for polymer structures and their preparation and resulting novel functionalities including open-shell character and high intrinsic conductivity with wide-range tenability. Electrical conductivity can be further modulated by introducing or blending with materials, fillers, dopants, and/or additives. The materials or resultant composites of the invention can be processed by various techniques into different forms to realize multiple applications.
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Patent Agency Ranking
公开(公告)号：US11649320B2
公开(公告)日：2023-05-16
申请号：US16579694
申请日：2019-09-23
Applicant: Joshua Tropp , Douglas V. Amato , Derek L. Patton , Jason D. Azoulay
Inventor： Joshua Tropp , Douglas V. Amato , Derek L. Patton , Jason D. Azoulay
CPC classification number: C08G61/126 , C08G61/02 , C08G2261/124 , C08G2261/145 , C08G2261/1412 , C08G2261/1426 , C08G2261/18 , C08G2261/228 , C08G2261/3142 , C08G2261/3223 , C08G2261/78
Abstract: The present invention provides novel polymer compounds and methods and processes for polymerizing and synthesizing the new polymers by post-modifying conjugated polymers bearing unsaturated functionalities. The post-modifications are facilitated by light-mediated initiators, thermal initiators, redox-based initiators, small molecule-based initiators, or a combination thereof. Syntheses and post-modifications are carried out to high conversion via thiol-ene “click” chemistry-based mechanisms. The products comprise monomeric, oligomeric, and polymeric materials with easily-accessible pendant functionalities which impart new, distinct, and/or improved properties.
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公开(公告)号：US10711092B2
公开(公告)日：2020-07-14
申请号：US16138162
申请日：2018-09-21
Applicant: Jason D. Azoulay , Joshua Tropp , Eric King
Inventor： Jason D. Azoulay , Joshua Tropp , Eric King
Abstract: The present invention provides novel methods and processes for polymerizing unsaturated substrates, such as alkyne bearing monomers, with arenes. The polymerizations are catalyzed by gold (Au) catalysts/complexes and/or other cocatalysts. The invention further provides novel structurally complex polymers prepared in high yield via an intermolecular polyhydroarylation mechanism. Such resulting products comprise oligomeric and polymeric materials with novel molecular architectures and microstructures, which subsequently impart unique properties. The invention includes both the synthesis methods and processes and the resulting compounds and compositions of matter.
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8.发明申请CONJUGATED POLYMERS HAVING AN IMINE GROUP AT THE INTRACHAIN ELECTRON DONOR BRIDGEHEAD POSITION USEFUL IN ELECTRONIC DEVICES 审中-公开在电子设备中有用的INTRACHAIN ELECTRON DONOR BRIDGEHEAD POSITION有电子组合的聚合聚合物公开(公告)号：US20130032791A1
公开(公告)日：2013-02-07
申请号：US13523716
申请日：2012-06-14
Applicant: Guillermo C. Bazan , Jason D. Azoulay , Bruno Caputo
Inventor： Guillermo C. Bazan , Jason D. Azoulay , Bruno Caputo
IPC: C08G75/32 , H01L51/54 , C07C251/20 , C07F7/22 , C07F5/02 , H01L51/46 , C07D495/04
CPC classification number: C07D495/04
Abstract: Described herein are novel light absorbing conjugated polymeric electron donor materials for organic photovoltaic devices and other applications. In one embodiment, the polymer structure comprises a conjugated electron rich donor unit with an imine functionality at the bridgehead position and a conjugated electron deficient unit in the polymer backbone arranged in an alternating fashion. Monomers suitable for making the polymers, and devices utilizing the polymers, are also disclosed.
Abstract translation: 本文描述了用于有机光伏器件和其它应用的新型光吸收共轭聚合电子供体材料。 在一个实施方案中，聚合物结构包含在桥头位置具有亚胺官能团的共轭电子富集供体单元和以交替方式排列的聚合物主链中的共轭电子缺陷单元。 还公开了适于制备聚合物的单体和利用聚合物的装置。
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9.发明授权Transition metal initiators supported by ketone diimine ligands for the homopolymerization of olefins and the copolymerization of olefins with polar comonomers 有权由酮二亚胺配体负载的过渡金属引发剂用于烯烃均聚和烯烃与极性共聚单体的共聚公开(公告)号：US08242297B2
公开(公告)日：2012-08-14
申请号：US12435706
申请日：2009-05-05
Applicant: Jason D. Azoulay , Yanika Schneider , Guillermo C. Bazan
Inventor： Jason D. Azoulay , Yanika Schneider , Guillermo C. Bazan
CPC classification number: C07F15/045 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/16 , C08F2500/01 , C08F2500/03 , C08F220/14 , C08F2500/04 , C08F210/14 , C08F4/7006
Abstract: Metal-ligand combination initiators are provided which yield organometallic complexes capable of the polymerization of olefins to high molecular weight polymers. Additionally, these initiators also enable the copolymerization of olefins with functionalized comonomers. These organometallic complexes comprise of a late transition metal with a neutral chelating ligand that contains a Lewis basic functionality in conjugation with an electronically delocalized conduit extending from the metal to the functionality. This structural feature results in a highly active complex, which generates high molecular weight polymers with unique microstructures. Under particular conditions, the organometallic complexes provide for the living polymerization of monomers and comonomers.
Abstract translation: 提供了金属 - 配体组合引发剂，其产生能够将烯烃聚合成高分子量聚合物的有机金属络合物。 此外，这些引发剂还使烯烃与官能化共聚单体共聚。 这些有机金属络合物包括具有中性螯合配体的后过渡金属，其含有与从金属延伸至官能团的电子离域导管共轭的路易斯碱性官能团。 这种结构特征导致高活性复合物，其产生具有独特微结构的高分子量聚合物。 在特定条件下，有机金属配合物提供单体和共聚单体的活性聚合。
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10.发明申请TRANSITION METAL INITIATORS SUPPORTED BY KETONE DIIMINE LIGANDS FOR THE HOMOPOLYMERIZATION OF OLEFINS AND THE COPOLYMERIZATION OF OLEFINS WITH POLAR COMONOMERS 有权由KETONE DIIMINE配体支持的过渡金属反应器用于烯烃的共聚合和烯烃与极性共聚物的共聚合公开(公告)号：US20090299020A1
公开(公告)日：2009-12-03
申请号：US12435706
申请日：2009-05-05
Applicant: Jason D. Azoulay , Yanika Schneider , Guillermo C. Bazan
Inventor： Jason D. Azoulay , Yanika Schneider , Guillermo C. Bazan
CPC classification number: C07F15/045 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/16 , C08F2500/01 , C08F2500/03 , C08F220/14 , C08F2500/04 , C08F210/14 , C08F4/7006
Abstract: Metal-ligand combination initiators are provided which yield organometallic complexes capable of the polymerization of olefins to high molecular weight polymers. Additionally, these initiators also enable the copolymerization of olefins with functionalized comonomers. These organometallic complexes comprise of a late transition metal with a neutral chelating ligand that contains a Lewis basic functionality in conjugation with an electronically delocalized conduit extending from the metal to the functionality. This structural feature results in a highly active complex, which generates high molecular weight polymers with unique microstructures. Under particular conditions, the organometallic complexes provide for the living polymerization of monomers and comonomers.
Abstract translation: 提供了金属 - 配体组合引发剂，其产生能够将烯烃聚合成高分子量聚合物的有机金属络合物。 此外，这些引发剂还使烯烃与官能化共聚单体共聚。 这些有机金属络合物包含具有中性螯合配体的后过渡金属，其含有与从金属延伸至官能团的电子离域导管共轭的路易斯碱性官能团。 这种结构特征导致高活性复合物，其产生具有独特微结构的高分子量聚合物。 在特定条件下，有机金属配合物提供单体和共聚单体的活性聚合。
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