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1.发明授权Water-forming hydrogenation reactions utilizing enhanced catalyst supports and methods of use 有权使用增强的催化剂载体和使用方法的成水氢化反应公开(公告)号：US08530528B2
公开(公告)日：2013-09-10
申请号：US13016745
申请日：2011-01-28
Applicant: Joe D. Allison , Byron G. Johnson
Inventor： Joe D. Allison , Byron G. Johnson
IPC: C07C27/00
CPC classification number: B01J23/70 , B01J21/005 , B01J21/04 , B01J21/12 , B01J23/005 , B01J23/40 , B01J23/63 , B01J23/89 , B01J35/023 , B01J35/1014 , B01J35/1061 , B01J37/0045 , B01J37/0207 , C08F8/04 , C10G2/33 , C10G3/42 , C10G3/48 , C10G3/50 , C10G45/04 , Y02P30/20
Abstract: Improved reaction efficiencies are achieved by the incorporation of enhanced hydrothermally stable catalyst supports in various water-forming hydrogenation reactions or reactions having water-containing feeds. Examples of water-forming hydrogenation reactions that may incorporate the enhanced hydrothermally stable catalyst supports include alcohol synthesis reactions, dehydration reactions, hydrodeoxygenation reactions, methanation reactions, catalytic combustion reaction, hydrocondensation reactions, and sulfur dioxide hydrogenation reactions. Advantages of the methods disclosed herein include an improved resistance of the catalyst support to water poisoning and a consequent lower rate of catalyst attrition and deactivation due to hydrothermal instability. Accordingly, higher efficiencies and yields may be achieved by extension of the enhanced catalyst supports to one or more of the aforementioned reactions.
Abstract translation: 通过在各种成水氢化反应中加入增强的水热稳定的催化剂载体或含有含水进料的反应来实现提高的反应效率。 可以引入增强的水热稳定催化剂载体的成水氢化反应的实例包括醇合成反应，脱水反应，加氢脱氧反应，甲烷化反应，催化燃烧反应，缩水反应和二氧化硫氢化反应。 本文公开的方法的优点包括催化剂载体对水中毒的改善的耐受性以及随之而来的较低的催化剂消耗速率和由于水热不稳定性而失活。 因此，通过将增强的催化剂载体延伸到一个或多个上述反应可以实现更高的效率和收率。
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公开(公告)号：US08487011B2
公开(公告)日：2013-07-16
申请号：US12951580
申请日：2010-11-22
Applicant: Douglas E. Fjare , Joe D. Allison
Inventor： Douglas E. Fjare , Joe D. Allison
IPC: C07C27/00
Abstract: Methods and compositions relate to a Fischer-Tropsch catalyst utilized to convert syngas into paraffins. The catalyst includes a given amount of sulfur content from contact of a catalytic supported metal with sulfur. Subsequent activation of the catalyst prepares the catalyst to be used for conversion of the syngas. The sulfur content maintained in the catalyst after being activated influences selectivity to paraffins over olefins and oxygenates.
Abstract translation: 方法和组合物涉及用于将合成气转化为石蜡的费 - 托催化剂。 催化剂包括由催化负载金属与硫接触的给定量的硫含量。 催化剂的随后活化制备用于合成气转化的催化剂。 激活后保持在催化剂中的硫含量影响链烷烃对烯烃和含氧化合物的选择性。
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公开(公告)号：US20130172650A1
公开(公告)日：2013-07-04
申请号：US13717869
申请日：2012-12-18
Applicant: Shetian Liu , Jianhua Yao , Xiaochun Xu , Patrick W. Blosser , Joe D. Allison , Edward L. Sughrue, II
Inventor： Shetian Liu , Jianhua Yao , Xiaochun Xu , Patrick W. Blosser , Joe D. Allison , Edward L. Sughrue, II
IPC: C07C2/24
CPC classification number: C07C2/24 , C10G50/00 , C10G2300/1092 , C10G2400/02 , C10G2400/10
Abstract: Methods and systems relate to upgrading light olefins, such as ethylene, propylene and butylenes, diluted in a gas mixture, such as refinery fuel gas. The upgrading yields products in a gasoline, distillate, lube oil or wax range without requiring purification or compression of the gas mixture prior to feeding the gas mixture to a reactor. In operation, the mixture contacts a solid oligomerization catalyst, such as silica supported chromium, within the reactor. This contact occurs at a first temperature suitable to produce oligomers that are formed of the olefins and adsorb on the catalyst in liquid or solid phases. Next, heating the catalyst to a second temperature higher the first temperature desorbs the oligomers that are recovered and separated into the products.
Abstract translation: 方法和系统涉及在诸如炼油厂燃料气体的气体混合物中稀释的轻质烯烃，例如乙烯，丙烯和丁烯。 升级产生汽油，馏出物，润滑油或蜡的产品，而不需要在将气体混合物送入反应器之前对气体混合物进行纯化或压缩。 在操作中，混合物在反应器内接触固体低聚催化剂，例如二氧化硅负载的铬。 该接触在适于产生由烯烃形成并以液相或固相吸附在催化剂上的低聚物的第一温度下进行。 接下来，将催化剂加热至高于第一温度的第二温度，第一温度将回收并分离成产物的低聚物解吸附。
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公开(公告)号：US08450545B2
公开(公告)日：2013-05-28
申请号：US12509253
申请日：2009-07-24
Applicant: Glenn W. Dodwell , Joe D. Allison , Shetian Liu , Scott McQueen , Dennis G. Schultz , Byron G. Johnson , Madhu Anand , Melinda L. Johnson , Larry E. Reed , Brian C. Dunn
Inventor： Glenn W. Dodwell , Joe D. Allison , Shetian Liu , Scott McQueen , Dennis G. Schultz , Byron G. Johnson , Madhu Anand , Melinda L. Johnson , Larry E. Reed , Brian C. Dunn
IPC: C07C1/20
CPC classification number: B01J29/40 , B01J29/06 , B01J29/076 , B01J29/48 , B01J2229/123 , B01J2229/186 , B01J2229/32 , C10G3/44 , C10G3/49 , C10G2300/1011 , C10G2300/305 , C10G2400/02 , C10L1/06 , Y02P30/20
Abstract: A process of modifying a zeolite catalyst to produce a modified zeolite catalyst wherein the modified zeolite catalyst has blocked pore sites. An oxygenated feed is flowed over the modified zeolite catalyst, wherein the oxygenated feed comprises hydrocarbons, methanol and dimethyl ether or a mixture thereof. The hydrocarbons, methanol and dimethyl ether in the oxygenated feed react with the modified zeolite catalyst to produce cyclic hydrocarbons, wherein the cyclic hydrocarbons produced has less than 10% durene and a median carbon number is C8.
Abstract translation: 一种改性沸石催化剂以制备改性沸石催化剂的方法，其中改性沸石催化剂具有阻塞的孔隙位点。 氧化进料流过改性沸石催化剂，其中含氧进料包括烃，甲醇和二甲醚或其混合物。 含氧进料中的烃，甲醇和二甲醚与改性沸石催化剂反应生成环状烃，其中产生的环状烃具有小于10％的杜烯，中位碳数为C8。
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公开(公告)号：US08420564B2
公开(公告)日：2013-04-16
申请号：US13236326
申请日：2011-09-19
Applicant: Madhu Anand , Joe D. Allison
Inventor： Madhu Anand , Joe D. Allison
IPC: B01J27/051 , B01J37/00 , C01G39/06
CPC classification number: C01G39/06 , B01J21/066 , B01J27/051 , B01J35/1014 , B01J35/1019 , B01J37/0203 , B01J37/088 , B01J37/10 , B01J37/18 , B01J37/20
Abstract: A method of producing a MoS2 catalyst. The method begins by the decomposition of ammonium tetrathiomolybdate in an organic solvent. This decomposition is done in the presence of a solution comprising: a solvent and a promoter, and done under gaseous pressure.
Abstract translation: 一种制备MoS 2催化剂的方法。 该方法开始于有机溶剂中四硫代钼酸铵的分解。 这种分解是在包含溶剂和促进剂的溶液的存在下进行的，并在气压下进行。
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Patent Agency Ranking
6.发明申请SITU HYDROCARBON UPGRADING WITH FLUID GENERATED TO PROVIDE STEAM AND HYDROGEN 审中-公开发动机提供蒸汽和氢气的SITU碳氢化合物公开(公告)号：US20120073810A1
公开(公告)日：2012-03-29
申请号：US13239018
申请日：2011-09-21
Applicant: Scott Macadam , James P. Seaba , Wayne Reid Dreher, JR. , Joe D. Allison
Inventor： Scott Macadam , James P. Seaba , Wayne Reid Dreher, JR. , Joe D. Allison
IPC: E21B43/24
CPC classification number: E21B43/305 , E21B43/2406
Abstract: Methods and apparatus relate to recovery of in situ upgraded hydrocarbons by injecting steam and hydrogen into a reservoir containing the hydrocarbons. A mixture output generated as water is vaporized by direct contact with flow from fuel-rich combustion provides the steam and hydrogen. The steam heats the hydrocarbons facilitating flow of the hydrocarbons and reaction of the hydrogen with the hydrocarbons to enable hydroprocessing prior to recovery of the hydrocarbons to surface.
Abstract translation: 方法和装置涉及通过将蒸汽和氢气注入含有烃的储层中回收原位升级的烃。 通过与富燃燃烧的流体直接接触而产生的水产生的混合物产生蒸汽和氢。 蒸汽加热烃促进烃的流动和氢气与烃的反应，以便在将烃回收到表面之前进行加氢处理。
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7.发明申请Water-Forming Hydrogenation Reactions Utilizing Enhanced Catalyst Supports and Methods of Use 有权使用增强的催化剂载体和使用方法的水形成氢化反应公开(公告)号：US20110230572A1
公开(公告)日：2011-09-22
申请号：US13016745
申请日：2011-01-28
Applicant: Joe D. Allison , Byron G. Johnson
Inventor： Joe D. Allison , Byron G. Johnson
CPC classification number: B01J23/70 , B01J21/005 , B01J21/04 , B01J21/12 , B01J23/005 , B01J23/40 , B01J23/63 , B01J23/89 , B01J35/023 , B01J35/1014 , B01J35/1061 , B01J37/0045 , B01J37/0207 , C08F8/04 , C10G2/33 , C10G3/42 , C10G3/48 , C10G3/50 , C10G45/04 , Y02P30/20
Abstract: Improved reaction efficiencies are achieved by the incorporation of enhanced hydrothermally stable catalyst supports in various water-forming hydrogenation reactions or reactions having water-containing feeds. Examples of water-forming hydrogenation reactions that may incorporate the enhanced hydrothermally stable catalyst supports include alcohol synthesis reactions, dehydration reactions, hydrodeoxygenation reactions, methanation reactions, catalytic combustion reaction, hydrocondensation reactions, and sulfur dioxide hydrogenation reactions. Advantages of the methods disclosed herein include an improved resistance of the catalyst support to water poisoning and a consequent lower rate of catalyst attrition and deactivation due to hydrothermal instability. Accordingly, higher efficiencies and yields may be achieved by extension of the enhanced catalyst supports to one or more of the aforementioned reactions.
Abstract translation: 通过在各种成水氢化反应中加入增强的水热稳定的催化剂载体或含有含水进料的反应来实现提高的反应效率。 可以引入增强的水热稳定催化剂载体的成水氢化反应的实例包括醇合成反应，脱水反应，加氢脱氧反应，甲烷化反应，催化燃烧反应，缩水反应和二氧化硫氢化反应。 本文公开的方法的优点包括催化剂载体对水中毒的改善的耐受性以及随之而来的较低的催化剂消耗速率和由于水热不稳定性而失活。 因此，通过将增强的催化剂载体延伸到一个或多个上述反应可以实现更高的效率和收率。
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公开(公告)号：US20110124751A1
公开(公告)日：2011-05-26
申请号：US12951580
申请日：2010-11-22
Applicant: Douglas E. Fjare , Joe D. Allison
Inventor： Douglas E. Fjare , Joe D. Allison
Abstract: Methods and compositions relate to a Fischer-Tropsch catalyst utilized to convert syngas into paraffins. The catalyst includes a given amount of sulfur content from contact of a catalytic supported metal with sulfur. Subsequent activation of the catalyst prepares the catalyst to be used for conversion of the syngas. The sulfur content maintained in the catalyst after being activated influences selectivity to paraffins over olefins and oxygenates.
Abstract translation: 方法和组合物涉及用于将合成气转化为石蜡的费 - 托催化剂。 催化剂包括由催化负载金属与硫接触的给定量的硫含量。 催化剂的随后活化制备用于合成气转化的催化剂。 激活后保持在催化剂中的硫含量影响链烷烃对烯烃和含氧化合物的选择性。
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公开(公告)号：US07938894B2
公开(公告)日：2011-05-10
申请号：US12039664
申请日：2008-02-28
Applicant: Shigeo Ted Oyama , Yunfeng Gu , Joe D. Allison , Garry C. Gunter , Scott A. Scholten
Inventor： Shigeo Ted Oyama , Yunfeng Gu , Joe D. Allison , Garry C. Gunter , Scott A. Scholten
CPC classification number: B01D69/141 , B01D53/228 , B01D67/0072 , B01D67/0079 , B01D2323/08 , Y02C10/10 , Y02C20/20 , Y10S55/05 , Y10T428/249953
Abstract: The invention discloses a composition comprising a hybrid composite organic-inorganic membrane. The hybrid organic-inorganic membrane according to the present invention may comprise an amorphous porous layer incorporating organic functionalities. The amorphous porous layer may be deposited on a porous alumina substrate by chemical vapor deposition (CVD). The amorphous porous layer may comprise a single top-layer (STL), multiple top-layers (MTL) or mixed top-layers (XTL). The substrate may comprise a single layer or multiple graded layers of alumina.
Abstract translation: 本发明公开了一种包含杂化复合有机 - 无机膜的组合物。 根据本发明的杂化有机 - 无机膜可以包括结合有机官能团的无定形多孔层。 可以通过化学气相沉积（CVD）将无定形多孔层沉积在多孔氧化铝衬底上。 非晶多孔层可以包括单个顶层（STL），多个顶层（MTL）或混合顶层（XTL）。 基底可以包括单层或多层氧化铝分级层。
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公开(公告)号：US20090205500A1
公开(公告)日：2009-08-20
申请号：US12039664
申请日：2008-02-28
Applicant: Shigeo Ted Oyama , Yunfeng Gu , Joe D. Allison , Garry C. Gunter , Scott A. Scholten
Inventor： Shigeo Ted Oyama , Yunfeng Gu , Joe D. Allison , Garry C. Gunter , Scott A. Scholten
CPC classification number: B01D69/141 , B01D53/228 , B01D67/0072 , B01D67/0079 , B01D2323/08 , Y02C10/10 , Y02C20/20 , Y10S55/05 , Y10T428/249953
Abstract: The invention discloses a composition comprising a hybrid composite organic-inorganic membrane. The hybrid organic-inorganic membrane according to the present invention may comprise an amorphous porous layer incorporating organic functionalities. The amorphous porous layer may be deposited on a porous alumina substrate by chemical vapor deposition (CVD). The amorphous porous layer may comprise a single top-layer (STL), multiple top-layers (MTL) or mixed top-layers (XTL). The substrate may comprise a single layer or multiple graded layers of alumina.
Abstract translation: 本发明公开了一种包含杂化复合有机 - 无机膜的组合物。 根据本发明的杂化有机 - 无机膜可以包括结合有机官能团的无定形多孔层。 可以通过化学气相沉积（CVD）将无定形多孔层沉积在多孔氧化铝衬底上。 非晶多孔层可以包括单个顶层（STL），多个顶层（MTL）或混合顶层（XTL）。 基底可以包括单层或多层氧化铝分级层。
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