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    Product By Integrated Process for Producing Propylene Polymers and Copolymers with Reduced Greenhouse Gas Emission
    1.
    发明申请
    Product By Integrated Process for Producing Propylene Polymers and Copolymers with Reduced Greenhouse Gas Emission 有权

    公开(公告)号：US20220073655A1

    公开(公告)日：2022-03-10

    申请号：US17017562

    申请日：2020-09-10

    Applicant: REXtac, LLC

    Inventor： James Nicholas Fowler ,  Deborah Lawrence ,  Stephen Craig McHaney

    IPC: C08F10/06 ,  C07C2/82 ,  C07C2/08 ,  C07C6/10

    Abstract: A product made by a substantially zero-carbon-emission (ZCE) process for making propylene polymers and copolymers including: converting alkanes to the olefin monomers ethylene, propylene, and butene or combinations thereof, using renewable electric power and scrubbing the stack gases from any fired heaters or boilers to remove carbon dioxide, in an oxidative-coupling of methane plant including the steps of passing alkanes through an ethylene plant while adding oxygen, passing a portion of the polymerization grade ethylene through a 2-butene plant, and passing the 2-butene stream and a portion of the polymerization grade ethylene stream through a propylene plant. The polymerization grade propylene is polymerized to produce isotactic homopolymer polypropylene, or ethylene-propylene random copolymer, or impact-grade polypropylene containing ethylene-propylene rubber.

    Process for pre-contacting catalyst components ex-reactor to produce amorphous poly alpha-olefins
    2.
    发明授权
    Process for pre-contacting catalyst components ex-reactor to produce amorphous poly alpha-olefins 有权

    公开(公告)号：US10995162B2

    公开(公告)日：2021-05-04

    申请号：US16508491

    申请日：2019-07-11

    Applicant: REXtac, LLC

    Inventor： Mitchell Arnold ,  Andres Sustic ,  Steve Oetting ,  Nick Fowler

    IPC: C08F10/06

    Abstract: A continuous process for pre-contacting coordination polymerization catalyst components with each other before they are introduced into a polymerization reactor at 130 degrees Fahrenheit to 200 degrees Fahrenheit, where the activated coordination catalyst is contacted with at least one monomer to produce amorphous poly alpha olefin (APAO), the process involving blending a Ziegler-Natta pro-catalyst with a liquid carrier forming a Ziegler-Natta pro-catalyst slurry and flowing a co-catalyst mixture into the Ziegler-Natta pro-catalyst slurry continuously in a pre-contacting device, forming an activated Ziegler-Natta catalyst; continuously injecting the activated Ziegler-Natta catalyst into the heated polymerization reactor while simultaneously, and continuously, injecting propylene monomer and any other alpha-olefin monomers, and hydrogen gas for molecular weight control, initiating an exothermic reaction forming a monomer-polymer-catalyst slurry then continuously stirring the monomer-polymer-catalyst slurry forming an amorphous poly alpha olefin with a saturated backbone.

    Performance APAO hot melt adhesives containing high melt flow rate hydrogenated styrene block copolymers
    3.
    发明申请
    Performance APAO hot melt adhesives containing high melt flow rate hydrogenated styrene block copolymers 有权
    性能APAO热熔胶含有高熔体流动速率的氢化苯乙烯嵌段共聚物

    公开(公告)号：US20160222258A1

    公开(公告)日：2016-08-04

    申请号：US15011256

    申请日：2016-01-29

    Applicant: Rextac LLC.

    Inventor： Andres Sustic ,  Enrico L. Buenacosa ,  James Haselman ,  James Nicholas Fowler

    IPC: C09J123/20 ,  C08J3/00 ,  C08J3/20

    CPC classification number: C08J3/005 ,  C08J3/201 ,  C08J2323/20 ,  C08J2423/12 ,  C08J2453/02 ,  C08L23/14 ,  C08L53/02

    Abstract: Adding a compatible high melt flow rate (MFR), low melt viscosity, hydrogenated styrene block copolymer to amorphous poly alpha-olefins (APAOs) results in adhesives that show acceptably high elongation and tensile strength, and which, when applied by different hot melt application methods onto elastic strands, result in personal hygiene article components that perform comparably to such components assembled using just styrene block copolymer components formulated with compatible tackifiers, processing oils and other additives.

    Abstract translation: 将可溶性高熔体流动速率（MFR），低熔体粘度，氢化苯乙烯嵌段共聚物加入到无定形聚α-烯烃（APAO）中，导致显示可接受的高伸长率和拉伸强度的粘合剂，并且当通过不同的热熔体应用 使用弹性股线的方法，导致个人卫生制品组件与使用仅与配合的增粘剂，加工油和其它添加剂配制的苯乙烯嵌段共聚物组分组装的这些组分相当地进行。

    APAO hot melt adhesives containing a low molecular weight, functionalized, isotactic polypropylene
    6.
    发明申请
    APAO hot melt adhesives containing a low molecular weight, functionalized, isotactic polypropylene 有权
    含有低分子量官能化全同立构聚丙烯的APAO热熔胶

    公开(公告)号：US20160289511A1

    公开(公告)日：2016-10-06

    申请号：US15085255

    申请日：2016-03-30

    Applicant: REXtac LLC

    Inventor： Andres Sustic ,  Enrico L. Buenacosa

    IPC: C09J123/20 ,  C09J123/14

    CPC classification number: C09J123/20 ,  C08K5/13 ,  C08L51/06 ,  C09J123/08

    Abstract: Adding a low molecular weight (or alternatively, high melt flow rate), functionalized, isotactic polypropylene (iPP) to a hot melt adhesive (HMA), composition containing a propylene-butene-1, and/or a propylene-ethylene amorphous poly alpha olefin (APAO) copolymer, in addition to other co-adjuvants (such as a tackifier or a plasticizer), results in an APAO-based HMA that shows improved tensile strength and bonding properties, over an HMA that contains only the propylene-butene-1 and/or the propylene-ethylene APAO copolymer (with or without a tackifier and/or a plasticizer).

    Abstract translation: 向热熔粘合剂（HMA）中加入低分子量（或者高熔体流动速率）官能化的全同立构聚丙烯（iPP），含有丙烯 - 丁烯-1和/或丙烯 - 乙烯无定形聚α 烯烃（APAO）共聚物除了其它辅助助剂（如增粘剂或增塑剂）之外，还产生了一种基于APAO的HMA，其显示出比仅包含丙烯 - 丁烯 - 丁烯共聚物的HMA显示出更好的拉伸强度和粘合性能， 1和/或丙烯 - 乙烯APAO共聚物（具有或不具有增粘剂和/或增塑剂）。

    PROCESS FOR PRE-CONTACTING CATALYST COMPONENTS EX-REACTOR TO PRODUCE AMORPHOUS POLY ALPHA-OLEFINS
    10.
    发明申请
    PROCESS FOR PRE-CONTACTING CATALYST COMPONENTS EX-REACTOR TO PRODUCE AMORPHOUS POLY ALPHA-OLEFINS 有权

    公开(公告)号：US20210017306A1

    公开(公告)日：2021-01-21

    申请号：US16508491

    申请日：2019-07-11

    Applicant: REXtac, LLC

    Inventor： Mitchell Arnold ,  Andres Sustic ,  Steve Oetting ,  Nick Fowler

    IPC: C08F10/06

    Abstract: A continuous process for pre-contacting coordination polymerization catalyst components with each other before they are introduced into a polymerization reactor at 130 degrees Fahrenheit to 200 degrees Fahrenheit, where the activated coordination catalyst is contacted with at least one monomer to produce amorphous poly alpha olefin (APAO), the process involving blending a Ziegler-Natta pro-catalyst with a liquid carrier forming a Ziegler-Natta pro-catalyst slurry and flowing a co-catalyst mixture into the Ziegler-Natta pro-catalyst slurry continuously in a pre-contacting device, forming an activated Ziegler-Natta catalyst; continuously injecting the activated Ziegler-Natta catalyst into the heated polymerization reactor while simultaneously, and continuously, injecting propylene monomer and any other alpha-olefin monomers, and hydrogen gas for molecular weight control, initiating an exothermic reaction forming a monomer-polymer-catalyst slurry then continuously stirring the monomer-polymer-catalyst slurry forming an amorphous poly alpha olefin with a saturated backbone.

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