Purification of alkyl naphthalenes by distillation and furfural extraction
    2.
    发明授权
    Purification of alkyl naphthalenes by distillation and furfural extraction 失效
    通过蒸馏和糠醛萃取纯化烷基萘

    公开(公告)号:US3869357A

    公开(公告)日:1975-03-04

    申请号:US42828573

    申请日:1973-12-26

    CPC classification number: C07C7/005 C07C7/10 C07C15/24

    Abstract: Methylnaphthalenes are obtained from a hydrocarbon mixture boiling within the range of 375* to 600*F containing alkylnaphthalenes and non-naphthalenes by distilling the hydrocarbon mixture to a boiling range of 460*-530*F and then treating this narrow boiling range fraction with a furfural extraction.

    Abstract translation: 通过将烃混合物蒸馏至460〜-530°F的沸程,从含有烷基萘和非萘的沸点在375〜600°F范围内的烃混合物得到甲基萘,然后用 糠醛提取。

    Reaction of peroxides with nitriles
    3.
    发明授权
    Reaction of peroxides with nitriles 失效
    过氧化物与硝酸的反应

    公开(公告)号:US3852349A

    公开(公告)日:1974-12-03

    申请号:US29950872

    申请日:1972-10-20

    Inventor: TURNER J NORTON R

    CPC classification number: C07C231/06

    Abstract: N-alkyl amides may be formed by reacting aliphatic peroxides or hydroperoxides with aliphatic or aromatic nitriles in a solution of a strong acid and an alcohol.

    Abstract translation: N-烷基酰胺可以通过将脂族过氧化物或氢过氧化物与强酸和醇的溶液中的脂族或芳族腈反应而形成。

    Separation of cyclic hydrocarbons with molecular sieve adsorbent
    4.
    发明授权
    Separation of cyclic hydrocarbons with molecular sieve adsorbent 失效
    用分子吸附剂分离循环碳氢化合物

    公开(公告)号:US3840610A

    公开(公告)日:1974-10-08

    申请号:US26337272

    申请日:1972-06-06

    Inventor: HEDGE J

    CPC classification number: C07C7/13 C07C13/573 C07C15/24 C07C15/27 C07C13/547

    Abstract: 1. A PROCESS FOR SEPARATING TWO STRUCTURALLY SIMILAR CYCLIC AROMATIC HYDROCARBONS CONTAINING IN THE RANGE OF 1-4 AROMATIC RINGS, AND IN THE RANGE OF 8-36 CARBON ATOMS AND WHEREIN SAID AROMATIC HYDROCARBONS CONTAIN AT LEAST ONE CONDENSED RING, SAID PROCESS COMPRISING: (A) CONTACTING A FLUID FEED MIXTURE COMPRISING SAID CYCLIC AROMATIC HYDROCARBONS WITH A SOLID ABSORBENT COMPRISING A PARTIALLY DEHYDRATED, SUBSTANTIALLY CRYSTALLINE ALUMINO-SILICATE ZEOLITE HAVING A CRITICAL PORE DIAMETER GREATER THAN ABOUT 6A, THE RATIO AL/SI OF THE ALUMINO- SILICATE FRAMEWORK OF THE ZEOLITE BEING IN THE RANGE OF 0.65-0.2, THE ZEOLITE HAVING BEEN PARTIALLY DEHYDRATED BY EXPOSURE TO A TEMPERATURE IN THE RANGE OF 80-300* C., WHEREBY THERE IS OBTAINED A RICH ADSORBENT CONTAINING AN ADSORBATE WHICH IS RICHER IN ONE SAID CYCLIC AROMATIC HYDROCARBON THAN WAS SAID FLUID FEED MIXTURE, AND A RAFFINATE PRODUCT WHICH CONTAINS LESS OF THE ONE SAID CYCLIC AROMATIC HYDROCARBON THAN DID SAID FLUID FEED MIXTURE; (B) SEPARATING SAID RAFFINATE PRODUCT FROM SAID RICH ADSORBENT AND, (C) REMOVING THE ONE SAID CUCLIC AROMATIC HYDROCARBON FROM SAID RICH ADSORBENT.

    Process for conversion of alkyldecalins and/or alkyltetralins
    5.
    发明授权
    Process for conversion of alkyldecalins and/or alkyltetralins 失效
    转化烷基蒽环辛酸和/或烷基四氢萘酚的方法

    公开(公告)号:US3928482A

    公开(公告)日:1975-12-23

    申请号:US45896274

    申请日:1974-04-08

    CPC classification number: C07C5/2737 C07C5/2708 C07C5/367 C07C13/50 C07C13/48

    Abstract: A process for conversion of a feed consisting essentially of an alkyldecalin or an alkyltetralin (or a non-equilibrium mixture thereof) comprises contacting the feed with an alumino-silicate zeolite containing polyvalent metal cations in exchange positions, the contacting being at a temperature in the range of 100-350*C., liquid hourly space velocity in the range of 0.25 to 10 and a pressure in the range of 15 to 1500 psig.

    Abstract translation: 基本上由烷基茶碱或烷基四氢萘(或其非平衡混合物)组成的饲料的转化方法包括使饲料与含有交换位置的多价金属阳离子的铝硅酸盐沸石接触,接触温度为 范围为100-350℃,液时空速为0.25至10,压力为15至1500psig。

    Ethylene-propylene copolymer oil
    6.
    发明授权
    Ethylene-propylene copolymer oil 失效
    乙烯 - 丙烯共聚物油

    公开(公告)号:US3923919A

    公开(公告)日:1975-12-02

    申请号:US45258274

    申请日:1974-03-19

    Abstract: New ethylene-propylene copolymer oils containing 29-71 mol percent ethylene, the rest being at least substantially entirely propylene, said oils being of rich viscosity index, low pour point, and high stability, are produced from monoolefin mixtures containing ethylene and propylene employing specified vanadiumaluminum or titanium-aluminum Ziegler-type catalyst systems. Hydrogen under pressure is used with the vanadium-aluminum catalyst system to control molecular weight. Oils of lubricating oil viscosity can be produced directly, or after cracking higher molecular weight oil, said cracking usually, but not necessarily, followed by hydrogenating. Dewaxing can be employed to reduce pour point.

    Abstract translation: 含有29-71mol%乙烯的新乙烯 - 丙烯共聚物油,其余至少基本上全部为丙烯,所述油具有富粘度指数,低倾点和高稳定性,由含乙烯和丙烯的单烯烃混合物制成, 钒铝或钛 - 齐格勒型催化剂体系。 压力下的氢气与钒 - 铝催化剂体系一起使用以控制分子量。 润滑油的粘度油可以直接生产,或在裂解较高分子量的油之后,通常开裂,但不一定,然后进行氢化。 脱蜡可用于减少倾点。

    Process for hydrolysis of nitriles
    7.
    发明授权
    Process for hydrolysis of nitriles 失效
    腈水解方法

    公开(公告)号:US3920670A

    公开(公告)日:1975-11-18

    申请号:US40496673

    申请日:1973-10-10

    Inventor: NORTON RICHARD V

    CPC classification number: C07C51/08

    Abstract: A process for the catalytic acid hydrolysis of an aromatic or heterocyclic nitrile to acid by feeding an aqueous solution of the nitrile and acid catalyst to a reflux reactor held at a temperature and pressure to maintain liquid reflux conditions whereby hydrolysis of nitrile occurs and the ammonium salt of the acid catalyst which forms pyrolyzes to amide, distilling off vapors of said catalyst and the amide of said catalyst, and separating from said reactor aromatic acid or heterocyclic acid product in high purity.

    Abstract translation: 通过将腈和酸催化剂的水溶液加入到温度和压力下的回流反应器中将芳族或杂环腈催化酸水解成酸,以保持腈水解,并且铵盐 形成热解为酰胺的酸催化剂,蒸馏所述催化剂的蒸气和所述催化剂的酰胺,并从所述反应器中分离出高纯度的芳族酸或杂环酸产物。

    Preparation of improved motor fuels containing furan antiknocks
    10.
    发明授权
    Preparation of improved motor fuels containing furan antiknocks 失效
    制备含有呋喃抗爆剂的改进的机动燃料

    公开(公告)号:US3909216A

    公开(公告)日:1975-09-30

    申请号:US27186072

    申请日:1972-07-14

    Abstract: The octane rating of gasoline alkylate may be improved by separating therefrom 2,4- and 2,5-dimethylhexanes (''''DMH'''') and subjecting said DMH to the following combination of steps: (1) oxidizing the DMH to form the corresponding hydroperoxides; (2) reacting of the hydroperoxides with propylene to yield the corresponding diols plus propylene oxide; and (3) dehydrating of the diols to produce 2,2,5,5-tetramethyltetrahydrofuran (''''TMTHF''''), which product is then added to the gasoline alkylate, thereby improving its octane rating. In addition, valuable propylene oxide is recovered as a by-product.

    Abstract translation: 汽油烷基化物的辛烷值可以通过与2,4-和2,5-二甲基己烷(“DMH”)分离并使所述DMH进行以下步骤组合来改善:(1)氧化DMH以形成相应的氢过氧化物; (2)氢过氧化物与丙烯的反应,得到相应的二醇和环氧丙烷; 和(3)二醇脱水以产生2,2,5,5-四甲基四氢呋喃(“TMTHF”),然后将该产物加入到烷基化汽油中,从而提高其辛烷值。 此外,作为副产物回收有价值的环氧丙烷。

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