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公开(公告)号：US20110224315A1
公开(公告)日：2011-09-15
申请号：US13111573
申请日：2011-05-19
Applicant: Takashi TERAJIMA , Toshihiro Takai , Hideaki Nakamura
Inventor： Takashi TERAJIMA , Toshihiro Takai , Hideaki Nakamura
CPC classification number: C08F8/40 , B01J31/10 , B01J2231/40 , C07C37/20 , C07C39/16 , C07F9/5442
Abstract: There is provided a modified ion exchange resin catalyst which exhibits higher bisphenols selectivity than the conventional modified ion exchange resins in processes wherein bisphenols are produced by reacting a phenolic compound with ketones, and to provide such a process for producing bisphenols. A modified ion exchange resin is characterized in that at least one compound selected from (A) and (B) shown below is ionically bonded to an acidic functional group of an acidic ion exchange resin: (A) Compound represented by Formula (1) and (B) Compound represented by Formula (2)
Abstract translation: 提供了一种改性离子交换树脂催化剂，其在通过使酚类化合物与酮反应制备双酚的方法中表现出比常规改性离子交换树脂更高的双酚选择性，并提供了制备双酚的方法。 改性离子交换树脂的特征在于，选自下述（A）和（B）中的至少一种化合物与酸性离子交换树脂的酸性官能团离子键合：（A）式（1）表示的化合物和 （B）式（2）表示的化合物
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公开(公告)号：US20110092744A1
公开(公告)日：2011-04-21
申请号：US12981133
申请日：2010-12-29
Applicant: Takashi TERAJIMA , Yuko Maruyama , Toshihiro Takai , Kenji Fujiwara
Inventor： Takashi TERAJIMA , Yuko Maruyama , Toshihiro Takai , Kenji Fujiwara
IPC: C07C39/16
CPC classification number: C07C39/16 , B01J31/10 , B01J2231/347 , C07C37/20 , C08F8/32 , C08F8/36 , C08F12/08 , C08F212/08
Abstract: The present invention provides a process for producing bisphenol A by reacting phenol with actone, wherein reaction is performed at higher temperatures while maintaining high selectivity, and thus high productivity is obtained. The invention relates to a cation-exchange resin, wherein a cation-exchange group is introduced into a syndiotactic polystyrene polymer and the amount of acid is 0.8 milliequivalent/g or more, to a catalyst comprising the cation-exchange resin, and to a process for producing bisphenol A using a cation-exchange resin catalyst.
Abstract translation: 本发明提供了一种通过使酚与活性苯酚反应生产双酚A的方法，其中反应在较高温度下进行，同时保持高选择性，从而获得高生产率。 本发明涉及一种阳离子交换树脂，其中将阳离子交换基团引入间同立构聚苯乙烯聚合物中，并且酸的量为0.8毫当量/ g或更高，对于包含阳离子交换树脂的催化剂以及一种方法 用于使用阳离子交换树脂催化剂生产双酚A.
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公开(公告)号：US20070073091A1
公开(公告)日：2007-03-29
申请号：US10571134
申请日：2004-09-01
Applicant: Takashi Terajima , Yuko Maruyama , Toshihiro Takai , Kenji Fujiwara
Inventor： Takashi Terajima , Yuko Maruyama , Toshihiro Takai , Kenji Fujiwara
IPC: C07C39/16
CPC classification number: C07C39/16 , B01J31/10 , B01J2231/347 , C07C37/20 , C08F8/32 , C08F8/36 , C08F12/08 , C08F212/08
Abstract: The present invention provides a process for producing bisphenol A by reacting phenol with acetone, wherein reaction is performed at higher temperatures while maintaining high selectivity, and thus high productivity is obtained. The invention relates to a cation-exchange resin, wherein a cation-exchange group is introduced into a syndiotactic polystyrene polymer and the amount of acid is 0.8 milliequivalent/g or more, to a catalyst comprising the cation-exchange resin, and to a process for producing bisphenol A using the cation-exchange resin catalyst.
Abstract translation: 本发明提供一种通过苯酚与丙酮反应生产双酚A的方法，其中反应在较高温度下进行，同时保持高选择性，从而获得高生产率。 本发明涉及一种阳离子交换树脂，其中将阳离子交换基团引入间同立构聚苯乙烯聚合物中，并且酸的量为0.8毫当量/ g或更多，对于包含阳离子交换树脂的催化剂以及一种方法 用于使用阳离子交换树脂催化剂生产双酚A.
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公开(公告)号：US4482850A
公开(公告)日：1984-11-13
申请号：US422566
申请日：1982-09-24
Applicant: Masakazu Sonoda , Takashi Terajima , Minoru Ozawa
Inventor： Masakazu Sonoda , Takashi Terajima , Minoru Ozawa
IPC: G11B15/18 , G11B15/20 , G11B15/467 , G11B15/48 , G11B15/54 , H02P3/08 , H02P7/06 , H02P23/00 , H02P3/10
CPC classification number: G11B15/1808 , G11B15/1875 , G11B15/20 , H02P23/16 , H02P23/186 , H02P3/08 , H02P7/06 , G11B15/4673 , G11B15/48 , G11B15/54
Abstract: A control circuit is used during slow or stop-motion playback operation of a video tape device to drive video tape intermittently. In order to avoid errors in the stopping position of the tape, a pulse width modulated (PWM) signal is provided to a motor controller circuit associated with the capstan motor of the video tape device. A frequency signal generator coupled to this motor generates a frequency signal that varies with the capstan motor speed, and this frequency signal is provided to a retrigger monostable multivibrator which generates a PWM signal whose duty ratio changes in proportion to the capstan motor speed. A drive pulse generator and a brake pulse generator provide drive start and brake start signals, respectively, when it is desired to commence and stop movement of the tape. A drive circuit, including the retrigger monostable multivibrator, receives the drive start signal, the brake start signal, and the frequency signal to generate the PWM signal which is supplied to the motor controller circuit. The frequency signal is selected to have a pulse rate several tens of times the ripple frequency of the motor's torque ripple characteristic so that inaccuracies in stopping position of the motor are eliminated.
Abstract translation: 在录像带设备的慢速或停止运动播放操作期间使用控制电路来间歇地驱动视频磁带。 为了避免磁带停止位置的错误，将脉冲宽度调制（PWM）信号提供给与录像带装置的主导轴电机相关联的电机控制器电路。 耦合到该电动机的频率信号发生器产生随主导轴电动机速度而变化的频率信号，并且该频率信号被提供给再触发单稳态多谐振荡器，其产生占空比与主导轴电动机速度成比例地变化的PWM信号。 当需要开始和停止磁带的移动时，驱动脉冲发生器和制动脉冲发生器分别提供驱动启动和制动启动信号。 包括再触发单稳态多谐振荡器的驱动电路接收驱动开始信号，制动开始信号和频率信号，以产生提供给马达控制器电路的PWM信号。 选择频率信号具有电机转矩脉动特性的脉动频率几十倍的脉冲频率，从而消除电机停止位置的不准确。
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公开(公告)号：US20110224461A1
公开(公告)日：2011-09-15
申请号：US13111600
申请日：2011-05-19
Applicant: Takashi TERAJIMA , Toshihiro Takai , Hideaki Nakamura
Inventor： Takashi TERAJIMA , Toshihiro Takai , Hideaki Nakamura
IPC: C07F9/54
CPC classification number: C08F8/40 , B01J31/10 , B01J2231/40 , C07C37/20 , C07C39/16 , C07F9/5442
Abstract: There is provided a modified ion exchange resin catalyst which exhibits higher bisphenols selectivity than the conventional modified ion exchange resins in processes wherein bisphenols are produced by reacting a phenolic compound with ketones, and to provide such a process for producing bisphenols. A modified ion exchange resin is characterized in that at least one compound selected from (A) and (B) shown below is ionically bonded to an acidic functional group of an acidic ion exchange resin: (A) Compound represented by Formula (1) and (B) Compound represented by Formula (2)
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Patent Agency Ranking
公开(公告)号：US20080051480A1
公开(公告)日：2008-02-28
申请号：US11631292
申请日：2005-06-14
Applicant: Takashi Terajima , Toshihiro Takai , Hideaki Nakamura
Inventor： Takashi Terajima , Toshihiro Takai , Hideaki Nakamura
CPC classification number: C08F8/40 , B01J31/10 , B01J2231/40 , C07C37/20 , C07C39/16 , C07F9/5442
Abstract: There is provided a modified ion exchange resin catalyst which exhibits higher bisphenols selectivity than the conventional modified ion exchange resins in processes wherein bisphenols are produced by reacting a phenolic compound with ketones, and to provide such a process for producing bisphenols. A modified ion exchange resin is characterized in that at least one compound selected from (A) and (B) shown below is ionically bonded to an acidic functional group of an acidic ion exchange resin: (A) Compound represented by Formula (1) and (B) Compound represented by Formula (2)
Abstract translation: 提供了一种改性离子交换树脂催化剂，其在通过使酚类化合物与酮反应制备双酚的方法中表现出比常规改性离子交换树脂更高的双酚选择性，并提供了制备双酚的方法。 改性离子交换树脂的特征在于，选自下述（A）和（B）中的至少一种化合物与酸性离子交换树脂的酸性官能团离子键合：（A）式（1）表示的化合物和 （B）式（2）表示的化合物
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公开(公告)号：US08436055B2
公开(公告)日：2013-05-07
申请号：US12875016
申请日：2010-09-02
Applicant: Takashi Terajima , Toshihiro Takai , Kenji Fujiwara
Inventor： Takashi Terajima , Toshihiro Takai , Kenji Fujiwara
IPC: C08J5/20
CPC classification number: B01J31/0239 , B01J31/0268 , B01J31/08 , B01J31/10 , B01J2231/342 , C07C37/20 , Y02P20/52 , C07C39/16
Abstract: The present invention provides an ion-exchange resin catalyst, as a catalyst for preparing bisphenol from phenol compounds and ketone, which has a higher selectivity to bisphenol and a longer life time, as compared to a conventional ion-exchange resin, and a method for preparing the same.The present invention also provides a method for preparing bisphenol comprising reacting phenol compounds with ketone, wherein the modified acidic ion-exchange resin in which at least one kind of cationic compound selected from the following (a), (b), (c) and (d) ionically binds to an acidic functional group, is used as a catalyst: (a) a quaternary phosphonium ion, (b) a quaternary ammonium ion, (c) a bis(phosphoranylidene) ammonium ion, and (d) an N-substituted nitrogen-containing aromatic cation.
Abstract translation: 本发明提供一种离子交换树脂催化剂，作为与常规离子交换树脂相比，具有较高的双酚选择性和较长使用寿命的酚类化合物和酮制备双酚的催化剂， 准备一样 本发明还提供一种制备双酚的方法，其包括使酚化合物与酮反应，其中所述改性酸性离子交换树脂其中至少一种选自以下（a），（b），（c）和 （d）与酸性官能团离子键合，用作催化剂：（a）季鏻离子，（b）季铵离子，（c）双（亚正膦基）铵离子，和（d）N 取代的含氮芳族阳离子。
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公开(公告)号：US08263521B2
公开(公告)日：2012-09-11
申请号：US12981133
申请日：2010-12-29
Applicant: Takashi Terajima , Yuko Maruyama , Toshihiro Takai , Kenji Fujiwara
Inventor： Takashi Terajima , Yuko Maruyama , Toshihiro Takai , Kenji Fujiwara
CPC classification number: C07C39/16 , B01J31/10 , B01J2231/347 , C07C37/20 , C08F8/32 , C08F8/36 , C08F12/08 , C08F212/08
Abstract: The present invention provides a process for producing bisphenol A by reacting phenol with actone, wherein reaction is performed at higher temperatures while maintaining high selectivity, and thus high productivity is obtained. The invention relates to a cation-exchange resin, wherein a cation-exchange group is introduced into a syndiotactic polystyrene polymer and the amount of acid is 0.8 milliequivalent/g or more, to a catalyst comprising the cation-exchange resin, and to a process for producing bisphenol A using a cation-exchange resin catalyst.
Abstract translation: 本发明提供了一种通过使酚与活性苯酚反应生产双酚A的方法，其中反应在较高温度下进行，同时保持高选择性，从而获得高生产率。 本发明涉及一种阳离子交换树脂，其中将阳离子交换基团引入间同立构聚苯乙烯聚合物中，并且酸的量为0.8毫当量/ g或更高，对于包含阳离子交换树脂的催化剂以及一种方法 用于使用阳离子交换树脂催化剂生产双酚A.
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公开(公告)号：US20100324341A1
公开(公告)日：2010-12-23
申请号：US12875016
申请日：2010-09-02
Applicant: Takashi TERAJIMA , Toshihiro Takai , Kenji Fujiwara
Inventor： Takashi TERAJIMA , Toshihiro Takai , Kenji Fujiwara
IPC: C07C39/16
CPC classification number: B01J31/0239 , B01J31/0268 , B01J31/08 , B01J31/10 , B01J2231/342 , C07C37/20 , Y02P20/52 , C07C39/16
Abstract: The present invention provides an ion-exchange resin catalyst, as a catalyst for preparing bisphenol from phenol compounds and ketone, which has a higher selectivity to bisphenol and a longer life time, as compared to a conventional ion-exchange resin, and a method for preparing the same.The present invention also provides a method for preparing bisphenol comprising reacting phenol compounds with ketone, wherein the modified acidic ion-exchange resin in which at least one kind of cationic compound selected from the following (a), (b), (c) and (d) ionically binds to an acidic functional group, is used as a catalyst: (a) a quaternary phosphonium ion, (b) a quaternary ammonium ion, (c) a bis(phosphoranylidene) ammonium ion, and (d) an N-substituted nitrogen-containing aromatic cation.
Abstract translation: 本发明提供一种离子交换树脂催化剂，作为与常规离子交换树脂相比，具有较高的双酚选择性和较长使用寿命的酚类化合物和酮制备双酚的催化剂， 准备一样 本发明还提供一种制备双酚的方法，其包括使酚化合物与酮反应，其中所述改性酸性离子交换树脂其中至少一种选自以下（a），（b），（c）和 （d）与酸性官能团离子键合，用作催化剂：（a）季鏻离子，（b）季铵离子，（c）双（亚正膦基）铵离子，和（d）N 取代的含氮芳族阳离子。
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公开(公告)号：US5631338A
公开(公告)日：1997-05-20
申请号：US499904
申请日：1995-07-11
Applicant: Kaoru Inoue , Tuneyuki Ohkubo , Takashi Terajima
Inventor： Kaoru Inoue , Tuneyuki Ohkubo , Takashi Terajima
CPC classification number: C08G77/392 , B01J31/10 , B01J31/124 , C07C37/20 , B01J2231/347
Abstract: The present invention provides a process for preparing bisphenol A with a high conversion and selectivity by reacting phenol with acetone in the presence of both a polyorganosiloxane having a mercapto group-containing hydrocarbon group and an acid. It is preferable that the polyorganosiloxane having a mercapto group-containing hydrocarbon group and the acid is a polyorganosiloxane having both a mercapto group-containing hydrocarbon group and a sulfonic acid group.
Abstract translation: 本发明提供了在具有含巯基的烃基的聚有机硅氧烷和酸的存在下，通过苯酚与丙酮反应制备具有高转化率和选择性的双酚A的方法。 优选具有含巯基的烃基的聚有机硅氧烷和酸是具有含巯基的烃基和磺酸基的聚有机硅氧烷。
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