Silicon carbide articles reinforced with short graphite fibers
    9.
    发明授权
    Silicon carbide articles reinforced with short graphite fibers 失效
    用短石墨纤维增强的碳化硅制品

    公开(公告)号:US06030913A

    公开(公告)日:2000-02-29

    申请号:US26347

    申请日:1998-02-19

    CPC classification number: F16D69/023 C04B35/573 C04B35/806 F16D2200/0047

    Abstract: A composite material article reinforced with high strength short graphite fibers and having a matrix substantially consisting of silicon carbide is prepared which has an elongation at break of 0.25 to 0.5% and thus exhibits quasi-ductile failure behavior. The short reinforcing graphite fibers are enclosed by at least two shells of graphitized carbon which have been obtained by impregnation with carbonizable impregnating agents and subsequent carbonization. The shell closest to the graphite fibers contains no cracks. The outermost shell is partially converted into silicon carbide. The starting material used comprises long or short fiber prepregs, which are first carbonized, then subjected at least once to an operation consisting of impregnation with a carbonizable impregnating agent and recarbonization, then graphitized at a temperature of up to maximum of 2400.degree. C. and then comminuted to yield a dry material for the production of a precursor article. This dry material is then mixed with a binder having a high carbon content and the mixture is compression molded to yield a green article. The green molding is then carbonized and afterwards infiltrated with liquid silicon, with the carbon matrix of the carbonized precursor article being converted into silicon carbide.

    Abstract translation: 制备用高强度短石墨纤维增强并具有基本上由碳化硅组成的基体的复合材料制品,其具有0.25至0.5%的断裂伸长率,因此显示出准韧性破坏行为。 短的增强石墨纤维被至少两个石墨化碳壳包围,这些石墨化碳通过用可碳化浸渍剂浸渍并随后进行碳化而获得。 最靠近石墨纤维的壳体不含裂纹。 最外壳被部分转化为碳化硅。 使用的起始原料包括长纤维或短纤维预浸料,其首先被碳化,然后至少进行一次操作,其中包括用可碳化浸渍剂的浸渍和再碳化,然后在最高达2400℃的温度下石墨化, 然后粉碎以产生用于制备前体制品的干材料。 然后将该干燥材料与具有高碳含量的粘合剂混合,并将该混合物压塑以产生绿色制品。 然后将绿色模制品碳化,然后用液态硅渗透,碳化前体制品的碳基体转化为碳化硅。

    METHOD FOR REMOVING ACROLEIN FROM THE PROCESS GAS OF A HETEROGENEOUSLY CATALYSED OXIDATION OF PROPENE
    10.
    发明申请
    METHOD FOR REMOVING ACROLEIN FROM THE PROCESS GAS OF A HETEROGENEOUSLY CATALYSED OXIDATION OF PROPENE 有权
    从丙烯异构体催化氧化过程气体中除去丙烯的方法

    公开(公告)号:US20150353460A1

    公开(公告)日:2015-12-10

    申请号:US14762124

    申请日:2014-01-28

    CPC classification number: C07C45/35 C07C45/78 C07C45/783 C07C45/82 C07C47/22

    Abstract: The invention relates to a process for separating acrolein from the process gas of a heterogeneously catalysed oxidation of propene by means of atmospheric oxygen, wherein high boilers (including acrylic acid) are firstly separated off from the process gas by means of quenching and technical-grade acrolein having small proportions of low boilers is then obtained by means of absorption and subsequent distillation. Small amounts of a solvent by means of which, in particular, oligomers formed are separated off and the tendency for foam to be formed in the apparatuses or columns is reduced is added in the columns and heat exchangers in the work-up process. The solvent is, according to the invention, separated off and recycled in the form of an organic phase in-situ within the existing process.

    Abstract translation: 本发明涉及一种通过大气氧从异丙烯催化的丙烯氧化的工艺气体中分离出丙烯醛的方法,其中高沸点(包括丙烯酸)首先通过淬火和技术级分离工艺气体 然后通过吸收和随后的蒸馏获得具有小比例的低锅炉的丙烯醛。 在后处理过程中,在塔和热交换器中加入少量的溶剂,特别是所形成的低聚物被除去,并且在装置或塔中形成泡沫的趋势被减少。 根据本发明,溶剂在现有方法中分离并以有机相的形式在原位再循环。

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