DIFLUOROMETHYLATION REACTION OF HETEROCYCLIC RING USING TETRAFLUOROETHYLENE

    公开(公告)号:US20240199553A1

    公开(公告)日:2024-06-20

    申请号:US18438086

    申请日:2024-02-09

    Applicant: AGC INC.

    CPC classification number: C07D215/12

    Abstract: A method for producing a difluoromethyl-substituted aromatic heterocyclic compound having a partial structure represented by the formula (Ia):




    The method includes reacting an N-oxido aromatic heterocyclic compound having a partial structure represented by the formula (Ia):




    with tetrafluoroethylene in a presence of a base, in a solvent selected from an aromatic hydrocarbon solvent, an ester solvent and an ether solvent.

    METHOD FOR PRODUCING FLUORINE-CONTAINING COMPOUND AND METHOD FOR PRODUCING SURFACE TREATMENT AGENT

    公开(公告)号:US20230407004A1

    公开(公告)日:2023-12-21

    申请号:US18456128

    申请日:2023-08-25

    Applicant: AGC Inc.

    CPC classification number: C08G65/337 C08G65/336 C09K3/18

    Abstract: An object is to provide a method for producing a fluorine-containing compound by using an easily available compound under relatively mild reaction conditions to produce a fluorine-containing compound, and a method for producing a surface treatment agent using the fluorine-containing compound obtained by the production method.
    A method for producing a fluorine-containing compound represented by the following formula (C1) or (C2), the method including: reacting a compound represented by the following formula (A1) or (A2) with a compound represented by the following formula (B1) or (B2).


    G1-L1-CR1R2—X1  Formula (A1)



    X2—CR3R4-L2-G2-L3-CR5R6—X2  Formula (A2)



    R11—ZnR12  Formula (B1)



    R11—BR13R14  Formula (B2)



    G1-L1-CR1R2—R11  Formula (C1)



    R11—CR3R4-L2-G2-L3-CR5R6—R11  Formula (C2)



    where, each reference sign in the formula is as described in the specification.

    METHOD FOR PRODUCING FLUORINE-CONTAINING COMPOUND AND METHOD FOR PRODUCING SURFACE TREATMENT AGENT

    公开(公告)号:US20230399471A1

    公开(公告)日:2023-12-14

    申请号:US18455768

    申请日:2023-08-25

    Applicant: AGC Inc.

    CPC classification number: C08G77/24 B01J23/72

    Abstract: An object is to provide a method for producing a fluorine-containing compound by using an easily available compound under relatively mild reaction conditions to produce a fluorine-containing compound, and a method for producing a surface treatment agent using the fluorine-containing compound obtained by the production method.
    A method for producing a fluorine-containing compound represented by the following formula (C1) or (C2), the method including: reacting a compound represented by the following formula (A1) or (A2) with a compound represented by the following formula (B1).


    G1-L1-CR1R2—X1  Formula (A1)



    X2—CR3R4-L2-G2-L3-CR5R6—X3  Formula (A2)



    R11—MgR12  Formula (B1)



    G1-L1-CR1R2—R11  Formula (C1)



    R11—CR3R4-L2-G2-L3-CR5R6—R11  Formula (C2)



    where, each reference sign in the formula is as described in the specification.

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