公开(公告)号：US20130266815A1

公开(公告)日：2013-10-10

申请号：US13859100

申请日：2013-04-09

Applicant: ARKEMA FRANCE

Inventor： James P. Horgan ,  Jeffrey A. Klang ,  Yuhong He ,  James Goodrich

IPC: C09D133/14

CPC classification number: C09D133/14 ,  C07F7/1804 ,  C08F230/08 ,  C08L2312/08 ,  C09D143/04 ,  Y10T428/31663

Abstract: The present invention includes silicon-containing (meth)acrylate compounds of formula (I) where A is a C1-C12 organic moiety such as an alkyl or aryl moiety, B is a silane functional group, C is a (meth)acrylate functional group and D is an allyl functional group, with w=0 or 1, z=0, 1 or 2, x=1, 2 or 3, y=1, 2 or 3 and w+x+y+z=4. The compounds are suitable for use in curable compositions, such as peroxide-curable compositions or radiation-curable compositions and may be applied to a substrate as a coating or sealant, for example. Compositions containing the silicon-containing (meth)acrylate compounds may have reduced volatility and odor problems along with improved adhesion to substrates, increased crosslink density and/or improved hardness.

Abstract translation: 本发明包括式（I）的含硅（甲基）丙烯酸酯化合物，其中A是C 1 -C 12有机部分如烷基或芳基部分，B是硅烷官能团，C是（甲基）丙烯酸酯官能团 并且D是烯键式官能团，其中w = 0或1，z = 0,1或2，x = 1,2或3，y = 1,2或3，w + x + y + z = 4。 该化合物适用于可固化组合物，例如过氧化物可固化组合物或可辐射固化的组合物，并且可以例如作为涂层或密封剂施用于基材。 包含含硅（甲基）丙烯酸酯化合物的组合物可能具有降低的挥发性和气味问题，同时改善对基材的粘附性，增加的交联密度和/或改善的硬度。

公开(公告)号：US09695331B2

公开(公告)日：2017-07-04

申请号：US13859100

申请日：2013-04-09

Applicant: Arkema France

Inventor： James P. Horgan ,  Jeffrey A. Klang ,  Yuhong He ,  James Goodrich

IPC: C07F7/18 ,  C09D133/14 ,  C08F230/08 ,  C09D143/04

CPC classification number: C09D133/14 ,  C07F7/1804 ,  C08F230/08 ,  C08L2312/08 ,  C09D143/04 ,  Y10T428/31663

Abstract: The present invention includes silicon-containing (meth)acrylate compounds of formula (I): where A is a C1-C12 organic moiety such as an alkyl or aryl moiety, B is a silane functional group, C is a (meth)acrylate functional group and D is an allyl functional group, with w=0 or 1, z=0, 1 or 2, x=1, 2 or 3, y=1, 2 or 3 and w+x+y+z=4. The compounds are suitable for use in curable compositions, such as peroxide-curable compositions or radiation-curable compositions and may be applied to a substrate as a coating or sealant, for example. Compositions containing the silicon-containing (meth)acrylate compounds may have reduced volatility and odor problems along with improved adhesion to substrates, increased crosslink density and/or improved hardness.