公开(公告)号：US3862944A

公开(公告)日：1975-01-28

申请号：US25203172

申请日：1972-05-10

Applicant: BASF AG

Inventor： EILINGSFELD HEINZ ,  SCHWANTJE GERD

IPC: C09B5/16 ,  C07D51/46

CPC classification number: C09B5/16

Abstract: New dyes of the formula:

IN WHICH TWO OF THE GROUPS X are hydroxyl and the third X is unsubstituted or substituted alkylamino, unsubstituted or substituted phenylamino, phenylthio, aliphatic, cycloaliphatic or aromatic acylamino or N''-alkylureido for dyeing synthetic material. Dyeings obtained therewith have good fastness properties. The invention relates to new dyes based on anthrapyrimidines for synthetic fibers.

Abstract translation: 新染料的配方：

公开(公告)号：US3906012A

公开(公告)日：1975-09-16

申请号：US41256273

申请日：1973-11-05

Applicant: BASF AG

Inventor： SCHUHMACHER ALFRED ,  SCHWANTJE GERD

IPC: C07C67/00 ,  C07C231/00 ,  C07C231/02 ,  C07C235/84 ,  C07C237/30 ,  C07C237/48 ,  C07D265/12 ,  C09B1/22 ,  C09B1/28 ,  C07C103/75 ,  C09B1/36

CPC classification number: C07D265/12 ,  C09B1/22 ,  C09B1/28

Abstract: Production of amides of 1-aminoanthraquinone-2-carboxylic acid which bear hydrogen, cyclohexylamino, chloro, bromo or nitro as substituent in the 4-position by reaction of 1,2-dihydro-7,8diphthaloyl-3,1,4H-benzoxazone-4:

IN WHICH R2 is H, Cl, Br, NH-cyclohexyl or NO2, with an aliphatic or cycloaliphatic amine of one to eight carbon atoms in the molar ratio 1:1. Some of the amides are disperse dyes but particularly they are intermediates for the production of disperse dyes.

Abstract translation: 通过1,2-二氢-7,8-二邻苯二甲酰基-3,1,4H的反应制备在4-位上带有氢，环己基氨基，氯，溴或硝基作为取代基的1-氨基蒽醌-2-羧酸的酰胺 苯并恶嗪-4：

公开(公告)号：US3867406A

公开(公告)日：1975-02-18

申请号：US36649873

申请日：1973-06-04

Applicant: BASF AG

Inventor： SCHWANTJE GERD

IPC: C07D209/48 ,  C09B1/51 ,  C09B1/514 ,  C07D27/00 ,  C07D27/52

CPC classification number: C09B1/51

Abstract: A disperse dye of the formula (I):

in which ONE X is OH and the other X is NH2; and R is hydrogen, cycloalkyl, phenyl or alkyl which may bear hydroxyl or alkoxy as a substitutent. It dyes linear polyesters deep bluish green hues of outstanding fastness properties.

Abstract translation: 式（I）的分散染料：

公开(公告)号：US3887591A

公开(公告)日：1975-06-03

申请号：US41242173

申请日：1973-11-02

Applicant: BASF AG

Inventor： ELSER WOLFGANG ,  SCHWANTJE GERD

IPC: C07C227/12 ,  C07C229/74 ,  C07D265/12 ,  C09B1/22

CPC classification number: C09B1/22 ,  C07D265/12

Abstract: The production of 1-amino-4-nitroanthraquinone-2-carboxylic esters by reaction of 1,2-dihydro-6-nitro-7,8-diphthaloyl-3,1,4Hbenzoxazone-4 with an alcohol in the presence of an acid catalyst. Pure carboxylic esters are immediately obtained in a high yield previous isolation of the carboxylic acid.

Abstract translation: 通过1,2-二氢-6-硝基-7,8-二邻苯二甲酰基-3,1,4H-苯并恶嗪-4与醇在存在下反应生产1-氨基-4-硝基蒽醌-2-羧酸酯 酸催化剂。 立即以高产率先前分离羧酸得到纯羧酸酯。

公开(公告)号：US3886188A

公开(公告)日：1975-05-27

申请号：US39917473

申请日：1973-09-20

Applicant: BASF AG

Inventor： SCHUHMACHER ALFRED ,  SCHWANTJE GERD

IPC: C07C227/12 ,  C07C20060101 ,  C07C229/74 ,  C09B1/22

CPC classification number: C09B1/22

Abstract: An improvement in the process for the production of 1-amino-4nitroanthraquinone-2-carboxylic acid from 1-aminoanthraquinone-2carboxylic acid by reaction with formaldehyde in concentrated sulfuric acid and nitration of the reaction product into 1,2dihydro-6-nitro-7,8-diphthaloyl-3,1,4H-benzoxazone-4 followed by hydrolysis of the same. The improvement consists in precipitating the benzoxazone derivative by adding a precipitant, hydrolyzing the isolated benzoxazone derivative in aqueous solution and precipitating the 1-amino-4-nitro-anthraquinone-2-carboxylic acid from the alkaline solution by acidification. 1-amino-4nitroanthraquinone-2-carboxylic acid is obtained in a purity of 95 percent by weight or more.

Abstract translation: 通过在浓硫酸中与甲醛反应，由1-氨基蒽醌-2-羧酸生产1-氨基-4-硝基蒽醌-2-羧酸的方法的改进，并将反应产物硝化成1,2-二氢 -6-硝基-7,8-二邻苯二甲酰基-3,1,4H-苯并恶嗪-4，然后水解。 改进在于通过添加沉淀剂沉淀苯并恶嗪衍生物，水解分离的苯并恶嗪衍生物并通过酸化从碱性溶液中沉淀出1-氨基-4-硝基 - 蒽醌-2-羧酸。 得到纯度为95重量％以上的1-氨基-4-硝基蒽醌-2-羧酸。