Polyisobutenyl ethers and thioethers
    2.
    发明申请
    Polyisobutenyl ethers and thioethers 失效
    聚异丁烯基醚和硫醚

    公开(公告)号:US20040102653A1

    公开(公告)日:2004-05-27

    申请号:US10698457

    申请日:2003-11-03

    CPC classification number: C08G81/021 C08F8/00 C08F110/10

    Abstract: A process for preparing polyisobutenyl (thio)ethers by reacting a polyisobutene epoxide having at least one terminal epoxide group with itself, with other epoxides and/or with nucleophiles selected from among alcohols and thiols in the presence of a Lewis-acid compound as catalyst and/or a cationic photoinitiator with illumination is described. The side reaction of the rearrangement of the epoxide to the polyisobutenyl aldehyde is suppressed. In addition, a curable composition comprising a polyisobutene epoxide, an epoxide different therefrom and optionally a poly(thi)ol is also described.

    Abstract translation: 通过使具有至少一个末端环氧基团的聚异丁烯环氧化物自身与其它环氧化物和/或与路易斯酸化合物作为催化剂存在下的选自醇和硫醇的亲核试剂反应来制备聚异丁烯基(硫代)醚的方法,以及 /或具有照明的阳离子光引发剂。 环氧化物与聚异丁烯醛的重排的副反应被抑制。 此外,还描述了包含聚异丁烯环氧化物,与其不同的环氧化物和任选的聚(硫醇)的可固化组合物。

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