公开(公告)号：US20130196224A1

公开(公告)日：2013-08-01

申请号：US13752936

申请日：2013-01-29

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Jin Yong Kim ,  Guosheng Li ,  Xiaochuan Lu ,  Vincent L. Sprenkle ,  John P. Lemmon ,  Zhenguo Yang ,  Christopher A. Coyle

IPC: H01M10/0563

CPC classification number: H01M10/0563 ,  C01F7/002 ,  C01P2006/40 ,  H01M10/399 ,  H01M2300/0048 ,  H01M2300/0057

Abstract: Sodium metal-halide energy storage devices utilizing a substituting salt in its secondary electrolyte can operate at temperatures lower than conventional ZEBRA batteries while maintaining desirable performance and lifetime characteristics. According to one example, a sodium metal-halide energy storage device operates at a temperature less than or equal to 200° C. and has a liquid secondary electrolyte having MxNa1-yAlCl4-yHy, wherein M is a metal cation of a substituting salt, H is an anion of the substituting salt, y is a mole fraction of substituted Na and Cl, and x is a ratio of y over r, where r is the oxidation state of M. The melting temperature of the substituting salt is less than that of NaCl.

Abstract translation: 在其二次电解质中使用取代盐的金属卤化物储能装置可以在比常规ZEBRA电池低的温度下工作，同时保持期望的性能和寿命特性。 根据一个实例，钠金属卤化物能量储存装置在小于或等于200℃的温度下工作，并具有具有MxNa1-yAlCl4-yHy的液体二次电解质，其中M是取代盐的金属阳离子， H是取代盐的阴离子，y是取代的Na和Cl的摩尔分数，x是y与r的比值，其中r是M的氧化态。取代盐的熔融温度小于 的NaCl。