公开(公告)号：US3829455A

公开(公告)日：1974-08-13

申请号：US34116173

申请日：1973-03-14

Applicant: BERGER A ,  WILKUS E

Inventor： WILKUS E ,  BERGER A

IPC: A61K8/893 ,  A61Q13/00 ,  A61Q19/00 ,  C07F7/08 ,  C07F7/12 ,  C07F7/10

CPC classification number: A61K8/893 ,  A61Q13/00 ,  A61Q19/00 ,  C07F7/0812 ,  C07F7/0818 ,  C07F7/0834 ,  C07F7/0852 ,  C07F7/0856 ,  C07F7/12

Abstract: ONE CLASS OF ORGANOSILICON MATERIALS ARE PROVIDED HAVING CHEMICALLY COMBINED.

*SI-R"-CO-Q

UNITS, WHERE R" IS A DIVALENT HYDROCARBON RADICAL AND Q IS A RADICAL SELECTED FROM ARYLOXYARYL, ARYLTHIOANYL, ARYLSULFONYLARYL, AND CERTAIN HETEROAROMATIC RADICALS. IN ADDITION, ORGANOSILICON POLYMERS AND COPOLYMERS ARE PROVIDED HAVING CHEMICALLY COMBINED.
UNITS, WHERE Q'' IS A RADICAL SELECTED FROM Q RADICALS, NONVALENT AROMATIC HYDROCARBON RADICALS AND HALOGENATED MONOVALENT AROMATIC HYDROCARBON RADICALS. THE MONOMERS AND POLYMERS CAN BE EMPLOYED AS PERFUM OIL BASES, IN COSMETICS AND AS FLUIDS IN THE MANUFACTURE OF ELASTOMERS AND RESINS.

*SI-R"-CO-Q''

公开(公告)号：US3773817A

公开(公告)日：1973-11-20

申请号：US3773817D

申请日：1972-12-20

Applicant: BERGER A ,  SELIN T

Inventor： BERGER A ,  SELIN T

IPC: C03C25/40 ,  C07F7/12 ,  C07F7/18 ,  C08G77/38 ,  C07F7/08 ,  C07F7/10

CPC classification number: C08G77/38 ,  C03C25/40 ,  C07F7/12 ,  C07F7/182 ,  C07F7/1836

Abstract: SILYL MALEATES AND FUMARATES AND POLYSILOXANE MALEATES AND FUMARATES USEFUL AS GLASS SIZING AGENTS ARE PREPARED IN ACCORDANCE WITH THE PRESENT INVENTION. THE SILYL MALEATES AND POLYSILOXANE MALEATES AND FUMARATES ARE FORMED BY REACTING EITHER THE CIS-OR TRANS-1,2-BIS-CARBALKOXYETHYLENES HAVING AN UNSATURATED ALKENYL GROUP THEREIN WITH HYDROGEN SILANE OR HYDROGEN POLYSILOXANE IN THE PRESENCE OF A PLATINUM CATALYST.

公开(公告)号：US3745129A

公开(公告)日：1973-07-10

申请号：US3745129D

申请日：1971-08-27

Applicant: BROWN E ,  BERGER A

Inventor： BROWN E ,  BERGER A

IPC: C07F17/02 ,  C08G77/22 ,  C08G77/26 ,  C10L1/28 ,  C10M169/00 ,  C10M1/50

CPC classification number: C08G77/22 ,  C07F17/02 ,  C08G77/26 ,  C10L1/285 ,  C10M3/00 ,  C10M2227/04 ,  C10M2229/02 ,  C10M2229/041 ,  C10M2229/05 ,  C10M2229/052 ,  C10N2210/03 ,  C10N2210/04 ,  C10N2210/05 ,  C10N2210/06 ,  C10N2210/07 ,  C10N2210/08

Abstract: SILYLORGANOMETALLOCENES SELECTED FROM THE CLASS OF: (A) POLYMERS OF THE FORMULA,

S-W-R"-SI(-R)A-O((3-A)/2)

(B) COPOLYMERS HAVING UNITS OF THE FORMULA,

(R)B-SIO((4-B)/2)

AND AT LEAST ONE UNIT OF (A), AND (C) DISILOXANES OF THE FORMULA,

(S-W-R"(R)2SI)20

WHERE R IS A MONOVALENT HYDROCARBON RADICAL, W IS A CARBAMYL RADICAL, R" IS A DIVALENT HYDROCARBON RADICAL AND S IS AN ORGANOMETALLOCENE OF THE FORMULA,

-(C5Q4)M(C5Q5)

WHERE Q IS SELECTED FROM HYDROGEN, AN ELECTRON DONATING ORGANIC RADICAL, AND AN ELECTRON WITHDRAWING ORGANIC RADICAL AND M IS A TRANSITION METAL, A IS A WHOLE NUMBER EQUAL FROM 0 TO 2 AND B IS A WHOLE NUMBER EQUAL FROM 0 TO 3. THESE SILYLORGANOMETALLOCENES ARE USEFUL AS ANTIOXIDANTS FOR ORGANOPOLYSILOXANE FLUIDS UNDER EXTREME OXIDATION CONDITIONS.

公开(公告)号：US3816494A

公开(公告)日：1974-06-11

申请号：US32498973

申请日：1973-01-18

Applicant: BERGER A

Inventor： BERGER A

IPC: C02F1/54 ,  C07F7/18 ,  C08J5/08 ,  C07F7/10

CPC classification number: C02F1/545 ,  C07F7/1804 ,  C08J5/08

Abstract: A NOVEL CLASS OF SILICONE COMPOUNDS OF THE FORMULA,

(R1-O-)(3-A)-SI(-R)A-(CH(-R16))H-N
CH(-R15)-CH(-R14)-)

WHEREIN R, R1, R16, R12, R13, R14 AND R15 ARE SELECTED FROM HYDROGEN AND HYDROCARBON RADICALS, WHILE M IS SELECTED FROM SULFONE AND KETONE GROUPS, H IS A WHOLE NUMBER THAT VARIES FROM 2 TO 20 AND A IS A WHOLE NUMBER THAT VARIES FROM 0 TO 2. THIS NOVEL CLASS OF COMPOUNDS ARE USEFUL AS FLOCCULENTS FOR COLLOIDAL ORGANIC MATTER, AS INGREDIENTS FOR DETERGENT RESISTANT POLISHES AND AS BONDING AGENTS FOR BONDING VARIOUS PLASTIC RESINS AND RUBBER TO GLASS FIBERS AND OTHER TYPES OF GLASS MATERIAL.

公开(公告)号：US3726938A

公开(公告)日：1973-04-10

申请号：US3726938D

申请日：1971-11-16

Applicant: BERGER A

Inventor： BERGER A

IPC: C07C11/02 ,  C07C3/62

CPC classification number: C07C11/02 ,  C07C5/2506 ,  C07C6/04

Abstract: Ethylene is converted to linear monoolefins of a selected range of carbon atoms by (1) oligomerizing ethylene to linear Alpha olefins (2) separating the linear Alpha -olefins into a lower Alpha -olefin fraction, and intermediate Alpha -olefin fraction of a selected range of carbon atoms and a higher Alpha -olefin fraction (3) recovering the intermediate Alpha -olefin fraction as product (4) isomerizing and disproportionating at least a portion of the lower and higher Alpha -olefin fractions to a mixture of monoolefins (5) separating the mixture of monoolefins into a lower monoolefin fraction, an intermediate monoolefin fraction of a selected range of carbon atoms and a higher monoolefin fraction (6) recovering the second intermediate monoolefin fraction as product, and (7) recycling at least a portion of the lower and higher monoolefin fractions for further isomerization and disproportionation.

Abstract translation: 乙烯通过（1）将乙烯低聚成直链α-烯烃（2）将线性α-烯烃分离成低级α-烯烃部分和选择的α-烯烃级分的中间体α-烯烃级分将其转化成选定范围的碳原子的直链单烯烃 碳原子的范围和较高的α-烯烃级分（3），回收中间体α-烯烃部分作为产物（4）将至少一部分低级和高级α-烯烃部分异构化和歧化成单烯烃（5）的混合物， 将单烯烃的混合物分离成低级单烯烃馏分，选定范围的碳原子的中间单烯烃部分和高级单烯烃馏分（6），回收第二中间单烯烃馏分作为产物，和（7）回收至少一部分 较低和较高的单烯烃部分进一步异构化和歧化。