公开(公告)号：US20150291719A1

公开(公告)日：2015-10-15

申请号：US14746142

申请日：2015-06-22

Applicant: Bridgestone Corporation

Inventor： Xiaorong Wang ,  Hideki Kitano ,  James Herman Pawlow ,  Christopher G. Robertson ,  Yaohong Chen ,  Yuan-Yong Yan

IPC: C08F279/02 ,  C08L9/06

CPC classification number: C08F279/02 ,  C08F297/046 ,  C08L9/06 ,  C08L21/00 ,  C08L2205/03 ,  C08L2207/53 ,  C08L7/00 ,  C08L9/00 ,  C08L53/00 ,  C08L53/02

Abstract: Compositions and methods are included for preparing a hairy polymeric nanoparticle including first and second shell block polymer arms are at least partially phase-separated and surround a polymeric core. One type of polymeric arm can have a greater polarity than the other type(s) of polymeric arms. A rubber composition including the hairy nanoparticles is also provided.

Abstract translation: 包括用于制备毛发聚合物纳米颗粒的组合物和方法，包括第一和第二壳嵌段聚合物臂至少部分地相分离并且围绕聚合物芯。 一种类型的聚合物臂可以具有比其它类型的聚合物臂更大的极性。 还提供了包含毛状纳米颗粒的橡胶组合物。

公开(公告)号：US09631056B2

公开(公告)日：2017-04-25

申请号：US14499895

申请日：2014-09-29

Applicant: Bridgestone Corporation

Inventor： Yaohong Chen ,  Mindaugas Rackaitis ,  Xiaorong Wang ,  Hideki Kitano

IPC: C08L9/06 ,  C08G81/02 ,  B60C1/00 ,  C08F287/00 ,  C08G77/442 ,  C08K3/04 ,  C08K3/36 ,  C08K5/548 ,  C08L51/00

CPC classification number: C08G81/025 ,  B60C1/0016 ,  C08F287/00 ,  C08G77/442 ,  C08K3/04 ,  C08K3/36 ,  C08K5/548 ,  C08L9/06 ,  C08L51/00 ,  Y10S525/902 ,  Y10S977/773 ,  Y10T428/2989

Abstract: A method is provided for synthesizing a core-shell nanoparticle that includes the following steps: providing a polymeric seed (in a solvent) that includes mono-vinyl monomer cross-liniked with a cross-linking agent to form the core of the nanoparticle, the core has an average diameter of from about nanometers to about 10,000 nanometers, and the core has polymer chains with living ends; adding a stabilizer to stabilize the seed and prevent the seed from precipitating out of solution; and grafting a shell species onto the living ends of the core to form the shell of the nanoparticle. A core-first synthesized nanoparticle, along with a rubber composition and tire product are also provided.

公开(公告)号：US20140096882A1

公开(公告)日：2014-04-10

申请号：US14118933

申请日：2012-05-29

Applicant: KURARAY CO., LTD. ,  BRIDGESTONE CORPORATION

Inventor： Hideki Kitano ,  Tetsuo Amamoto ,  Takatsugu Tanaka ,  Yuwa Takahashi ,  Nahoto Hayashi ,  Masao Hikasa ,  Yusuke Tanaka

IPC: B60C5/14 ,  B32B25/14 ,  B32B25/12 ,  B32B25/08

CPC classification number: B60C5/14 ,  B32B1/00 ,  B32B25/08 ,  B32B25/12 ,  B32B25/14 ,  B32B27/16 ,  B32B27/302 ,  B32B27/306 ,  B32B27/322 ,  B32B27/34 ,  B32B27/36 ,  B32B27/40 ,  B32B2250/42 ,  B32B2274/00 ,  B32B2307/7244 ,  B60C1/0008 ,  B60C2005/145 ,  C08L7/00 ,  C08L21/00 ,  Y10T428/2495 ,  Y10T428/269 ,  Y10T428/31504 ,  Y10T428/31826 ,  Y10T428/31931 ,  C08L23/28

Abstract: To provide a multilayer structure that may adhere to rubber material without the necessity of providing an adhesive layer, an inner liner and a pneumatic tire using the multilayer structure. According to the present invention, a multilayer structure 1 is formed by alternately laminating elastomer layers 3 containing thermoplastic elastomer and barrier layers 2 containing a gas barrier resin, wherein an outermost layer 4 laminated uppermost among layers constituting the multilayer structure 1 contains an elastomer component that may heat-adhere to diene rubber.

Abstract translation: 提供可以粘附到橡胶材料而不需要提供粘合剂层的多层结构，内衬和使用该多层结构的充气轮胎。 根据本发明，通过交替层叠含有热塑性弹性体的弹性体层3和含有阻气性树脂的阻隔层2，形成多层结构体1，其中，构成多层结构体1的层中最上层的最外层4含有弹性体成分， 可以热粘附到二烯橡胶上。

公开(公告)号：US20150125685A1

公开(公告)日：2015-05-07

申请号：US14397225

申请日：2013-05-02

Applicant: BRIDGESTONE CORPORATION

Inventor： Hideki Kitano ,  Hideyuki Chiashi ,  Tetsuo Amamoto

IPC: C09D109/00 ,  C09D109/06

CPC classification number: C09D109/00 ,  B32B25/08 ,  B32B25/12 ,  B32B27/306 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B2264/102 ,  B32B2264/108 ,  B32B2433/02 ,  B32B2605/08 ,  C08C19/06 ,  C08C19/08 ,  C08J5/18 ,  C08J2300/26 ,  C08J2309/00 ,  C08J2309/06 ,  Y10T428/269 ,  C08L21/00 ,  C08L7/00 ,  C08L15/00 ,  C08L91/00 ,  C08K3/04 ,  C08K2003/2296 ,  C08K5/09 ,  C08K5/548 ,  C08K3/06 ,  C08L9/00 ,  C08K3/36

Abstract: The present invention provides a rubber sheet having a thickness of 500 μm or less, wherein a rubber component in a rubber composition to constitute the rubber sheet contains a liquid elastomer having a weight-average molecular weight of from 500 to 100000, and a method for producing a rubber sheet having a thickness of 500 μm or less, which includes a step (A) of forming a film of a rubber composition not containing an organic compound having a boiling point not higher than 150° C., on a substrate sheet at a temperature at which the viscosity of the rubber composition falls within a range of from 10 to 100000 mPa·s. Using the specific liquid elastomer, the present invention provides a rubber sheet having a thickness of 500 μm or less. Not using any special coating apparatus, the present invention provides a method for producing a rubber sheet of a rubber composition not containing an organic compound having a boiling point not higher than 150° C.

Abstract translation: 本发明提供一种厚度为500μm以下的橡胶片，其中构成橡胶片的橡胶组合物中的橡胶成分含有重均分子量为500〜100000的液态弹性体， 制造厚度为500μm以下的橡胶片，其包括在基材片上形成不含沸点不高于150℃的有机化合物的橡胶组合物的膜的工序（A） 橡胶组合物的粘度在10〜100000mPa·s的范围内的温度。 使用特定的液体弹性体，本发明提供厚度为500μm以下的橡胶片。 不使用任何特殊的涂布装置，本发明提供一种不含沸点不高于150℃的有机化合物的橡胶组合物的橡胶片的制造方法。

公开(公告)号：US20150017446A1

公开(公告)日：2015-01-15

申请号：US14499895

申请日：2014-09-29

Applicant: BRIDGESTONE CORPORATION

Inventor： Yaohong Chen ,  Mindaugas Rackaitis ,  Xiaorong Wang ,  Hideki Kitano

IPC: C08G81/02 ,  C08G77/442

CPC classification number: C08G81/025 ,  B60C1/0016 ,  C08F287/00 ,  C08G77/442 ,  C08K3/04 ,  C08K3/36 ,  C08K5/548 ,  C08L9/06 ,  C08L51/00 ,  Y10S525/902 ,  Y10S977/773 ,  Y10T428/2989

Abstract: A method is provided for synthesizing a core-shell nanoparticle that includes the following steps: providing a polymeric seed (in a solvent) that includes mono-vinyl monomer cross-liniked with a cross-linking agent to form the core of the nanoparticle, the core has an average diameter of from about nanometers to about 10,000 nanometers, and the core has polymer chains with living ends; adding a stabilizer to stabilize the seed and prevent the seed from precipitating out of solution; and grafting a shell species onto the living ends of the core to form the shell of the nanoparticle. A core-first synthesized nanoparticle, along with a rubber composition and tire product are also provided.

Abstract translation: 提供了一种用于合成核 - 壳纳米颗粒的方法，其包括以下步骤：提供聚合物种子（在溶剂中），其包括与交联剂交联的单乙烯基单体以形成纳米颗粒的核心， 芯具有约纳米至约10,000纳米的平均直径，并且芯具有带有端部的聚合物链; 添加稳定剂以稳定种子并防止种子从溶液中沉淀出来; 并将壳物种接枝到芯的活的末端以形成纳米颗粒的壳。 还提供了核心优先合成的纳米颗粒，以及橡胶组合物和轮胎产品。

公开(公告)号：US09493601B2

公开(公告)日：2016-11-15

申请号：US14746142

申请日：2015-06-22

Applicant: Bridgestone Corporation

Inventor： Xiaorong Wang ,  Hideki Kitano ,  James Herman Pawlow ,  Christopher G. Robertson ,  Yaohong Chen ,  Yuan-Yong Yan

IPC: C08L21/00 ,  C08L7/00 ,  C08L53/02 ,  C08F279/02 ,  C08F297/04 ,  C08L9/06

CPC classification number: C08F279/02 ,  C08F297/046 ,  C08L9/06 ,  C08L21/00 ,  C08L2205/03 ,  C08L2207/53 ,  C08L7/00 ,  C08L9/00 ,  C08L53/00 ,  C08L53/02

Abstract: Compositions and methods are included for preparing a hairy polymeric nanoparticle including first and second shell block polymer arms are at least partially phase-separated and surround a polymeric core. One type of polymeric arm can have a greater polarity than the other type(s) of polymeric arms. A rubber composition including the hairy nanoparticles is also provided.

公开(公告)号：US20160039964A1

公开(公告)日：2016-02-11

申请号：US14822039

申请日：2015-08-10

Applicant: Bridgestone Corporation

Inventor： Hideki Kitano ,  Yaohong Chen

IPC: C08F299/02

CPC classification number: C08F299/02 ,  B01J13/18 ,  C08F2/06 ,  C08F8/00 ,  C08F212/08 ,  C08F257/02 ,  C08F2800/20 ,  C08F2810/20 ,  Y10T428/2982 ,  C08F212/36

Abstract: A method is provided for making nanoparticles, including the steps of: combining a hydrocarbon solvent and an aprotic, polar co-solvent, a mono-vinyl aromatic monomer, polymerization initiator, a solution stabilizer, and a first charge of a cross-linking agent. Subsequently, a second charge of cross-linking agent is added. The nanoparticles have an average diameter of 5 nanometers to about 10,000 nanometers. Spherical nanoparticles are also provided that include a cross-linking agent comprising 30% to 60% by weight of the combined weight of a mono-vinyl aromatic species and the cross-linking agent. The spherical nanoparticles also meet the following equation: 0.90≦(D1/D2)≦1.1 wherein D1 is a first diameter of a nanoparticle and D2 is a second diameter of the nanoparticle, and D1 and D2 intersect at right angles.

Abstract translation: 提供了制备纳米颗粒的方法，包括以下步骤：将烃溶剂与非质子极性共溶剂，单乙烯基芳族单体，聚合引发剂，溶液稳定剂和交联剂的第一电荷 。 随后，加入第二次交联剂。 纳米颗粒具有5纳米至约10,000纳米的平均直径。 还提供了球形纳米颗粒，其包括含有单乙烯基芳族物质和交联剂的组合重量的30重量％至60重量％的交联剂。 球形纳米粒子还满足以下等式：0.90＆nlE;（D1 / D2）＆nlE; 1.1其中D1是纳米颗粒的第一直径，D2是纳米颗粒的第二直径，D1和D2以直角相交。

公开(公告)号：US20150183270A1

公开(公告)日：2015-07-02

申请号：US14416331

申请日：2013-07-23

Applicant: BRIDGESTONE CORPORATION

Inventor： Hideki Kitano ,  Hideyuki Chiashi

IPC: B60C5/14 ,  B32B27/30 ,  B32B25/08 ,  B60C1/00 ,  B32B25/12

CPC classification number: B60C5/14 ,  B29D30/0681 ,  B29D2030/0682 ,  B32B1/00 ,  B32B1/08 ,  B32B7/00 ,  B32B7/02 ,  B32B7/04 ,  B32B25/00 ,  B32B25/04 ,  B32B25/08 ,  B32B25/12 ,  B32B25/14 ,  B32B25/16 ,  B32B27/00 ,  B32B27/06 ,  B32B27/08 ,  B32B27/18 ,  B32B27/26 ,  B32B27/28 ,  B32B27/30 ,  B32B27/306 ,  B32B27/38 ,  B32B2250/03 ,  B32B2250/24 ,  B32B2250/40 ,  B32B2274/00 ,  B32B2307/50 ,  B32B2307/7242 ,  B32B2307/7244 ,  B32B2307/7246 ,  B32B2307/7248 ,  B32B2405/00 ,  B32B2597/00 ,  B32B2605/00 ,  B60C1/0008 ,  B60C2005/145 ,  C08L9/00 ,  Y10T428/24942 ,  Y10T428/269 ,  Y10T428/31826 ,  Y10T428/31924

Abstract: Provided is a laminate for inner liner which uses a resin film in which adhesiveness between an adjacent member such as a carcass and a resin film can be sufficiently secured and a tire using the same. The laminate is a laminate for inner liner including: a gas barrier layer 1 comprising a resin material which is composed of a thermoplastic resin or a mixture of a thermoplastic resin and a thermoplastic elastomer; and rubber layers 2A, 2B each arranged on each of both sides of the gas barrier layer. The rubber layer contains at least a diene elastomer, the diene elastomer is modified by a compound including a functional group having an affinity for the resin material, and at least one of the rubber layers contains a cross-linking agent.

Abstract translation: 提供了一种内衬层压材料，其使用树脂膜，其中可以充分确保相邻的构件如胎体和树脂膜之间的粘合性，以及使用该树脂膜。 层压体是内衬层压体，其包括：阻气层1，其包含由热塑性树脂或热塑性树脂和热塑性弹性体的混合物构成的树脂材料; 以及分别设置在阻气层的两侧的橡胶层2A，2B。 橡胶层至少包含二烯弹性体，二烯弹性体通过包括对树脂材料具有亲和性的官能团的化合物进行改性，并且至少一个橡胶层含有交联剂。