公开(公告)号：US20150259440A1

公开(公告)日：2015-09-17

申请号：US14435312

申请日：2013-10-17

Applicant: BROMINE COMPOUNDS LTD.

Inventor： Bertha Croitoru ,  Dov Beruben ,  Michael Peled ,  Yaakov Rachmilevitch ,  Yaniv Hirschsohn ,  Yelena Epshtein Assor ,  Ella Rapaport ,  Dan Kopel

IPC: C08F2/10 ,  D06M15/263 ,  C08L33/16 ,  C08L23/14 ,  C08L25/06

CPC classification number: C08F2/10 ,  C08F212/08 ,  C08F220/24 ,  C08L23/14 ,  C08L25/06 ,  C08L33/14 ,  C08L33/16 ,  C08L2201/02 ,  C08L2203/12 ,  D06M15/263 ,  D06M2101/06 ,  D06M2101/32 ,  D06M2200/30

Abstract: The invention provides a solution polymerization process, comprising polymerizing pentabromobenzyl acrylate or pentabromobenzyl methacrylate in a mixture of water-miscible aprotic solvent and water, in the presence of a water-soluble free radical initiator and preferably also chain length regulator. The polymers obtained and their uses as flame retardants in polypropylene, HIPS, ABS and textile products are also disclosed.

Abstract translation: 本发明提供一种溶液聚合方法，其包括在水溶性自由基引发剂和优选链长度调节剂的存在下，在水混溶性非质子传递溶剂和水的混合物中聚合丙烯酸五溴苄酯或甲基丙烯酸五溴苄酯。 获得的聚合物及其在聚丙烯，HIPS，ABS和纺织品中的阻燃剂的用途也被公开。

公开(公告)号：US09493584B2

公开(公告)日：2016-11-15

申请号：US14435312

申请日：2013-10-17

Applicant: BROMINE COMPOUNDS LTD.

Inventor： Bertha Croitoru ,  Dov Beruben ,  Michael Peled ,  Yaakov Rachmilevitch ,  Yaniv Hirschsohn ,  Yelena Epshtein Assor ,  Ella Rapaport ,  Dan Kopel

IPC: C08F2/10 ,  C08F220/14 ,  C08L33/14 ,  C08L23/14 ,  C08L25/06 ,  C08L33/16 ,  D06M15/263 ,  C08F220/24 ,  C08F212/08 ,  D06M101/06 ,  D06M101/32

CPC classification number: C08F2/10 ,  C08F212/08 ,  C08F220/24 ,  C08L23/14 ,  C08L25/06 ,  C08L33/14 ,  C08L33/16 ,  C08L2201/02 ,  C08L2203/12 ,  D06M15/263 ,  D06M2101/06 ,  D06M2101/32 ,  D06M2200/30

Abstract: Poly (pentabromobenzyl acrylate) having weight average molecular weight (Mw) in the range from 4,000 to 120,000 and polydispersity index of less than 10 as determined by high temperature gel permeation chromatography, wherein the glass transition temperature of the poly (pentabromobenzyl acrylate) is not more than 150 C.°, the poly (pentabromobenzyl acrylate) includes chains which are terminated by an end group derived from a chain length regulator, wherein the end group is a thiol group —SR1, and wherein R1, is a linear or branched alkyl group composed of not less than 8 carbon atom.

Abstract translation: 通过高温凝胶渗透色谱法测定的重均分子量（Mw）为4,000〜120,000，多分散指数小于10的聚（五溴苄基丙烯酸酯），其中聚（五溴苄基丙烯酸酯）的玻璃化转变温度不是 聚（五溴苄基丙烯酸酯）包括由端基衍生自链长调节剂的端基，其中端基是硫醇基-SR1，其中R1是直链或支链烷基 组不少于8个碳原子。