公开(公告)号：US20150322196A1

公开(公告)日：2015-11-12

申请号：US14762242

申请日：2014-01-21

Applicant: BAYER MATERIALSCIENCE AG

Inventor： Hartmut NEFZGER ,  Xiang LIU ,  John ZHANG ,  Sam Torres

IPC: C08G18/42 ,  C09J175/06 ,  C09D175/06

CPC classification number: C08G18/4238 ,  C08G18/664 ,  C08G2101/0066 ,  C08G2101/0083 ,  C08K3/24 ,  C09D175/06 ,  C09J175/06 ,  C08L75/06

Abstract: The present invention relates to a polyester polyurethane material with long term hydrolysis resistance which is prepared from perchlorates and a polyester polyol comprising structure unit I, II, and III. The polyester polyurethane material having a mole ratio of structure unit II to III of 1:1.5 to 1.5:1 has better long term hydrolysis resistance. In another aspect of the present invention, there is provided soles, carpets, rollers, sealing strips, coating, tires, wipers, steering wheels or gaskets prepared from the polyester polyurethane material, and a use of the polyester polyurethane material.

Abstract translation: 本发明涉及由高氯酸盐制备的具有长期耐水解性的聚酯聚氨酯材料和包含结构单元I，II和III的聚酯多元醇。 结构单元II至III的摩尔比为1:1.5至1.5:1的聚酯聚氨酯材料具有更好的长期耐水解性。 在本发明的另一方面，提供了由聚酯聚氨酯材料制备的鞋底，地毯，辊子，密封条，涂层，轮胎，刮水器，方向盘或垫圈，以及聚酯聚氨酯材料的用途。

公开(公告)号：US20150183949A1

公开(公告)日：2015-07-02

申请号：US14407973

申请日：2013-06-14

Applicant: Bayer MaterialScience AG

Inventor： Jianfeng Xu ,  Sam Torres ,  John Zhang

IPC: C08J9/14 ,  C08J9/12

CPC classification number: C08J9/143 ,  C08G18/3206 ,  C08G18/4072 ,  C08G18/4837 ,  C08G18/632 ,  C08G18/6564 ,  C08G18/8009 ,  C08G2101/0066 ,  C08J9/02 ,  C08J9/127 ,  C08J9/146 ,  C08J2201/022 ,  C08J2203/142 ,  C08J2203/146 ,  C08J2203/182 ,  C08J2205/044 ,  C08J2375/04 ,  C08J2375/08

Abstract: The present invention, which is characterized by the employment of blowing agents comprising fluorinated ethers with a boiling point in the range of from about 0 DEG C to 75° C., pertains to a composition of microcellular polyurethane, a method for preparing the same, and its use in manufacturing shoe materials. Compared to shoe soles made from traditional microcellular polyurethane, in particular those made using 1,1,1,2-tetrafluoroethane (HFC 134a) as the blowing agent, the polyurethane shoe soles prepared according to the present invention exhibit similar shrinkage characteristics, and their linear shrinkage is compatible with the current processing conditions, thus can replace traditional blowing systems comprising 1,1,1,2-tetrafluoroethane (HFC 134a) in shoe manufacturing without the need of changing molds. On the premise of being more environmental-friendly, the present invention also effectively saves production cost for shoe manufacturers.

Abstract translation: 本发明的特征在于使用包含沸点在约0℃至75℃范围内的氟化醚的发泡剂，涉及微孔聚氨酯的组合物，其制备方法， 并用于制造鞋材。 与由传统微孔聚氨酯制成的鞋底相比，特别是使用1,1,1,2-四氟乙烷（HFC 134a）作为发泡剂制成的鞋底，根据本发明制备的聚氨酯鞋底表现出相似的收缩特性， 线性收缩与当前的加工条件相适应，因此可以代替鞋制造中包含1,1,1,2-四氟乙烷（HFC 134a）的传统吹塑系统，而不需要改变模具。 在更加环保的前提下，本发明也有效地节省了鞋制造商的生产成本。