公开(公告)号：US08806851B2

公开(公告)日：2014-08-19

申请号：US12680338

申请日：2008-09-09

Applicant: Cyrill Kammer ,  Berthold Keppeler ,  Jochen Lahr ,  Markus Paule ,  Anke Traebert ,  Nicole Werquet ,  Axel Zuschlag

Inventor： Cyrill Kammer ,  Berthold Keppeler ,  Jochen Lahr ,  Markus Paule ,  Anke Traebert ,  Nicole Werquet ,  Axel Zuschlag

IPC: F01N3/00

CPC classification number: F01N3/208 ,  F01N3/0814 ,  F01N3/0842 ,  F01N9/00 ,  F01N2250/12 ,  F01N2610/02 ,  Y02A50/2325 ,  Y02T10/24 ,  Y02T10/47

Abstract: In a method for reducing the emission of nitrogen dioxide in a motor vehicle having an exhaust gas purification system having an SCR catalytic converter with adsorption centers for nitrogen oxides, an exhaust gas enriched with ammonia is supplied to the SCR catalytic converter above an operating temperature. Below the operating temperature, the exhaust gas supplied to the SCR catalytic converter is enriched with a material such that an adsorption of nitrogen oxides is inhibited at corresponding adsorption centers of the SCR catalytic converter. In order to reduce the overall NOx emissions below a first, predeterminable amount, an exhaust gas enriched with ammonia is supplied to the SCR catalytic converter and the NO2 portion of the total NOx emissions is reduced below a second, predeterminable amount in that NO2 is converted with hydrocarbons stored in the SCR catalytic converter.

Abstract translation: 在具有具有SCR催化转化器的排气净化系统的具有氮氧化物吸附中心的机动车辆的二氧化氮排放的方法中，将富含氨的废气在工作温度以上供给SCR催化剂。 低于工作温度，供应给SCR催化转化器的废气富含一种材料，使得在SCR催化转化器的相应吸附中心抑制氮氧化物的吸附。 为了将总体NOx排放量降低到低于第一可预定量的条件下，向SCR催化转化器供给富含氨的废气，并且将总NO x排放的NO 2部分降低到可转换的NO2以下的可预定量 碳氢化合物储存在SCR催化转化器中。

公开(公告)号：US20110005199A1

公开(公告)日：2011-01-13

申请号：US12680338

申请日：2008-09-09

Applicant: Cyrill Kammer ,  Berthold Keppeler ,  Jochen Lahr ,  Markus Paule ,  Anke Traebert ,  Nicole Werquet ,  Axel Zuschlag

Inventor： Cyrill Kammer ,  Berthold Keppeler ,  Jochen Lahr ,  Markus Paule ,  Anke Traebert ,  Nicole Werquet ,  Axel Zuschlag

IPC: F01N3/00

CPC classification number: F01N3/208 ,  F01N3/0814 ,  F01N3/0842 ,  F01N9/00 ,  F01N2250/12 ,  F01N2610/02 ,  Y02A50/2325 ,  Y02T10/24 ,  Y02T10/47

Abstract: In a method for reducing the emission of nitrogen dioxide in a motor vehicle having an exhaust gas purification system having an SCR catalytic converter with adsorption centers for nitrogen oxides, an exhaust gas enriched with ammonia is supplied to the SCR catalytic converter above an operating temperature. Below the operating temperature, the exhaust gas supplied to the SCR catalytic converter is enriched with a material such that an adsorption of nitrogen oxides is inhibited at corresponding adsorption centers of the SCR catalytic converter. In order to reduce the overall NOx emissions below a first, predeterminable amount, an exhaust gas enriched with ammonia is supplied to the SCR catalytic converter and the NO2 portion of the total NOx emissions is reduced below a second, predeterminable amount in that NO2 is converted with hydrocarbons stored in the SCR catalytic converter.

Abstract translation: 在具有具有SCR催化转化器的排气净化系统的具有氮氧化物吸附中心的机动车辆的二氧化氮排放的方法中，将富含氨的废气在工作温度以上供给SCR催化剂。 低于工作温度，供应给SCR催化转化器的废气富含一种材料，使得在SCR催化转化器的相应吸附中心抑制氮氧化物的吸附。 为了将总体NOx排放量降低到低于第一可预定量的条件下，向SCR催化转化器供给富含氨的废气，并且将总NO x排放的NO 2部分降低到可转换的NO2以下的可预定量 碳氢化合物储存在SCR催化转化器中。

公开(公告)号：US06713202B2

公开(公告)日：2004-03-30

申请号：US09796712

申请日：2001-03-02

Applicant: Marcel Corneille ,  Martina Fischer ,  Berthold Keppeler ,  Christian Lorenz ,  Stefan Paulik ,  Bernd Schönrock

Inventor： Marcel Corneille ,  Martina Fischer ,  Berthold Keppeler ,  Christian Lorenz ,  Stefan Paulik ,  Bernd Schönrock

IPC: H01M804

CPC classification number: B60L11/1898 ,  B60L11/1885 ,  B60L11/1894 ,  C01B3/386 ,  C01B3/48 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  H01M8/0612 ,  H01M8/0618 ,  H01M8/0668 ,  Y02P20/128 ,  Y02T90/16 ,  Y02T90/34

Abstract: A multifuel fuel cell system includes a hydrogen production unit; at least one fuel cell; means for heating a first catalytic converter element in the hydrogen production unit to an operating temperature which can be preset; means for metering liquid fuel, air, and optionally water to the catalytic converter element to produce a synthetic gas mixture containing hydrogen or a reformate; and means for passing the synthetic gas or reformate to further components of the hydrogen production unit which are connected between the catalytic converter element and the at least one fuel cell. The fuel cell system also contains means for switching the fuel cell system between a first and a second operating mode. Separation occurs between the hydrogen production unit and the at least one fuel cell during the first operating mode, and a communicating connection occurs between the hydrogen production unit and the at least one fuel cell during the second operating mode, so that reformate can be transferred from the hydrogen production unit to the at least one fuel cell only during the second operating mode.

Abstract translation: 多燃料燃料电池系统包括氢气生产单元; 至少一个燃料电池; 用于将氢气生产单元中的第一催化转化元件加热至可预设的工作温度的装置; 用于将液体燃料，空气和任选的水计量到催化转化器元件以产生包含氢气或重整产物的合成气体混合物的装置; 以及用于将合成气体或重整产物转移到连接在催化转化器元件和至少一个燃料电池之间的氢气产生单元的另外部件的装置。 燃料电池系统还包括用于在第一和第二操作模式之间切换燃料电池系统的装置。 在第一操作模式期间在氢气产生单元和至少一个燃料电池之间发生分离，并且在第二操作模式期间在氢气产生单元和至少一个燃料电池之间发生连通连接，使得重整产物可以从 氢气产生单元仅在第二操作模式期间连接到至少一个燃料电池。

公开(公告)号：US06432871B1

公开(公告)日：2002-08-13

申请号：US09421352

申请日：1999-10-18

Applicant: Patrick Bachinger ,  Berthold Keppeler ,  Oskar Lamla ,  Bernd Schoenrock ,  Martin Schuessler ,  Dagmar Waidelich

Inventor： Patrick Bachinger ,  Berthold Keppeler ,  Oskar Lamla ,  Bernd Schoenrock ,  Martin Schuessler ,  Dagmar Waidelich

IPC: B01J2370

CPC classification number: C01B3/326 ,  B01J23/72 ,  C01B2203/1076 ,  Y02P20/52

Abstract: A process for manufacturing a catalyst body for generating hydrogen having at least one thin, large-surface catalyst layer, through which the reaction mixture can be passed includes steps of pressing a copper powder (particularly dendritic copper) to form a thin and highly compressed layer which forms a formed body, sintering, the formed body in a reducing atmosphere so that a net-type carrier structure made of copper is formed, and activating a surface layer of the formed body.

Abstract translation: 一种用于制造具有至少一个薄的大表面催化剂层的催化剂体的方法，通过该催化剂层可以通过反应混合物，其包括将铜粉（特别是树枝状铜）挤压以形成薄且高度压缩的层 其形成成形体，在还原气氛中烧结成形体，从而形成由铜制成的网状载体结构，并且活化成形体的表面层。

公开(公告)号：US09157356B2

公开(公告)日：2015-10-13

申请号：US14115695

申请日：2011-12-09

Applicant: Ortwin Balthes ,  Thomas Beckmann ,  Berthold Keppeler ,  Siegfried Mueller

Inventor： Ortwin Balthes ,  Thomas Beckmann ,  Berthold Keppeler ,  Siegfried Mueller

IPC: F01N3/00 ,  F01N3/20 ,  F01N3/023 ,  F01N3/30 ,  F01N9/00 ,  F02D41/00 ,  F02D41/02 ,  F02M25/07 ,  F01N13/00 ,  F02B29/04 ,  F02M35/10

CPC classification number: F01N3/2066 ,  F01N3/023 ,  F01N3/30 ,  F01N9/002 ,  F01N13/009 ,  F01N2430/06 ,  F02B29/0418 ,  F02D41/0055 ,  F02D41/029 ,  F02M26/08 ,  F02M26/15 ,  F02M26/24 ,  F02M26/35 ,  F02M35/1038 ,  Y02A50/2324 ,  Y02A50/2325 ,  Y02T10/22 ,  Y02T10/24 ,  Y02T10/47

Abstract: A method for operating a motor vehicle diesel engine having an exhaust emission control system is provided. The emission control system includes an oxidation catalytic converter, a particle filter, and an SCR catalytic converter, in which the exhaust gas that is discharged from the diesel engine is passed through the oxidation catalytic converter before passing through the particle filter and the SCR catalytic converter. A regeneration of the particle filter with thermal soot burn-off is occasionally carried out, during which the diesel engine is operated at an air-fuel ratio having a lambda value (λ) of at least approximately 1.0, and air is added to the exhaust gas after it exits the oxidation catalytic converter and before it enters the particle filter air, so that soot deposited on the particle filter is burnt-off.

Abstract translation: 提供一种具有废气排放控制系统的机动车用柴油发动机的运转方法。 排放控制系统包括氧化催化转化器，颗粒过滤器和SCR催化转化器，其中从柴油发动机排出的废气在通过颗粒过滤器和SCR催化转化器之前通​​过氧​​化催化转化器 。 偶尔进行具有热烟灰燃烧的颗粒过滤器的再生，在此期间柴油发动机以λ值（λ）至少约为1.0的空燃比操作，并且将空气添加到排气 气体在其离开氧化催化转化器之后并且在其进入颗粒过滤器空气之前，使得沉积在颗粒过滤器上的烟灰被烧掉。

公开(公告)号：US20100005783A1

公开(公告)日：2010-01-14

申请号：US12296817

申请日：2007-04-03

Applicant: Berthold Keppeler ,  Aleksandar Knezevic ,  Markus Paule ,  Detlef Scharr

Inventor： Berthold Keppeler ,  Aleksandar Knezevic ,  Markus Paule ,  Detlef Scharr

IPC: F01N11/00

CPC classification number: F01N11/002 ,  F01N3/106 ,  F01N2560/02 ,  Y02T10/47

Abstract: A device for monitoring an exhaust gas catalytic converter in the exhaust system of an internal combustion engine, includes a measuring apparatus that is arranged in the exhaust system in such a way that, in the greatest part of the operating range of the internal combustion engine, it assumes a temperature that is correlated with a temperature of the exhaust gas catalytic converter. The measuring apparatus has a temperature-sensitive component with a temperature-dependent characteristic component parameter that changes either abruptly at a predetermined transition temperature or temperature range, or continuously in a predetermined way as a function of the temperature. A control and evaluation unit connected to the measuring arrangement detects the characteristic component parameter and/or a change in the latter, and correlates it with an aging state of the exhaust gas catalytic converter.

Abstract translation: 一种用于监测内燃机的排气系统中的废气催化转化器的装置，包括：排气系统中设置的排气系统的测量装置，其特征在于，在所述内燃机的工作范围的最大部分， 它假定与废气催化转化器的温度相关的温度。 该测量装置具有温度敏感性部件，该温度敏感部件具有在预定的转变温度或温度范围内突然变化的温度依赖特性成分参数，或以预定方式连续地作为温度的函数。 连接到测量装置的控制和评估单元检测特征成分参数和/或后者的变化，并将其与废气催化转化器的老化状态相关联。

公开(公告)号：US20050126158A1

公开(公告)日：2005-06-16

申请号：US10484459

申请日：2002-07-19

Applicant: Uwe Benz ,  Berthold Keppeler ,  Andre Martin ,  Peter Schuerstedt ,  Detlef zur Megede

Inventor： Uwe Benz ,  Berthold Keppeler ,  Andre Martin ,  Peter Schuerstedt ,  Detlef zur Megede

IPC: B01D53/94 ,  F01N3/02 ,  F01N3/04 ,  F01N3/05 ,  F01N3/20 ,  F01N3/10 ,  F01N3/00

CPC classification number: F01N3/2046 ,  B01D53/9431 ,  B01D53/9495 ,  F01N3/0205 ,  F01N3/043 ,  F01N3/05 ,  F01N3/206 ,  F01N2240/30 ,  F01N2610/04 ,  Y02A50/2322 ,  Y02T10/26

Abstract: In a system and method for the reduction of nitrogen oxides in the exhaust of an internal combustion engine, the exhaust line of the internal combustion engine contains a DeNOx catalytic converter, in which the nitrogen oxides are reduced by means of hydrogen that is produced on-board the vehicle. The DeNOx catalytic converter is incorporated into a temperature-controlled heat exchanger, allowing the DeNOx catalytic converter to be operated within a desired temperature range, thereby improving the level of conversion.

Abstract translation: 在用于还原内燃机排气中的氮氧化物的系统和方法中，内燃机的排气管含有DeNOx催化转化器，其中氮氧化物通过在上述制造的氢气中的氢气还原， 登上车辆。 DeNOx催化转化器被结合到温度控制的热交换器中，允许DeNOx催化转化器在期望的温度范围内运行，从而提高转化水平。

公开(公告)号：US20050074377A1

公开(公告)日：2005-04-07

申请号：US10487579

申请日：2002-08-30

Applicant: Pascal Brakonier ,  Marcel Corneille ,  Uwe Griesmeier ,  Berthold Keppeler

Inventor： Pascal Brakonier ,  Marcel Corneille ,  Uwe Griesmeier ,  Berthold Keppeler

IPC: B01J12/00 ,  B01J19/00 ,  B01J19/02 ,  C01B3/48 ,  F28F19/02 ,  F28D1/00

CPC classification number: B01J12/007 ,  B01J19/0026 ,  B01J19/02 ,  B01J2219/00247 ,  B01J2219/0236 ,  C01B3/48 ,  C01B2203/0205 ,  C01B2203/0288 ,  C01B2203/0872 ,  C01B2203/1035 ,  C01B2203/1041 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1094 ,  F28F19/02

Abstract: A gas generation system comprises a reformer (1) to generate a hydrogen-containing reformate stream (4), a reformate stream cooler (2), and a shift stage (3) down-stream of the reformate stream cooler to purify the reformate stream. The surfaces of the cooler that come into contact with the reformate stream are coated with a material that contains at least one catalytically active constituent. The coating is selected such that it also protects against corrosion and sooting in the presence of oxidizing, reducing, and carbon-containing gases. By directly utilizing the coated reformate stream cooler as a catalytically active reactor unit, a water-gas shift reaction to reduce the carbon monoxide concentration takes place to some extent in the cooler prior to the reformate stream entering the actual shift stage. This enables the size of subsequent shift stage(s) to be reduced.

Abstract translation: 气体发生系统包括：重整器（1），用于产生含氢重整产物流（4），重整油流冷却器（2）和重整产物流冷却器下游的变换级（3），以净化重整产物流 。 与重整产物流接触的冷却器的表面涂覆有含有至少一种催化活性成分的材料。 选择涂层，使其在氧化，还原和含碳气体的存在下也可防止腐蚀和烟炱。 通过直接利用涂覆的重整油流冷却器作为催化活性反应器单元，在重整料流进入实际的转化阶段之前，在冷却器中发生一定程度的水煤气变换反应，以减少一氧化碳浓度。 这使得能够减小随后的换档阶段的尺寸。

公开(公告)号：US06669923B2

公开(公告)日：2003-12-30

申请号：US09796713

申请日：2001-03-02

Applicant: Berthold Keppeler

Inventor： Berthold Keppeler

IPC: B01J700

CPC classification number: B01J8/04 ,  B01J7/00 ,  B01J2219/00006 ,  C01B3/323 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/025 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/044 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/0844 ,  C01B2203/0866 ,  C01B2203/0883 ,  C01B2203/1064 ,  C01B2203/1205 ,  C01B2203/1223 ,  C01B2203/1288 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/143 ,  C01B2203/82 ,  Y02P20/128

Abstract: A gas generator for generating a hydrogen-rich carbon-monoxide-lean gas from a water-fuel mixture by catalytic steam reforming and/or from an oxygen-fuel mixture by partial oxidation includes at least one fuel reservoir vessel; a reforming reactor; a CO shift reactor; a gas purifying unit; and a line to feed water from a water reservoir vessel into the reformate gas stream fed to the CO shift reactor. The water reservoir vessel contains a water-methanol mixture having a mixing ratio effective to ensure adequate frost protection.

Abstract translation: 一种用于通过催化蒸汽重整和/或通过部分氧化从氧 - 燃料混合物产生来自水 - 燃混合物的富含贫二氧化碳的气体的气体发生器包括至少一个燃料储存容器; 重整反应器; 一个CO转移反应堆; 气体净化单元; 以及将水从储水容器进料到进料到CO转化反应器的重整产品气流中的管线。 储水容器含有具有有效保证充分防霜的混合比的水 - 甲醇混合物。

公开(公告)号：US20140109554A1

公开(公告)日：2014-04-24

申请号：US14115695

申请日：2011-12-09

Applicant: Ortwin Balthes ,  Thomas Beckmann ,  Berthold Keppeler ,  Siegfried Mueller

Inventor： Ortwin Balthes ,  Thomas Beckmann ,  Berthold Keppeler ,  Siegfried Mueller

IPC: F01N3/20

CPC classification number: F01N3/2066 ,  F01N3/023 ,  F01N3/30 ,  F01N9/002 ,  F01N13/009 ,  F01N2430/06 ,  F02B29/0418 ,  F02D41/0055 ,  F02D41/029 ,  F02M26/08 ,  F02M26/15 ,  F02M26/24 ,  F02M26/35 ,  F02M35/1038 ,  Y02A50/2324 ,  Y02A50/2325 ,  Y02T10/22 ,  Y02T10/24 ,  Y02T10/47

Abstract: A method for operating a motor vehicle diesel engine having an exhaust emission control system is provided. The emission control system includes an oxidation catalytic converter, a particle filter, and an SCR catalytic converter, in which the exhaust gas that is discharged from the diesel engine is passed through the oxidation catalytic converter before passing through the particle filter and the SCR catalytic converter. A regeneration of the particle filter with thermal soot burn-off is occasionally carried out, during which the diesel engine is operated at an air-fuel ratio having a lambda value (λ) of at least approximately 1.0, and air is added to the exhaust gas after it exits the oxidation catalytic converter and before it enters the particle filter air, so that soot deposited on the particle filter is burnt-off.

Abstract translation: 提供一种具有废气排放控制系统的机动车用柴油发动机的运转方法。 排放控制系统包括氧化催化转化器，颗粒过滤器和SCR催化转化器，其中从柴油发动机排出的废气在通过颗粒过滤器和SCR催化转化器之前通​​过氧​​化催化转化器 。 偶尔进行具有热烟灰燃烧的颗粒过滤器的再生，在此期间柴油发动机以λ值（λ）至少约为1.0的空燃比操作，并且将空气添加到排气 气体在其离开氧化催化转化器之后并且在其进入颗粒过滤器空气之前，使得沉积在颗粒过滤器上的烟灰被烧掉。