Abstract:
Processes for inhibiting scale produced during wet process phosphoric acid production by adding a scale-inhibiting amount of a reagent having a primary amine-containing polymer, or salt thereof, to one or more stages of a wet process phosphoric acid production stream are provided herein, wherein the primary amine-containing polymer includes an A mer according to Formula (I): where R is H, C1-C6 alkyl, C2-C6 alkenyl, halide, or carboxyl; R1 is H, C1-C6 alkyl, or C2-C6 alkenyl; R2 is H or an A mer according to Formula (I) as herein defined; R3 is chosen from a direct bond or a C1-C12 alkyl, C2-C12 alkenyl, or a C6-C12 aryl group; and n is an integer chosen to provide a weight average molecular weight of the primary amine-containing polymer of at least 300 Daltons, and wherein the percentage of primary amines in the polymer is from 30 mole % to 100 mole % based on the total percentage of mer units in the polymer.
Abstract:
Processes for inhibiting scale produced during wet process phosphoric acid production by adding a scale-inhibiting amount of a reagent having a primary amine-containing polymer to at least one stage of a wet process phosphoric acid production process are provided herein, wherein said primary amine-containing polymer includes one or more organic moieties that reduce the polymer's solubility in an aqueous environment as compared to its native form, thereby reducing or preventing scale in the wet process phosphoric acid production process.