公开(公告)号：US5012750A

公开(公告)日：1991-05-07

申请号：US581735

申请日：1990-09-12

Applicant: Harold R. Sheely ,  Constantine D. Miserlis ,  Ivan L. Rosenblatt

Inventor： Harold R. Sheely ,  Constantine D. Miserlis ,  Ivan L. Rosenblatt

IPC: D21C11/12 ,  F22B31/00 ,  F23G5/30 ,  F23G5/46 ,  F23G7/04

CPC classification number: F23G5/30 ,  D21C11/12 ,  F22B31/0084 ,  F23G5/46 ,  F23G7/04

Abstract: An apparatus and method for recovering constituents and/or heat energy from a fluidized bed combustion process utilizes a single vessel which combines a combustor for fluidized bed combustion of a chemical mixture fed therein and a heat exchange section. Characteristics of the fluidized bed are controlled by withdrawing an appropriate portion of the larger, unburned constituent particles from the bottom of the combustor, and smaller constituent particles are withdrawn by becoming entrained within the gases of combustion and being transported to the heat exchange section. The smaller particles are separated from the gases without the use of a cyclone separator and accumulate as another fluidized bed in the heat exchange section where heat is adsorbed from the particles for recovery purposes and to cool the particles. A portion of the cooled particles is then recirculated to the combustor by, for example, pneumatic transport methods for controlling the operating temperature of the combustion process. The apparatus is particularly well-suited for recovering process salts and heat energy from the burning of black liquor effluent from a lignocellulosic pulping process.

Abstract translation: 用于从流化床燃烧过程中回收组分和/或热能的装置和方法利用单一的容器，其组合用于其中供给的化学混合物的流化床燃烧的燃烧器和热交换部分。 通过从燃烧器的底部排出较大的未燃烧组分颗粒的适当部分来控制流化床的特性，并且较小的组成颗粒通过夹带在燃烧气体中并被运送到热交换部分而被排出。 较小的颗粒与气体分离而不使用旋风分离器，并且在热交换部分中作为另一流化床积聚，其中热量从颗粒吸收以用于回收目的并冷却颗粒。 然后，通过用于控制燃烧过程的操作温度的气动输送方法将一部分冷却的颗粒再循环到燃烧室。 该设备特别适用于从木质纤维素制浆工艺的黑液流出物的燃烧中回收工艺盐和热能。

公开(公告)号：US4182801A

公开(公告)日：1980-01-08

申请号：US870117

申请日：1978-01-17

Applicant: Constantine D. Miserlis ,  Peter J. Lewis

Inventor： Constantine D. Miserlis ,  Peter J. Lewis

IPC: C08F10/00 ,  C08F4/66

CPC classification number: C08F10/00 ,  C08F110/06

Abstract: In the catalytic polymerization of olefins from liquid olefin monomer under positive pressure, the use of a fuel gas, required in any event for providing energy elsewhere in the system, as a regenerative drying gas to regenerate the beds of a molecular sieve dryer used to dry the liquid olefin to be polymerized.

Abstract translation: 在液体烯烃单体在正压下的烯烃的催化聚合中，使用在任何情况下都需要在系统中的其他地方提供能量的燃料气体作为再生干燥气体，以再生用于干燥的分子筛干燥器的床 待聚合的液态烯烃。

公开(公告)号：US4435581A

公开(公告)日：1984-03-06

申请号：US374385

申请日：1982-05-03

Applicant: Constantine D. Miserlis

Inventor： Constantine D. Miserlis

IPC: B01J8/00 ,  B01J8/28 ,  C07C51/25 ,  C07C51/31 ,  C07D307/89

CPC classification number: C07C51/252 ,  B01J8/0055 ,  B01J8/28 ,  C07C51/25 ,  C07C51/313

Abstract: A system for producing phthalic anhydride by the catalytic oxidation of naphthalene, wherein the system is characterized by reduced capital and operating costs due to lower operating pressures.

Abstract translation: 通过萘的催化氧化生产邻苯二甲酸酐的体系，其中该系统的特征在于由于较低的操作压力降低了资本和运行成本。

公开(公告)号：US4406836A

公开(公告)日：1983-09-27

申请号：US327122

申请日：1981-12-03

Applicant: Constantine D. Miserlis

Inventor： Constantine D. Miserlis

IPC: C11C1/08

CPC classification number: C11C1/08

Abstract: This invention constitutes an improved method for condensing fatty acids, particularly from steam streams exiting from distillation columns. Steam streams containing entrained high-titre fatty acids can be condensed in surface condensers if certain conditions are maintained. A surface condenser, having a shell and tube configuration, is oriented in a vertical position rather than the horizontal position often employed. Quite contrary to normal processing, the cooling medium is passed through the shell side of the surface condenser and the steam stream containing entrained high-titre fatty acids is passed through the tube side. Conditions must be maintained within the tube side of the condenser so that a velocity of at least 30' per second is provided and the steam stream must contain at least about 70% steam, by weight, in the tube side of the surface condenser.

Abstract translation: 本发明构成了一种用于冷凝脂肪酸的改进方法，特别是从蒸馏塔排出的蒸汽流中。 如果保持某些条件，则含有夹带的高滴度脂肪酸的蒸汽流可在表面冷凝器中冷凝。 具有壳和管结构的表面冷凝器被定向在垂直位置而不是经常采用的水平位置。 与正常加工相反，冷却介质通过表面冷凝器的壳侧，含有夹带的高滴度脂肪酸的蒸汽流通过管侧。 条件必须保持在冷凝器的管侧内，以便提供至少30'/秒的速度，并且蒸汽流在表面冷凝器的管侧中必须含有至少约70％重量的蒸汽。

公开(公告)号：US4068060A

公开(公告)日：1978-01-10

申请号：US728066

申请日：1976-09-30

Applicant: Constantine D. Miserlis ,  Peter J. Lewis

Inventor： Constantine D. Miserlis ,  Peter J. Lewis

IPC: C08F6/00 ,  C08F10/00 ,  C08F110/06

CPC classification number: C08F6/00 ,  C08F10/00 ,  C08F110/06

Abstract: Removing oligomers (short chain polymers of from two to seven atoms in the chain) from olefin monomer vapor recovered for recycle from the reaction mass resulting from the catalytic polymerization of liquid olefinic monomers by flowing such recovered vapor through a mass transfer plate tower upwardly through openings in the plates of said tower and in the form of bubbles through layers of liquid oligomer reflux maintained on said plates by weirs and downcomers by means of which said reflux is flowed from each plate downwardly to the plate below it and, as a layer, along the top of the plate and thence downwardly to the next lower plate, condensing in a reflux condenser the vapor from the top of said tower, removing olefin monomer from said condenser as a vapor and refluxing condensed liquid oligomers back to the top of said tower. Preferably the tower is a valve tray tower and the plates are valve trays.

Abstract translation: 从烯烃单体蒸气中除去低聚物（链中2至7个原子的短链聚合物），从烯烃单体蒸气回收，以从液体烯烃单体的催化聚合得到的反应物质循环，通过将这种回收的蒸气通过传质板塔向上通过开口 在所述塔的板中并且以气泡的形式通过堰和降液管保持在所述板上的液体低聚物回流层，借助于堰和降液管，所述回流从每个板向下流动到其下方的板，并且作为层 板的顶部，然后向下到下一个下板，在回流冷凝器中冷凝来自塔的顶部的蒸汽，将蒸气中的烯烃单体作为蒸气和回流的冷凝液体低聚物回流到塔的顶部。 优选地，塔是阀塔塔，并且板是阀塔。

公开(公告)号：US4435580A

公开(公告)日：1984-03-06

申请号：US374284

申请日：1982-05-03

Applicant: Constantine D. Miserlis

Inventor： Constantine D. Miserlis

IPC: B01J8/00 ,  B01J8/28 ,  C07C51/25 ,  C07C51/265 ,  C07C51/31 ,  C07D307/89

CPC classification number: C07C51/265 ,  B01J8/0055 ,  B01J8/28 ,  C07C51/25 ,  C07C51/252 ,  C07C51/313

Abstract: A system for producing phthalic anhydride by the catalytic oxidation of naphthalene, wherein without creating a significant pressure drop in the system substantially all of the catalyst particles are removed from the product stream before the product stream is sent to a battery of switch condensers for recovery of the phthalic anhydride.

Abstract translation: 用于通过萘的催化氧化生产邻苯二甲酸酐的体系，其中，在不产生显着的体系压降的情况下，基本上将所有催化剂颗粒从产物流中除去，然后将产物流送入一组开关冷凝器，以回收 邻苯二甲酸酐。

公开(公告)号：US4265223A

公开(公告)日：1981-05-05

申请号：US943373

申请日：1978-09-18

Applicant: Constantine D. Miserlis ,  Albert G. Luke, Jr. ,  Walter Laber ,  Friedrich Guetlhuber

Inventor： Constantine D. Miserlis ,  Albert G. Luke, Jr. ,  Walter Laber ,  Friedrich Guetlhuber

IPC: F03G6/00 ,  F22B1/00 ,  F24S90/00 ,  F24J3/02

CPC classification number: F24J2/34 ,  F22B1/006 ,  F24J2/07 ,  F24J2/42 ,  F24J2/4649 ,  Y02E10/41 ,  Y02E10/46

Abstract: A process and system are provided for economic utilization of solar energy. Solar energy is absorbed and converted to thermal energy by means of at least two systems, operating in different temperature ranges, for circulating a primary fluid heat transfer medium through separate collector sections of a solar receiver to recover solar heat and through separate output heat exchangers to supply heat to a second heat transfer medium functioning as a working medium, with heat storage means being associated with each system for the purpose of satisfying the heat requirements of the working fluid and also to prevent cooling down of the collector during the time that little or no solar radiation is available.

Abstract translation: 为太阳能的经济利用提供了一个过程和系统。 通过在不同温度范围内工作的至少两个系统吸收太阳能并将其转化为热能，用于使主流体传热介质通过太阳能接收器的单独的收集器部分循环，以回收太阳能热量并通过单独的输出热交换器 向作为工作介质起作用的第二传热介质供热，为了满足工作流体的热量要求，并且在少量或 没有太阳辐射可用。

公开(公告)号：US4089365A

公开(公告)日：1978-05-16

申请号：US728153

申请日：1976-09-30

Applicant: Constantine D. Miserlis ,  Peter J. Lewis

Inventor： Constantine D. Miserlis ,  Peter J. Lewis

IPC: B01J19/00 ,  C08F2/00 ,  C08F10/00 ,  B01J1/00

CPC classification number: B01J19/0013 ,  C08F10/00 ,  B01J2219/00083 ,  B01J2219/00101 ,  B01J2219/00114 ,  B01J2219/00162 ,  B01J2219/00168 ,  Y10S165/903

Abstract: Cooling the highly viscous reaction mass during catalytic polymerization of liquid olefins to polyolefins by pumping it to and from the reactor through the tubes of a heat transfer single pass cooler rather than a heat transfer multi-pass cooler as has been done in the past, increasing the number of the tubes in the single pass cooler as compared to the multi-pass cooler, reducing the diameter of the tubes and increasing the pump capacity. The number of tubes and pump capacity are increased sufficiently and the internal diameters of the tubes are decreased sufficiently so that the heat transfer coefficient of the single pass cooler is between 10 and 20 BTU/ft.sup.2 hr. .degree. F.

Abstract translation: 在液态烯烃到聚烯烃的催化聚合过程中，通过将其通过传热单通冷却器的管而不是传热多通道冷却器通过泵送到反应器而冷却高粘度的反应物质，如过去所做的那样，增加 与多通道冷却器相比，单通冷却器中的管道数量减少了管的直径并增加了泵的容量。 管的数量和泵容量被充分增加，并且管的内径被充分地减小，使得单程冷却器的传热系数在10和20BTU / ft 2小时之间。 DEG F.

公开(公告)号：US4068053A

公开(公告)日：1978-01-10

申请号：US728154

申请日：1976-09-30

Applicant: Constantine D. Miserlis ,  Peter J. Lewis

Inventor： Constantine D. Miserlis ,  Peter J. Lewis

IPC: C08F10/00 ,  C08F110/06 ,  C08F6/04 ,  C08F6/10 ,  C08F10/06

CPC classification number: C08F10/00 ,  C08F110/06

Abstract: Removing water and light ends from recycle liquid olefin monomer and fresh liquid olefin monomer feed before catalytic polymerization thereof in said liquid state with a water sensitive catalyst, by flowing them through a mass transfer plate tower with a reboiler which vaporizes them upwardly through openings in the plates of said tower and in the form of bubbles through layers of liquid monomer reflux maintained on said plates by weirs and downcomers by means of which said reflux is flowed from each plate downwardly to the plate below it and, as a layer, along the top of the plate and thence downwardly to the next lower plate, condensing in a reflux condenser the vapor from the top of said tower, removing from said condenser as a vapor said light ends, removing water from said condenser as a heavy condensed liquid fraction and refluxing back to the top of said tower as a lighter liquid fraction, condensed liquid monomer. Preferably the tower is a valve tray tower and the plates are valve trays.

Abstract translation: 在使用水敏感催化剂的所述液态催化聚合之前，通过将再循环液烯烃单体和新鲜的液体烯烃单体进料通过传质塔塔与再沸器一起流动，从而将它们从循环液体烯烃单体和新鲜的液体烯烃单体进料中除去， 所述塔的板和气泡的形式通过堰和降液管保持在所述板上的液体单体回流层，借助于堰和降液管，所述回流从每个板向下流动到其下方的板，并且作为层，沿着顶部 的板，然后向下到下一个下板，在回流冷凝器中冷凝来自塔的顶部的蒸气，从所述冷凝器中除去所述轻质的蒸气，从冷凝器中除去水，作为重的冷凝液体馏分并回流 回到顶部的塔作为较轻的液体馏分，冷凝液体单体。 优选地，塔是阀塔塔，并且板是阀塔。

公开(公告)号：US4979448A

公开(公告)日：1990-12-25

申请号：US461695

申请日：1990-01-08

Applicant: Harold R. Sheely ,  Constantine D. Miserlis ,  Ivan L. Rosenblatt

Inventor： Harold R. Sheely ,  Constantine D. Miserlis ,  Ivan L. Rosenblatt

IPC: F23C10/18 ,  B01J8/24 ,  B01J8/28 ,  C10G11/18 ,  D21C11/06 ,  D21C11/12 ,  F22B31/00 ,  F23C1/08 ,  F23C10/24 ,  F23G5/30 ,  F23G5/46 ,  F23G7/04

CPC classification number: D21C11/12 ,  F22B31/0084 ,  F23G5/30 ,  F23G5/46 ,  F23G7/04 ,  Y02P70/24

Abstract: An apparatus and method for recovering constituents and/or heat energy from a fluidized bed combustion process utilizes a single vessel which combines a combustor for fluidized bed combustion of a chemical mixture fed therein and a heat exchange section. Characteristics of the fluidized bed are controlled by withdrawing an appropriate portion of the larger, unburned constituent particles from the bottom of the combustor, and smaller constituent particles are withdrawn by becoming entrained within the gases of combustion and being transported to the heat exchange section. The smaller particles are separated from the gases without the use of a cyclone separator and accumulate as another fluidized bed in the heat exchange section where heat is adsorbed from the particles for recovery purposes and to cool the particles. A portion of the cooled particles is then recirculated to the combustor by, for example, pneumatic transport methods for controlling the operating temperature of the combustion process. The apparatus is particularly well-suited for recovering process salts and heat energy from the burning of black liquor effluent from a lignocellulosic pulping process.

Abstract translation: 用于从流化床燃烧过程中回收组分和/或热能的装置和方法利用单一的容器，其组合用于其中供给的化学混合物的流化床燃烧的燃烧器和热交换部分。 通过从燃烧器的底部排出较大的未燃烧组分颗粒的适当部分来控制流化床的特性，并且较小的组成颗粒通过夹带在燃烧气体中并被运送到热交换部分而被排出。 较小的颗粒与气体分离而不使用旋风分离器，并且在热交换部分中作为另一流化床积聚，其中热量从颗粒吸收以用于回收目的并冷却颗粒。 然后，通过用于控制燃烧过程的操作温度的气动输送方法将一部分冷却的颗粒再循环到燃烧室。 该设备特别适用于从木质纤维素制浆工艺的黑液流出物的燃烧中回收工艺盐和热能。