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公开(公告)号:US3694513A
公开(公告)日:1972-09-26
申请号:US3694513D
申请日:1970-06-08
Applicant: DOW CHEMICAL CO
Inventor: TOBEY STEPHEN W , LOURANDOS MARILYN Z
IPC: C07C205/23 , C07C79/24
CPC classification number: C07C201/08 , C07C205/23
Abstract: Alkylphenols are nitrated with nitric acid in the presence of a secondary or tertiary alcohol, a secondary alkyl nitrate, an aldehyde or a ketone. Use of such inhibitor decreases the quantity of oxidation products formed, especially quinone formation, and increases the conversion of the starting phenols to the desired nitrated products.
Abstract translation: 在二级或叔醇,仲硝酸烷基酯,醛或酮的存在下,用硝酸硝化烷基酚。 使用这种抑制剂可减少形成的氧化产物的数量,特别是醌的形成,并增加起始酚转化为所需的硝化产物。