SLURRY HYDROCONVERSION WITH PITCH RECYCLE

    公开(公告)号:US20220315844A1

    公开(公告)日:2022-10-06

    申请号:US17640105

    申请日:2020-08-14

    Abstract: Systems and methods are provided for performing slurry hydroconversion of feeds that include substantial amounts of 1050° F+ (566° C+) components. The productivity of the slurry hydroconversion reaction is improved by recycling slurry hydroconversion pitch or bottoms back to the slurry hydroprocessing reaction system. The mass flow rate of the recycle stream can correspond to 50% or more of the mass flow rate of the fresh feed to the reaction system, and the recycle stream can include more than 50 wt % of 566° C+ components. It has been discovered that using a substantial recycle stream composed of a majority of unconverted 566° C+ bottoms can increase the productivity of the slurry hydroprocessing reaction system when operating at a net conversion relative to 524° C (975° F) of less than 90 wt %. Additionally, by using a recycle stream composed of a majority of 566° C+ components, the amount of lower boiling components (in the heavy hydrocarbon feed and/or in the recycle stream) that are exposed multiple times to the slurry hydroprocessing environment is reduced or minimized This can allow for formation of slurry hydroconversion products with increased amounts of vacuum gas oil boiling range components.

    RENEWABLE ARCTIC DIESEL PRODUCTION
    3.
    发明公开

    公开(公告)号:US20240166960A1

    公开(公告)日:2024-05-23

    申请号:US18264740

    申请日:2021-02-09

    Abstract: A method for producing renewable arctic diesel is provided herein. The method includes contacting a bio-derived feedstock with a hydrotreatment catalyst under effective hydrotreatment conditions to produce a hydrotreated feedstock and separating the hydrotreated feedstock into gas phase products and liquid phase products. The liquid phase products include an oxygen content of less than 0.4 wt % but greater than 10 ppm. The method also includes contacting the liquid phase products with a ZSM-48-based isomerization/dewaxing catalyst under effective isomerization/dewaxing conditions to produce an isomerized product stream including a change in cloud point (ΔCP) of 50 degrees ° C. or more. The method further includes separating the isomerized product stream into gas phase products and liquid phase products, as well as fractionating the liquid phase products to produce renewable naphtha and renewable arctic diesel with a cloud point of −20° C. or less and a yield of 80 wt % or more.

    HYDROCONVERTED COMPOSITIONS
    4.
    发明申请

    公开(公告)号:US20230002687A1

    公开(公告)日:2023-01-05

    申请号:US17639880

    申请日:2020-08-14

    Abstract: An hydroconverted effluent composition is provided, along with systems and methods for making such a composition. The hydroconverted effluent composition can have an unexpectedly high percentage of vacuum gas oil boiling range components while having a reduce or minimized amount of components boiling above 593° C. (1100° F.). In some aspects, based in part on the hydroprocessing used to form the hydroconverted effluent composition, the composition can include unexpectedly high contents of nitrogen. Still other unexpected features of the composition can include, but are not limited to, an unexpectedly high nitrogen content in the naphtha fraction; and an unexpected vacuum gas oil fraction including an unexpectedly high content of polynuclear aromatics, an unexpectedly high content of waxy, paraffinic compounds, and/or an unexpectedly high content of n-pentane asphaltenes

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