Method of conversion of heavy aromatics

    公开(公告)号:US20030092950A1

    公开(公告)日:2003-05-15

    申请号:US10285736

    申请日:2002-11-01

    CPC classification number: C07C6/123 C07C6/12 C07C2529/18

    Abstract: A method is provided for conversion of heavy alkylaromatic compounds, particularly those in the C8-C12 range, into more valuable aromatics of benzene, toluene and xylene utilizing a toluene disproportionation unit containing a nickel, palladium or platinum-modified mordenite catalyst. The method allows large amounts of these heavy alkylaromatic compounds to be processed without adversely affecting catalyst activity or catalyst life. This is accomplished by introducing the heavy alkylaromatic compounds into the reactor at constant reaction severity conditions and maintaining those conditions during conversion.

    Dispersing agent and method for the delivery of cross-linking agent to polymer modified asphalt compositions
    2.
    发明申请
    Dispersing agent and method for the delivery of cross-linking agent to polymer modified asphalt compositions 失效
    用于将交联剂递送到聚合物改性沥青组合物的分散剂和方法

    公开(公告)号:US20040249024A1

    公开(公告)日:2004-12-09

    申请号:US10454001

    申请日:2003-06-04

    CPC classification number: B01F17/0064 C08L95/00 C08L2666/02

    Abstract: The present invention provides a dispersing agent that facilitates the delivery of a cross-linking agent to polymer modified asphalt. The present invention further includes a composition comprising a liquid hydrocarbon, the dispersant and cross-linking agent, and methods of preparing the composition and of preparing cross-linked polymer modified asphalt composition.

    Abstract translation: 本发明提供一种促进交联剂向聚合物改性沥青输送的分散剂。 本发明还包括包含液体烃,分散剂和交联剂的组合物,以及制备该组合物和制备交联聚合物改性沥青组合物的方法。

    Method for extending catalyst life in processes for preparing vinyl aromatic hydrocarbons
    3.
    发明申请
    Method for extending catalyst life in processes for preparing vinyl aromatic hydrocarbons 有权
    在制备乙烯基芳烃的方法中延长催化剂寿命的方法

    公开(公告)号:US20040049091A1

    公开(公告)日:2004-03-11

    申请号:US10235279

    申请日:2002-09-05

    Inventor: James R. Butler

    CPC classification number: C07C5/3332 B01J23/78 C07C2523/745 C07C15/46

    Abstract: Disclosed is a method for extending the life of dehydrogenation catalysts used to prepare vinyl aromatic hydrocarbons. The catalysts, which typically include both iron oxide and potassium containing catalysis promoter, are exposed to additional potassium delivered using a potassium carboxylate. The potassium carboxylates are desirably free of halogens and other catalysts poisons or groups that could result in the undesirable properties in vinyl aromatic hydrocarbons produced therewith. The present invention is particularly useful with the production of styrene and methyl styrene.

    Abstract translation: 公开了延长用于制备乙烯基芳烃的脱氢催化剂的寿命的方法。 通常包括氧化铁和含有催化剂催化剂的催化剂暴露于使用羧酸钾递送的另外的钾。 羧酸钾不需要卤素和其它催化剂毒物或基团,这些毒素或基团可能导致在其中产生的乙烯基芳烃中的不良性质。 本发明特别适用于生产苯乙烯和甲基苯乙烯。

    Freeze dry process for the preparation of a high surface area and high pore volume catalyst
    4.
    发明申请
    Freeze dry process for the preparation of a high surface area and high pore volume catalyst 审中-公开
    冷冻干法制备高表面积和高孔体积催化剂

    公开(公告)号:US20040235657A1

    公开(公告)日:2004-11-25

    申请号:US10442773

    申请日:2003-05-21

    Abstract: The present invention provides a process for the preparation of a catalyst having a high surface area and pore volume. The process includes freeze drying an intermediary of the catalyst. The present invention further includes a catalyst prepared by a process that includes the freeze drying step. The present invention also includes a catalyst having a high acidity, as indicated by having an ammonium desorption peak at greater than about 500null C. The prevent invention further includes a method of manufacturing isomerized organic compounds using the catalyst.

    Abstract translation: 本发明提供了制备具有高表面积和孔体积的催化剂的方法。 该方法包括冷冻干燥催化剂的中间体。 本发明还包括通过包括冷冻干燥步骤的方法制备的催化剂。 本发明还包括具有高酸度的催化剂,如通过在大于约500℃具有铵解吸峰所表明的。本发明还包括使用该催化剂制备异构化有机化合物的方法。

    Method for reducing the formation of nitrogen oxides in steam generation
    5.
    发明申请
    Method for reducing the formation of nitrogen oxides in steam generation 审中-公开
    减少蒸汽产生中氮氧化物形成的方法

    公开(公告)号:US20040185398A1

    公开(公告)日:2004-09-23

    申请号:US10738346

    申请日:2003-12-17

    Inventor: James R. Butler

    Abstract: Disclosed herein is a method for generating steam, comprising oxidizing a fuel to generate heat via a flameless reaction; and using the heat generated via the reaction to convert water to steam. In an embodiment, the amount of NOx present is flue gas from the reaction is less than about 10 PPMv. In an embodiment, the reaction temperature is less than about 2600null F. (1430null C.). In an embodiment, the method further comprises controlling the reaction temperature to minimize the formation of NOx. In an embodiment, controlling the reaction temperature further comprises sensing one or more process variables and adjusting a process controller in response to the sensed process variable. Also disclosed herein is a steam generator comprising a reaction zone wherein fuel is oxidized to generate heat via a flameless reaction and a heating zone wherein water is converted to steam via heat from the reaction.

    Abstract translation: 本文公开了一种产生蒸汽的方法,包括氧化燃料以通过无焰反应产生热量; 并使用通过反应产生的热量将水转化为蒸汽。 在一个实施方案中,存在的NOx的量来自反应的烟道气小于约10PPMv。 在一个实施方案中,反应温度低于约2600°F(1430℃)。 在一个实施方案中,该方法还包括控制反应温度以使NOx的形成最小化。 在一个实施例中,控制反应温度进一步包括感测一个或多个过程变量并响应于感测到的过程变量调整过程控制器。 本文还公开了一种蒸汽发生器,其包括反应区,其中燃料被氧化以通过无焰反应产生热量,以及加热区,其中通过反应经由热量将水转化为蒸汽。

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