Abstract:
Provided is a functional polymer membrane having a structure represented by the following Formula (1) and a structure represented by the following Formula (2), in which an ion exchange capacity is 2.0 meq/g to 7.0 meq/g; and a method for producing the same, —S-LL1-LL-LL2-S— Formula (1) in Formula (1), LL represents a single bond or an alkylene group which may have a substituent, —O—, —S—, —NRZ— or a linking group obtained by combining these, LL1 and LL2 represent —(CR1R2)I— or —(CR1R2)I—C(═O)O— (in which the atom bonded to LL is an oxygen atom), R1 and R2 represent a hydrogen atom or an alkyl group, I represents 1 or 2, RZ represents a hydrogen atom or a substituent, however, in a case where terminal atoms of a substituent in LL and a substituent of RZ are a sulfur atom, LL is the sulfur atom having a bond to be incorporated into the polymer chain, and in Formula (2), L1 represents an alkylene group or an alkenylene group, Ra, Rb, Rc, and Rd each independently represent an alkyl group or an aryl group, Ra and Rb, or/and Rc and Rd may be bonded to each other to form a ring, n1 represents an integer of 1 to 10, and X1− and X2− each independently represent an organic or inorganic anion.
Abstract translation:提供具有由下式(1)表示的结构和由下式(2)表示的结构的功能性聚合物膜,其中离子交换容量为2.0meq / g至7.0meq / g; 及其制作方法,€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ-S-LL 1 -LL-LL 2 -S-€ƒ€ƒ€ƒ€ƒFormula(1 在式(1)中,LL表示单键或可以具有取代基的亚烷基,-O-,-S-,-NR Z - 或通过组合这些获得的连接基,LL 1和LL 2表示 - (CR 1 R 2)I - 或 - (CR 1 R 2)I -C(= O)O-(其中与LL键合的原子是氧原子),R 1和R 2表示氢原子或 烷基,I表示1或2,RZ表示氢原子或取代基,但是在LL中的取代基的末端原子和RZ的取代基为硫原子的情况下,LL为与硫原子键 在式(2)中,L 1表示亚烷基或亚烯基,Ra,Rb,Rc和Rd各自独立地表示烷基或芳基,Ra和Rb,或/ 并且R c和R d可以彼此键合形成环,n1表示1〜10的整数 d X 1 - 和X 2 - 各自独立地表示有机或无机阴离子。
Abstract:
An ion exchange membrane obtained by using an ionic monomer having at least two or more polymerizable functional groups, in which a hydrophobicity index H obtained by an expression below from a monomer for forming an ion exchange resin and a material fixed to the resin in the ion exchange membrane is 1.6 or greater, and a manufacturing method therefor. Hydrophobicity index H=Σ{(log P of each component)×(molar ratio of each material in resin)}
Abstract:
Provided is an ion exchange film including a resin which is disposed in pores of a porous support and made of a styrene-acryl copolymer having a structure expressed by General Formula (PI) or (PII) below, a composition for forming the film, and a production method therefor. R1 and R2 represent a hydrogen atom or an alkyl group, Y1 and Y2 represent —O— or —N(Rx)-, and Rx represents a hydrogen atom or an alkyl group. L1 represents a p1+1-valent linking group having 2 or more carbon atoms, L2 represents a bivalent linking group, p1 represents an integer of 1 or greater, and n1, n2, and m1 represent integers of 1 or greater. Ra to Rg represent alkyl groups or aryl groups, 2 or 3 of Ra to Rc may be bonded to each other to form a ring, and 2 to 4 of Rd to Rg are bonded to each other to form a ring. X1− to X4− represent an organic or inorganic anion.
Abstract:
The present invention provides a polymer functional film obtained by polymerizing and curing a composition including (A) a styrene-based monomer represented by Formula (HSM); (B) a crosslinking agent represented by Formula (CL); and (C) a polymerization initiator represented by Formula (PI-1) or (PI-2), and a method for producing the same: in which R1 represents a halogen atom or —N+(R2)(R3)(R4)(X1−); n1 represents an integer from 1 to 10; here, R2 to R4 each independently represent a particular substituent; X1− represents an organic or inorganic anion;L1 represents an alkylene group or an alkenylene group; Ra, Rb, Rc and Rd each independently represent a particular substituent; n2 and n4 each independently represent an integer from 1 to 10; X2− and X3− each independently represent an organic or inorganic anion; andR5 to R10 each represent a hydrogen atom or a particular substituent.
Abstract:
There is provided a liquid filter having a small pressure loss and a manufacturing method for a liquid filter. The liquid filter is a liquid filter that is composed of a nonwoven fabric formed of fibers containing a water-insoluble polymer and a hydrophilizing agent. In the nonwoven fabric, a fiber density continuously changes in a film thickness direction, a fiber density difference is present in the film thickness direction, the fiber density of one surface of the nonwoven fabric in the film thickness direction is maximal, and the fiber density of the other surface of the nonwoven fabric in the film thickness direction is minimal.
Abstract:
A functional polymer membrane contains a polymer compound having a constitutional unit represented by Formula I as a constitutional unit A, a constitutional unit represented by Formula I′ as a constitutional unit A′, and a constitutional unit derived from a polyfunctional monomer having a C log P value of equal to or greater than −0.3 to less than 3.0 as a constitutional unit B.
Abstract:
There are provided a method of manufacturing a cured film, including a first exposure step of exposing a part of a photocurable film formed from a photocurable resin composition, a development step of developing the photocurable film after the exposure with a developing solution to obtain a pattern, and a second exposure step of exposing the pattern with light including light having a wavelength different from a wavelength of light used in the first exposure step, where the photocurable resin composition has a specific constitution, a photocurable resin composition that is used in the method of manufacturing the cured film, a method of manufacturing a laminate including the method of manufacturing a cured film, and a method of manufacturing an electronic device, which includes the method of manufacturing the cured film.
Abstract:
There are provide a cell separation filter with which cells can be separated without damage and can suppress adsorption, a filtering device, and a manufacturing method for a cell separation filter. The cell separation filter is composed of a nonwoven fabric that is formed of fibers containing a water-insoluble polymer and a hydrophilizing agent and has a fiber density difference in the film thickness direction. The nonwoven fabric has an average through-hole diameter of 2.0 μm or more and less than 10.0 μm, a void ratio of 75% or more and 98% or less, a film thickness of 100 μm or more, and a critical wet surface tension of 72 mN/m or more.
Abstract:
The composite anion exchange membrane includes: a surface layer on a single surface or both surfaces of an anion exchange membrane substrate, in which the above-described surface layer contains a copolymer of a monomer A which is a water-soluble polyfunctional monomer and a monomer B which is a cationic monomer, an anion exchange capacity of the above-described surface layer is 0.05 meq/cm3 to 0.50 meq/cm3, and an anion exchange capacity of the above-described anion exchange membrane substrate is 1.0 meq/cm3 to 5.0 meq/cm3.
Abstract:
An object of the present invention is to provide a high-performance ion exchange membrane having a small defect and a sufficient mechanical strength, a method for manufacturing the ion exchange membrane, and a module and a device which include the ion exchange membrane.An ion exchange membrane of the present invention contains a resin having an amino group and a constitutional unit represented by Formula 1, in which the number of amino groups per dry mass is 0.15 to 2.4 mmol/g. In Formula 1, L1 represents an alkylene group or an alkenylene group, Ra, Rb, Rc, and Rd each independently represent an alkyl group or an aryl group, Ra and Rb and/or Rc and Rd may form a ring by being bonded to each other, n1 and n2 each independently represent an integer of 1 to 10, and X1− and X2− each independently represent an organic or inorganic anion.