公开(公告)号：US3647641A

公开(公告)日：1972-03-07

申请号：US3647641D

申请日：1970-10-26

Applicant: GEN ELECTRIC

Inventor： GRUBB WILLARD T ,  MACUR ROBERT A

IPC: G01N27/49 ,  H01M8/08 ,  G01N27/46

CPC classification number: H01M8/08 ,  G01N27/404

Abstract: A REACTANT SENSOR IS DESCRIBED WHICH HAS A GAS DIFFUSION CATHODE, AN ANODE SPACED FROM THE CATHODE, THE ANODE WITH A CATALYTIC COATING OF PLATINUM, PALLADIUM, AND A THIRD LESS NOBLE METAL ON A SUBSTRATE THE CATHODE BEING LARGER THAN THE ANODE IN A GEOMETRIC AREA RATIO OF AT LEAST 3 TO 1, AND A CURRENT METER CONNECTED ACROSS THE CATHODE AND ANODE.

公开(公告)号：US3573992A

公开(公告)日：1971-04-06

申请号：US3573992D

申请日：1968-08-29

Applicant: GEN ELECTRIC

Inventor： GRUBB WILLARD T ,  MACUR ROBERT A

IPC: C25B11/10 ,  H01M4/86 ,  H01M13/00 ,  H01M27/00

CPC classification number: H01M4/86

Abstract: METHODS ARE DESCRIBED FOR FORMING ELECTRODES BY METALLIC DEPOSITION FROM A SOLUTION CONTAINING PLATINUM, PALLADIUM AND SELECTED THIRD METAL ONTO A POROUS SUBSTRATE HAVING AT LEAST A NON-NOBLE METAL COATING. THE METALLIC DEPOSITION IS ACCOMPLISHED BY SUBSTRATE IMMERSION, SUBSTRATE DIPPING, OR SUBSTRATE IMMERSION IN WHICH THE SUBSTRATE IS CONNECTED TO THE POSITIVE TERMINAL OF A POWDER SUPPLY. SUCH ELECTRODES PROVIDE HIGH PERFORMANCE ANODES FOR ELECTROCHEMICAL CELLS.

公开(公告)号：US3905889A

公开(公告)日：1975-09-16

申请号：US51979874

申请日：1974-11-01

Applicant: GEN ELECTRIC

Inventor： MACUR ROBERT A ,  LEBLANC JR OLIVER H ,  GRUBB WILLARD T

IPC: G01N27/403 ,  G01N27/30 ,  G01N27/404 ,  G01N27/46

CPC classification number: G01N27/4045

Abstract: A miniature probe contains a multifunctional electrochemical sensor which measures both the hydrogen ion activity or pH of samples and the carbon dioxide activity of samples. The miniature probe includes a carbon dioxide sensor. When the potential of one electrode in the probe is measured with respect to that of an external reference electrode, a pH sensor is provided.

Abstract translation: 微型探针包含多功能电化学传感器，其测量样品的氢离子活度或pH值和样品的二氧化碳活性。 微型探头包括二氧化碳传感器。 当探针中的一个电极的电位相对于外部参考电极的电位测量时，提供pH传感器。

公开(公告)号：US3650836A

公开(公告)日：1972-03-21

申请号：US3650836D

申请日：1970-04-06

Applicant: GEN ELECTRIC

Inventor： GRUBB WILLARD T ,  MACUR ROBERT A

IPC: H01M8/08 ,  H01M12/06 ,  H01M27/00

CPC classification number: H01M12/06 ,  H01M8/08

Abstract: An electrochemical cell has at least one positive wet-proofed gas diffusion electrode with its major portion within the casing covered with a fuel and oxidant impervious mask, and with its remaining portion within the casing covered with at least one water soluble polymeric thickening agent swellable in the aqueous alkaline electrolyte of a fuel-electrolyte solution and an alkali metal silicate dissolved in the solution. This cell eliminates or reduces substantially the conventional problems of carbonate crust formation, electrolyte leakage, drowning of the gas diffusion electrode, and loss of fuel.

Abstract translation: 电化学电池具有至少一个阳性防湿气体扩散电极，其主要部分在壳体内覆盖有燃料和氧化剂不透水掩模，并且其内部的剩余部分被至少一种可溶于水的可溶性聚合物增稠剂覆盖， 溶解在溶液中的燃料电解质溶液和碱金属硅酸盐的碱性电解液。 该电池消除或减少了碳酸盐地壳形成，电解液泄漏，气体扩散电极淹没和燃料损失的常规问题。