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公开(公告)号:US20250161879A1
公开(公告)日:2025-05-22
申请号:US18949693
申请日:2024-11-15
Applicant: Geo40 Limited
Inventor: Campbell McNicoll , Michael T. O'Sullivan , Isabela Alvares de Castro , William B. Bourcier
IPC: B01D61/14 , B01D15/16 , B01D15/20 , B01D61/02 , B01D61/24 , B01D61/58 , B01J39/02 , B01J39/10 , B01J47/011 , C22B3/24 , C22B26/12
Abstract: A process for mechanical separation of sorbent particles in a Direct Lithium Extraction (DLE) process using an ultrafiltration membrane and/or nanofiltration membrane. Also disclosed is a system for mechanical separation of sorbent particles in a Direct Lithium Extraction (DLE) process using an ultrafiltration membrane and/or nanofiltration membrane. Also disclosed is an improved DLE process with a pH controlled upload step.
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公开(公告)号:US11958749B2
公开(公告)日:2024-04-16
申请号:US16927849
申请日:2020-07-13
Applicant: GEO40 Limited
Inventor: Andrew W. Mitchelmore , Michael T. O'Sullivan , John Lea
IPC: C01B33/14 , B01D61/02 , B01D61/14 , B01D61/58 , B01D63/06 , B01D63/10 , B01J13/00 , C02F1/44 , C02F101/10 , C02F103/06
CPC classification number: C01B33/14 , B01D61/025 , B01D61/145 , B01D61/146 , B01D61/58 , B01D63/06 , B01D63/10 , B01J13/0013 , C02F1/441 , C02F1/444 , B01D2311/06 , B01D2311/25 , B01D2311/2642 , B01D2315/16 , C01P2002/01 , C01P2004/52 , C01P2004/64 , C02F2101/10 , C02F2103/06 , B01D2311/06 , B01D2311/2642
Abstract: The invention relates to methods of production of a silica concentrate from geothermal fluids. More particularly, although not exclusively, the invention relates to the production of a colloidal silica concentrate, colloidal silica or precipitated silica from high temperature geothermal fluids by ultrafiltration to produce size-specific silica colloids and step-wise concentration of silica to avoid precipitation or gelling.
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公开(公告)号:US11198095B2
公开(公告)日:2021-12-14
申请号:US15313849
申请日:2015-05-22
Applicant: GEO40 LIMITED
Inventor: Andrew W. Mitchelmore , Richard A. Simonis , Michael T. O'Sullivan
IPC: B01D61/02 , B01D61/04 , C02F1/44 , C02F1/66 , C01B33/12 , B01D61/14 , C01B33/14 , C02F101/10 , C02F103/06
Abstract: The invention concerns a method and apparatus for producing silica concentrates from geothermal fluids containing at least 300 ppm silica, by passing the fluid at a temperature above 80° C. and at a pH reduced to between 4.0 and 7.5 through a reverse osmosis membrane. In the diagram, geothermal fluid (I) is passed to a separator (2) to be flashed to produce steam (3) and separated geothermal water (SGW) (4). The SGW (4) is passed to a heat exchanger (5) then inlet pump (7). Acid is introduced to the geothermal fluid flow at a dosing means (6) to reduce the pH and an anti-sealant may also be introduced. The geothermal fluid is then passed to a reverse osmosis unit (8) to produce a concentrate (9) and a permeate (10). Following reverse osmosis, the concentrate and permeate may be treated with other processes to produce the desired product and concentration. For example, if precipitated silica is produced, the concentrate is passed to a curing tank (11) and to a thickener (12). The precipitated silica is collected (13) while the retained fluid is removed (14).
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公开(公告)号:US20240367152A1
公开(公告)日:2024-11-07
申请号:US18567715
申请日:2022-06-10
Applicant: Geo40 Limited
Inventor: Campbell McNicoll , Michael T. O'Sullivan , William L. Bourcier
Abstract: The present disclosure provides a process for recycling sorbent used in a process for extracting lithium from an aqueous solution containing lithium. The process may comprise bringing an aqueous solution containing lithium into contact with a hydrogen manganese oxide sorbent to absorb the lithium to produce a lithium loaded sorbent and lithium depleted solution, separating the lithium loaded sorbent and the lithium depleted solution, bringing the lithium loaded sorbent into contact with an acid to produce a lithium rich liquor and regenerated sorbent, separating the lithium rich liquor and the regenerated sorbent, treating the separated lithium rich liquor with a carbonate and/or hydroxide to precipitate manganese carbonate and/or manganese hydroxide, separating precipitated manganese carbonate and/or manganese hydroxide from the lithium rich liquor, and heating the manganese carbonate and/or manganese hydroxide with a source of lithium to produce a regenerated lithium loaded sorbent which is reused in the process. The disclosure also provides a system for recycling sorbent used in a process for extracting lithium from an aqueous solution containing lithium.
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公开(公告)号:US10717655B2
公开(公告)日:2020-07-21
申请号:US15737178
申请日:2016-06-20
Applicant: GEO40 LIMITED
Inventor: Andrew W. Mitchelmore , Michael T. O'Sullivan , John Lea
IPC: C01B33/14 , C02F1/44 , B01D61/02 , B01D61/14 , B01D61/58 , B01D63/10 , B01J13/00 , B01D63/06 , C02F103/06 , C02F101/10
Abstract: The invention relates to methods of production of a silica concentrate from geothermal fluids. More particularly, although not exclusively, the invention relates to the production of a colloidal silica concentrate, colloidal silica or precipitated silica from high temperature geothermal fluids by ultrafiltration to produce size-specific silica colloids and step-wise concentration of silica to avoid precipitation or gelling.
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