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    Stabilization of polyolefins
    2.
    发明授权
    Stabilization of polyolefins 失效
    聚烯烃的稳定化

    公开(公告)号：US3392141A

    公开(公告)日：1968-07-09

    申请号：US51797066

    申请日：1966-01-03

    Applicant: HERCULES INC

    Inventor： MORRIS BLUMBERG ,  MATLACK ALBERT S

    IPC: C08L23/02

    CPC classification number: C08L23/02 ,  C08K5/098 ,  C08K5/3492 ,  C08L23/10 ,  C08L81/04 ,  C08L81/00

    Abstract: 1,165,231. Stabilized polyolefines. HERCULES Inc. 2 Jan., 1967 [3 Jan., 1966], No. 98/67. Heading C3P. A polyolefine composition contains 0À02- 10% by wt. of poly(cyclohexylenedisulphide) and 0À02-10% of a hindered phenol. The polyolefine may be stereoregular polypropylene. The sulphide may be of formula where R is H or a C 1-18 alkyl and n is 5-100, e.g. poly-(dipentene-disulphide). The phenol may be a bis(alkylhydroxyphenyl)-alkanoic acid ester, a poly-(alkylhydroxyphenyl) alkane, a poly-(alkylhydroyphenoxy)-substituted triazine of formula where R is an alkylhydroxyphenyl group and R 1 is -OR or thioalkyl group, an alkylphenol/ acetylene condensate containing the repeating unit where R is H or a C 1-20 alkyl group, a thiobis- (alkylphenol) or a polymeric terpene-phenol condensate. In the examples, polypropylene was blended with (1) calcium stearate, 2,4,6-tris- (3,5 - di - tert. - butyl - 4 - hydroxyphenoxy)- 1,3,5-triazine and a poly-(dipentenedisulphide): (2-8) as (1) replacing the triazine by 2,4-bis- (3,5 - di - tert. - butyl - 4 - hydroxyphenoxy)-6- thiooctyl - 1,3,5 - triazine; 1,3,5 - trimethyl- 2,4,6 - tris - (3,5 - di - tert. - butyl - 4 - hydroxybenzyl) benzene; 2,2,4,4 - tetramethyl - 1,3- cyclobutyl - di[bis - (3,5 - di - tert. - butyl - 4- hydroxyphenyl)]-acetate; the polymeric condensate of p-tert. - butyl - phenol and acetylene; the reaction product of n-nonylphenol and acetone; and the condensate of p-tert.-octylphenol, formaldehyde and oxalic acid respectively.

    Pigments comprising nickel salts of iminoheterocyclicamides
    7.
    发明授权
    Pigments comprising nickel salts of iminoheterocyclicamides 失效
    包含铁蛋白镍的镍的颜料

    公开(公告)号：US3627552A

    公开(公告)日：1971-12-14

    申请号：US3627552D

    申请日：1970-02-18

    Applicant: HERCULES INC

    Inventor： MATLACK ALBERT S

    IPC: C07F15/04 ,  C09B57/10 ,  C08H17/14

    CPC classification number: C09B57/10 ,  C07F15/045

    Abstract: HIGHLY COLORED NICKEL SALTS OR CHELATES OF IMINOHETEROCYCLCIC CARBOXAMIDES OR CARBOTHIAMIDES SUITABLE AS PIGMENTS ARE DESCRIBED. THE NICKEL SALTS ARE PREPARED BY REACTING A NICKEL SALT OF A WEAK ACID WITH THE DESIRED IMINOHETEROCYLIC CARBOXAMIDE OR CARBOTHIAMIDE, AS FOR EXAMPLE, WITH 2-IMINOCOUMARIN-3 CARBOXAMIDE, WHICH IN TURN CAN BE PREFORMED OR FORMED IN SITU BY CONDENSING THE APPROPRIATE ALDEHYDE WITH A CYANOACETAMIDE OR CYANOTHIOACAETAMIDE. PIGMENTARY MIXED CHELATES ARE ALSO FORMED IN THE SAME MANNER BY REACTING THE NICKEL SALT WITH A MIXTURE OF THE DESIRED IMINOHETEROCYCLIC CARBOXAMIDE OR CARBOTHIAMIDE AND AT LEAST ONE OTHER CHELATING AGENT SUCH AS, FOR EXAMPLE, DIMETHYLGLYOXIME, 1-NITROSO-2-NAPHTHOL, ETC.

    Nickel salts of iminoheterocyclicamides
    8.
    发明授权
    Nickel salts of iminoheterocyclicamides 失效
    镍氢化合物的镍盐

    公开(公告)号：US3576012A

    公开(公告)日：1971-04-20

    申请号：US3576012D

    申请日：1967-11-02

    Applicant: HERCULES INC

    Inventor： MATLACK ALBERT S

    IPC: C07F15/04 ,  C09B57/10 ,  C07D7/20

    CPC classification number: C09B57/10 ,  C07F15/045

    Abstract: HIGHLY COLORED NICKEL SALTS OF CHELATES OF IMINOHETEROCYCLIC CARBOXAMIDS OR CARBOTHIAMIDES SUITABLE AS PIGMENTS ARE DESCRIBED. THE NICKEL SALTS ARE PREPARED BY REACTING A NICKEL HALIDE OR A NICKEL SALT OF A WEAK ACID WITH THE DESIRED IMINOHETEROCYCLIC CARBOXAMIDE OR CARBOTHIAMIDE, AS FOR EXAMPLE, WITH 2-IMINOCOUMARIN-3-CARBOXAMIDE, WHICH IN TURN CAN BE PREFORMED OR FORMED IN SITU BY CONDENSING THE APPROPRIATE ALDEHYDE WITH A CYANOACETAMIDE OR CYANOTHIOACETAMIDE. PIGMENTARY MIXED CHELATES ARE ALSO FORMED IN THE SAME MANNER BY REACTING THE NICKEL SALT WITH A MIXTURE OF THE DESIRED IMINOHETEROCYCLIC CARBOXAMIDE OR CARBOTHIAMIDE AND AT LEAST ONE OTHER CHELATING AGENT SUCH AS, FOR EXAMPLE, DIMETHYLGLYOXIME, 1NITROSO-2-NAPHTHOL, ETC.

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