Abstract:
The present invention belongs to the field of functional materials, and particularly relates to a directly printable image recording material, a preparation method and application thereof. The image recording material comprises 25 to 78.8 parts by mass of a photopolymerizable monomer, 0.2 to 5 parts by mass of a photoinitiator, 20 to 70 parts by mass of an inert component, and 0.05 to 2 parts by mass of a thermal polymerization inhibitor, and has an initial viscosity of 200 to 800 mPa·s. The photopolymerizable monomer includes a thiol monomer and an olefin monomer, at least one of which is a silicon-based monomer with polyhedral oligomeric silsesquioxane as a silicon core. By introducing a POSS-based thiol or olefin monomer into the photopolymerizable monomer in combination with other material components, the recording material is allowed to have an initial viscosity of 200 to 800 mPa·s, and meanwhile, the low thermal conductivity characteristic of the POSS-based photopolymerizable monomer is utilized, so that image storage quality is ensured, continuous industrial production of the image recording material is achieved, the process cost is reduced and the production efficiency is improved.
Abstract:
A holographic wavefront printing system and method are provided. A two-dimension digital blazed grating is loaded on a phase hologram, and the emergent direction of active region diffracted light is adjusted to prevent overlapping with the dead region diffracted light after being Fourier transformed by a lens, and a phase spatial light modulator is inclined by a preset angle to change the emergent direction of the diffracted light, such that the dead region zeroth-order and first-order diffracted light on a focusing surface are symmetrical with respect to a main optical axis of a first lens, the frequency spectrum center of active region zeroth-order diffracted light is then loaded to the original frequency spectrum center without information change. In this way, the adverse effects of the dead region diffracted light and active region high-order diffracted light of the phase spatial light modulator on holographic wavefront printing are eliminated.
Abstract:
A method for preparing a colorful three-dimensional hologram based on holographic polymer dispersed liquid crystal gratings comprises: first, in a 441.6 nm laser interference field, preparing with holography a holographic master (7) which stores the reflected (or transmitted) light wave information (amplitude and phase) of an object captured; then using an object light (6) to irradiate the holographic master at a Bragg angle to generate a diffraction light (8); and using the diffraction light and a reference light (10) to simultaneously irradiate a holographic base board (9) comprising a photosensitizer, a co-initiator, a monomer capable of free radical polymerization , and a liquid crystal so that, when total optical paths of the two laser beams reaching the holographic base board are equivalent to each other, optical coherence occurs between the two laser beams on the holographic base board, thereby obtaining a colorful three-dimensional hologram based on holographic polymer dispersed liquid crystal gratings from which an image of the captured object can be observed in the sunlight.
Abstract:
The disclosure belongs to the technical field of photopolymer materials, and more particularly relates to a dual image storage material as well as a preparation method and application thereof. The dual image storage material is obtained by selective photoreaction of 1 to 50 parts by weight of an organic fluorescent material, 7 to 50 parts by weight of liquid crystal, 0.2 to 10 parts by weight of a photoinitiator and 33 to 67 parts by weight of photopolymerizable monomers. The obtained dual image storage material can present a high-brightness holographic pattern under sunlight and a fluorescent pattern under ultraviolet light in the same spatial position. The presented holographic and fluorescent patterns may be the same or different. The obtained dual image storage material can be used in the field of optical anti-counterfeiting, optical information storage, displays or the like.