公开(公告)号：US3668278A

公开(公告)日：1972-06-06

申请号：US3668278D

申请日：1970-09-29

Applicant: MONTEDISON SPA

Inventor： BONVICINI ALBERTO ,  CANTATORE GUISEPPE

IPC: C08G69/00 ,  C08G69/26 ,  C08G69/50 ,  C08L23/02 ,  C08G41/04

CPC classification number: C08G69/50 ,  C08G69/00 ,  C08G69/26 ,  C08L23/02 ,  C08L23/10 ,  C08L77/00 ,  C08L2203/12 ,  C08L2207/14 ,  C08L2666/20

Abstract: A new class of basic polyamides having a molecular weight between about 2,000 and 200,000. The polyamides are prepared by first reacting an acrylic or methacrylic ester with a monoamine and then further reacting the product obtainable with a polyamine. The polyamides are suitable for use as tinctorial modifiers for polymeric materials and particularly for crystalline polyolefins consisting essentially of isotactic macromolecules.

Abstract translation: 一类新型基础聚酰胺，分子量约为2,000至200,000。 聚酰胺通过首先使丙烯酸或甲基丙烯酸酯与单胺反应，然后使可得到的产物与多胺反应来制备。 聚酰胺适合用作聚合物材料的着色改性剂，特别是用于基本上由全同立构大分子组成的结晶聚烯烃。

公开(公告)号：US3557086A

公开(公告)日：1971-01-19

申请号：US3557086D

申请日：1966-11-03

Applicant: MONTEDISON SPA

Inventor： CANTATORE GIUSEPPE ,  BONVICINI ALBERTO

IPC: C07D243/08 ,  C07D53/02

CPC classification number: C07D243/08

Abstract: ALKYL SUBSTITUTED HEXAHYDRO-1,4-DIAZEPINES HAVING THE FORMULA

2,2,3,3,5,5,6,6,7,7-DECA(R-)HEXAHYDRO-1,4-DIAZEPINE

WHEREIN THE R SUBSTITUENTS ARE THE SAME OR DIFFERENT AND ARE SELECTED FROM THE GROUP CONSISTING OF HYDROGEN ATOMS AND ALKYL GROUPS CONTAINING 1 TO 18 CARBON ATOMS ARE PREPARED BY REACTING AN ETHYLENE-DIAMINE WITH AN ALIPHATIC ALPHA-BETA UNSATURATED ALDEHYDE OR KETON AND THEN CATALYTICALLY HYDROGENATING THE REACTION MIXTURE. NOVEL ALKYL SUBSTITUTED HEXAHYDRO-1,4-DIAZEPINES ARE DISCLOSED.

公开(公告)号：US3502653A

公开(公告)日：1970-03-24

申请号：US3502653D

申请日：1967-02-21

Applicant: MONTEDISON SPA

Inventor： CANTATORE GIUSEPPE ,  BONVICINI ALBERTO

IPC: C07D243/08 ,  C07D53/02

CPC classification number: C07D243/08

公开(公告)号：US3640999A

公开(公告)日：1972-02-08

申请号：US3640999D

申请日：1967-10-10

Applicant: MONTEDISON SPA

Inventor： BONVICINI ALBERTO ,  CANTATORE GIUSEPPE

IPC: C07D243/08 ,  C07D53/02

CPC classification number: C07D243/08

Abstract: WHEREIN R IS AS PREVIOUSLY DEFINED, WITH A SATURATED ALIPHATIC KETONE OF THE FORMULA R''-CO-R'', WHERE THE R'' MAY BE THE SAME OR DIFFERENT AND IS AN ALKYL GROUP HAVING FROM ABOUT 1 TO 12 CARBON ATOMS, AND THEREAFTER SUBJECTING THE RESULTING MATERIAL TO CATALYTIC HYDROGENATION.

H2N-C(-R)2-C(-R)2-NH2

WHEREIN R MAY BE THE SAME OF DIFFERENT AND IS A HYDROGEN OR AN ALKYL GROUP HAVING FROM ABOUT 1 TO 12 CARBON ATOMS AND A MAY BE THE SAME OR DIFFERENT AND IS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN AND AN ALKYL GROUP HAVING FROM ABOUT 1 TO 12 CARBON ATOMS, THIS PROCESS COMPRISING REACTING, IN THE PRESENCE OF AN ACID CATALYST, AN ETHYLENEDIAMINE OF THE GENERAL FORMULA 2

2,2,3,3-TETRA(R-),5,5,7-TRI(A-)HEXAHYDRO-1,4-DIAZEPINE

PROCESS FOR PREPARATION OF ALKYL-SUBSTITUTED 1,4-DAZACYCLOHEPTANES OF THE GENERAL FORMULA 1

公开(公告)号：US3454670A

公开(公告)日：1969-07-08

申请号：US3454670D

申请日：1966-05-09

Applicant: MONTEDISON SPA

Inventor： CANTATORE GIUSEPPE ,  BONVICINI ALBERTO

IPC: C08G73/00 ,  C08G73/02 ,  C08L23/02 ,  C08F29/10

CPC classification number: C08G73/022 ,  C08G73/00 ,  C08K3/22 ,  C08K5/098 ,  C08L23/02 ,  C08L23/10 ,  C08L71/03 ,  C08L79/04 ,  D01F6/46 ,  C08L2666/20

Abstract: Shaped articles comprise a mixture of a crystalline olefin polymer and 1 to 25 per cent based on the weight of olefin polymer of a basic nitrogen containing polycondensate of epichlorohydrin with a bis-secondary amine and a diphenolic compound. The articles may be textile fibres and filaments, tapes or films. The olefin polymer may be polypropylene. The polycondensate may be prepared from dialkyl alkylenediamines, piperazine, 2-methyl piperazine or 2,5-dimethyl piperazine and 2,2-bis(4-hydroxyphenyl)propane, pyrocatechol, resorcinol, hydroquinone or 4,41-dihydroxy diphenyl methane. The polycondensates may be rendered water-insoluble by treating the articles with epoxy compounds, isocyanates, aldehydes, halogens or divinyl benzene. The polycondensates are said to improve the dyeability of the olefin polymer articles, which may be further improved by treatment with an acid. In examples epichlorohydrin and piperazine are reacted with (1 and 2) bisphenol A and (3) hydroquinone in methanol with the addition of sodium hydroxide in the later stages of the reaction. The products are mixed with polypropylene, calcium stearate and titanium dioxide and the resulting compositions melt spun into fibres which are stretched, treated with a solution of ethylene glycol diglycidyl ether and dyed.ALSO:Articles such as fibres, filaments, films and tapes made of compositions comprising a crystalline olefin polymer and 1 to 25 weight per cent based on said polymer of a polycondensate of epichlorohydrin, a bis secondary amine and a diphenolic compound or diglycigyl ether thereof, may be dyed with acid, metallised and dispersed dyestuffs. The olefin polymer may be polypropylene and the polycondensate may be derived from dialkyl alkylenediamines, piperazine, 2-methyl piperazine or 2, 5-dimethyl piperazine and 2,2-bis(4-hydroxyphenyl) propane, pyrocatechol, resorcinol, hydroquinone or 4,4\sv-dihydroxy diphenyl methane. The polycondensates may be rendered water-insoluble by treating the articles with epoxy compounds, isocyanates, aldehydes, halogens or divinyl benzene, and dyeability may be further improved by treating the articles with an acid. Dyeing with acid and metallised dyestuffs may be effected in the presence of ammonium acetate and a surface active agent, e.g. an alkyl phenol/ethylene oxide condensate, with the addition of acetic acid to improve exhaustion of the dyebath. Dyeing with disperse dyestuffs may be effected in the presence of a surface active agent. In examples fibres made of compositions comprising polypropylene, calcium stearate, titanium dioxide and polycondensates of epichlorohydrin, piperazine and (1 and 2) bisphenol A and (3) hydroquinone are dyed with acid, metallised and disperse dyes.

公开(公告)号：US3668280A

公开(公告)日：1972-06-06

申请号：US3668280D

申请日：1970-02-24

Applicant: MONTEDISON SPA

Inventor： BONVICINI ALBERTO ,  CANTATORE GIUSEPPE

IPC: C08L45/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L23/02 ,  C08L25/00 ,  C08L33/00 ,  C08L33/02 ,  C08L57/02 ,  C08L101/00 ,  D01F6/04 ,  D01F6/46

CPC classification number: D01F6/04 ,  C08L23/02 ,  C08L23/10 ,  C08L25/12 ,  C08L2203/12 ,  D01F1/10 ,  C08L2666/04 ,  C08L2666/06

Abstract: There are disclosed dyeable fibers comprising mixtures of olefinic polymers with terpolymers of (a) vinyl or isopropenyl derivatives of aromatic hydrocarbons, such as styrene, vinyltoluene, alpha-methylstyrene and the like; (b) alpha, betaunsaturated nitriles, such as acrylonitrile, methacrylonitrile, and the like; and (c) aromatic and cycloaliphatic hydrocarbons, containing a double vinylenic bond, such as indene, acenanaphthylene, cyclohexene, and the like. The olefin polymer may be, and preferably is, a high molecular weight polypropylene consisting essentially of isotactic polypropylene made up of isotactic macromolecules, i.e., of macromolecules having substantially isotactic structure and being non-extractable with boiling n-heptane. A process for preparing the dye-receptive fibers is also disclosed.

Abstract translation: 公开了包含烯烃聚合物与（a）芳族烃的乙烯基或异丙烯基衍生物如苯乙烯，乙烯基 - 甲苯，α-甲基苯乙烯等的三元共聚物的可染性纤维; （b）α，β-不饱和腈，如丙烯腈，甲基丙烯腈等; 和（c）含有双烯基键的芳族和脂环族烃，例如茚，亚苊烯，环己烯等。 烯烃聚合物可以是，优选的是由基本上由全同立构大分子构成的全同立构聚丙烯组成的高分子量聚丙烯，即具有基本上全同立构结构的大分子，并且不能用沸腾的正庚烷萃取。 还公开了一种制备染料接收纤维的方法。

公开(公告)号：US3510437A

公开(公告)日：1970-05-05

申请号：US3510437D

申请日：1967-05-22

Applicant: MONTEDISON SPA

Inventor： BONVICINI ALBERTO ,  CANTATORE GIUSEPPE

IPC: C08G73/02 ,  C08L23/02

CPC classification number: C08G73/0273 ,  C08G73/02 ,  C08K3/22 ,  C08K5/098 ,  C08L23/02 ,  C08L23/10 ,  C08L71/03 ,  C08L2666/20

Abstract: 1,182,002. Basic nitrogen-containing polycondensates; olefin polymer compositions. MONTECATINI EDISON S.p.A. 22 May, 1967 [2 May, 1966], No. 23704/67. Headings C3P and C3R. [Also in Division D1] A basic nitrogen-containing polycondensate useful as an additive to polyolefins and other polymers comprises the reaction product of epichlorohydrin and a seven-membered heterocyclic bi-secondary diamine, which product has been modified with a polyamine containing one or more primary amino groups. Suitable seven-member heterocyclic bi-secondary diamines have the general formula wherein R represents H or an alkyl group which may be the same or different in each case. Examples are 5,5,7-trimethylpiperazine, 5,6,7- trimethylpiperazine, 5,7 - dimethylpiperazine, 5,6 - dimethyl - 7 - propylpiperazine and tetramethylpiperazine. Suitable polyamines include hexamethylene diamine, ethylene diamine, diethylene triamine, tetraethylenepentamine and aminoethylpiperazine. The molar ratios of epichlorohydrin/heterocyclic amine/polyamine are generally 1 : 0À5-0À99 : 0À01-1 respectively. 1-25 % of the modified polycondensates may be incorporated into polyolefin compounds having isotactic structures and prepared from monomers of the general formula RCH = CH 2 where R is hydrogen or an alkyl or aryl group, such as polyethylene, polypropylene, polybutene-1, polypentene-1, polyhexene-1, poly-4- methyl-pentene-1, polyoctene-l or polystyrene, in order to improve dyeability of their fibres (see Division D1). Other polymers mentioned are those of acrylonitrile and vinyl chloride. The mixing may be carried out in the presence of a dispersing agent and the mixture granulated before extruding. The filaments may be insolubilized by reacting with epoxides, isocyanates, aldehydes, halogens or metal salts. Specification 1,104,059 is referred to.

公开(公告)号：US3907935A

公开(公告)日：1975-09-23

申请号：US50010274

申请日：1974-08-23

Applicant: MONTEDISON SPA

Inventor： BONVICINI ALBERTO ,  CANTATORE GIUSEPPE ,  BALATA FABRIZIO

IPC: C08F8/32 ,  C08L23/02 ,  C08F29/12 ,  C08F33/08

CPC classification number: C08F8/32 ,  C08K5/17 ,  C08L23/02 ,  C08L23/10 ,  C08L25/14 ,  C08L33/12 ,  C08L2203/12 ,  C08L2203/16 ,  C08L2205/03 ,  C08F20/12 ,  C08F22/14 ,  C08L2666/04

Abstract: A polyolefin composition which is highly receptive to acid, metallized, and disperse dyes comprises a mixture of about 99 to 75 percent by weight of a polyolefin consisting essentially of isotactic macromolecules and about 1 to 25 percent by weight of a basic nitrogen-containing polyamide obtained from the amination of homopolymers and copolymers of esters of alpha, betaunsaturated acids. The preparation of fibers and shaped articles from this composition is also disclosed.

Abstract translation: 对酸，金属化和分散染料高度接受的聚烯烃组合物包含约99至75重量％的基本上由全同立构大分子组成的聚烯烃和约1至25重量％的获得的碱性含氮聚酰胺的混合物 来自α，β-不饱和酸的酯的均聚物和共聚物的胺化。 还公开了从该组合物制备纤维和成型制品。

公开(公告)号：US3625958A

公开(公告)日：1971-12-07

申请号：US3625958D

申请日：1967-10-10

Applicant: MONTEDISON SPA

Inventor： CANTATORE GIUSEPPE ,  BONVICINI ALBERTO

IPC: A47B57/18 ,  A47B57/54 ,  A47F3/12 ,  C07D243/08 ,  C07D53/02

CPC classification number: C07D243/08 ,  A47F3/12

Abstract: Process for the preparation of a substituted 1,4-diazacycloheptene of the general formula:

WHEREIN R is as defined above, with a saturated aliphatic ketone of the general formula: R-CO-R wherein R may be the same or different and is an alkyl group having one to 12 carbon atoms.

WHEREIN R may be the same or different and is a hydrogen atom or an alkyl group having from about one to 12 carbon atoms. Involves reacting in the presence of an acid catalyst such as hydrochloric acid, nitric acid, acetic acid, formic acid, ammonium nitrate, ptoluene-sulphonic acid, aluminum chloride, ferric nitrate, or ethylenediamine dichlorohydrate, an ethylenediamine of the general formula:

公开(公告)号：US3560594A

公开(公告)日：1971-02-02

申请号：US3560594D

申请日：1969-08-19

Applicant: MONTEDISON SPA

Inventor： BONVICINI ALBERTO ,  CANTATORE GIUSEPPE

IPC: C08G73/02 ,  C08L23/02 ,  C08F41/12

CPC classification number: C08G73/0273 ,  C08G73/02 ,  C08K3/22 ,  C08K5/098 ,  C08L23/02 ,  C08L23/10 ,  C08L71/03 ,  C08L2666/20

Abstract: DYE-RECEPTIVE COMPOSITIONS, PREFERABLY IN THE FORM OF TEXTILE FIBERS, COMPRISING 1-25% BY WEIGHT OF A BASIC NITROGEN POLYCONDENSATE OBTAINED BY REACTING THE CONDENSATION PRODUCT OF EPICHLOROHYDRIN AND A HETEROCYCLIC SEVEN-MEMBERED DISECONDARY DIAMINE, THIS CONDENSATION PRODUCT HAVING THE FORMULA:

CL-CH2-CH(-OH)-CH2-((DECA(R-)HEXAHYDRO-1,4-DIAZEPIN-1,4-

YLENE)-CH2-CH(-OH)-CH2)N-CL

WHEREIN R RADICALS ARE THE SAME OR DIFFERENT RADICALS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN AND ALKYL RADICALS HAVING 1-12 CARBON ATOMS, AND N IS AN INTEGER FROM 1 THROUGH 100, WITH A POLYAMINE CONTAINING PRIMARY AMINO GROUPS OF THE TYPE

R-HN...X...NH2

WHERE R IS H, AND ALKYL GROUP OR A RESIDUE OF A HETEROCYCLIC NUCLEUS AND X IS A RESIDUE OF A BIVALENT HYDROCARBON, OPTIONALLY CONTAINING S, N, O, ETC., FOR EXAMPLE, HEXAMETHYLENEDIAMINE, ETHYLENEDIAMINE, DIETHYLENETRIAMINE, TETRAETHYLENEPENTAMINE, AMINOETHYLPIPERAZINE N-METHYLHEXAMETHYLENEDIAMINE, N-ISOPROPYLHEXAMETHYLENEDIAMINE, 3.3-DIAMINODIPROPYLETHER. 3,3''-DIAMINODIPHENYLMETHANE. N,N''-BIS-(3-AMINO-PROPYL) PIPERAZINE, AND THE LIKE; AD, CORRESPONDING. 99-75% BY WEIGHT OF A SYNTHETIC POLYMER, E.G., A POLYOLEFIN.