Process for preparing halogenated and mixed halogenated derivatives of methane by the chlorofluorination of methane
    3.
    发明授权
    Process for preparing halogenated and mixed halogenated derivatives of methane by the chlorofluorination of methane 失效
    通过甲烷氯化氢制备甲烷的氢化和混合的甲基化衍生物的方法

    公开(公告)号:US3679767A

    公开(公告)日:1972-07-25

    申请号:US75105668

    申请日:1968-08-08

    Applicant: MONTEDISON SPA

    CPC classification number: C07C17/10

    Abstract: Process for preparing chlorofluoromethanes by reaction of methane, chlorine and a recycle mixture of halogenated hydrocarbons, containing prevailingly carbon tetrachloride, with mineral calcium fluoride in a fluid bed at a temperature of from 450* to 600*C and for a contact time of from 0.5 to 120 seconds.

    Abstract translation: 通过甲烷,氯和含有普遍的四氯化碳的卤代烃与矿物氟化钙的循环混合物在流化床中在450℃至600℃的温度下反应并接触0.5次的方法来制备氯氟甲烷的方法 至120秒。

    Process for the production of iodopentafluoroethane
    8.
    发明授权
    Process for the production of iodopentafluoroethane 失效
    制备碘代四氢呋喃的方法

    公开(公告)号:US3644544A

    公开(公告)日:1972-02-22

    申请号:US77595668

    申请日:1968-11-04

    Applicant: MONTEDISON SPA

    CPC classification number: C07C19/16 C07C17/04 C07C17/206

    Abstract: A PROCESS FOR THE PRODUCTION OF IODOPENTAFLUOROETHANE (C2F5I) WHEREIN TETRAFLUOROETHYLENE (C2F4) IS REACTED WITH MOLECULAR IODINE (I2) TO YIELD DI-IODOPENTAFLUOROETHANE (C2F4I2). THE LATTER IS REACTED IN AN AUTOCLAVE WITH LEAD DIOXIDE (PBO2) AND HYDROGEN FLUORIDE (HF) AT A TEMPERATURE OF 25* TO 200*C. (PREFERABLY 80*C. TO 160*) AT A PRESSURE OF 5 TO 50 ATMOSPHERES ABSOLUTE (ATA.). PREFERABLY 25-36 ATA. THE MOLAR RATIO HF/C2F4I2 IS 2 TO 50 (PREFERABLY 10 TO 30). THE MOLAR RATION PBO2/C2F4I2 IS 0.5 TO 2 (PREFERABLY 0.5 TO 1).

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