公开(公告)号：US3793229A

公开(公告)日：1974-02-19

申请号：US3793229D

申请日：1971-06-08

Applicant: MONTEDISON SPA

Inventor： GROPPELLI G ,  VECCHIO M ,  FATTORE V ,  LODI L ,  COVINI R

IPC: B01J27/06 ,  C07C17/02 ,  C07C17/04 ,  C07C17/20 ,  C07C17/37 ,  B01J11/78

CPC classification number: C07C17/37 ,  B01J27/06 ,  C07C17/02 ,  C07C17/04 ,  C07C17/206 ,  C07C19/08

Abstract: A CATALYST IS DISCLOSED FOR PREPARING FLUORINATED OR CHLOROFLUORINATED HYDROCARBONS BY FLUORINATION OR CHLOREFLUORINATION OR DISPROPORTIONATION REACTIONS OR CHLOPHASE, WHICH CATALYST COMPRISES ALUMINUM FLUORIDE CONTAINING MINOR QUANTITIES OF ZINC, CHROMIUM, NICKEL AND PREFEABLY ALSO IRON COMPOUNDS WHICH ARE PRESENT IN QUANTITIES CORRESPONDING TO THE FOLLOWING PRECENTAGES BY WEIGHT OF METAL BASED ON THE TOTAL: FROM 0.05 TO 5% ZN, FROM 0.05 TO 5% CR, FROM 0.05 TO 5% NI, AND UP TO 3% FE. THE ZINCE, CHROMIUM, NICKEL AND IRON, IF ANY, ARE PRESENT AT LEAST PARTLY IN THE FORM OF HALIDES, IN PARTICULAR FLUORIDES, OR OXIDES OR OXY-HALIDES. A PROCESS FOR PARPARING THE CATALYST IS DISCLOSED, AS WELL AS VARIOUS DETAILS RELATING TO THE AFORESAID PROCESS FOR USING THE CATALYST.

公开(公告)号：US3787331A

公开(公告)日：1974-01-22

申请号：US3787331D

申请日：1969-10-07

Applicant: MONTEDISON SPA

Inventor： GROPPELLI G ,  FATTORE V ,  VECCHIO M ,  CASTELLAN A

IPC: C07C17/08 ,  B01J23/34 ,  B01J23/86 ,  B01J27/06 ,  C07B61/00 ,  C07C17/00 ,  C07C17/02 ,  C07C17/04 ,  C07C17/20 ,  C07C17/37 ,  C07C19/12 ,  C07C67/00 ,  B01J11/78

CPC classification number: C07C17/04 ,  B01J27/06 ,  C07C17/02 ,  C07C17/206 ,  C07C17/37 ,  C07C19/08 ,  C07C19/12

Abstract: A catalyst is disclosed for the preparation of fluroinated or chlorofluorinated hydrocarbons through fluorination or chlorofluorination reactions in gaseous phase, the catalyst comprising aluminum fluoride or fluorinated alumina containing minor quantities of manganese, chromium and preferably also nickel compounds present in quantities corresponding to the following percentages by weight of metal based on the total: from 0.05 to 5% of Mn, from 0.1 to 5% of Cr, and up to 5% of Ni. The manganese, the chromium and (when present) the nickel are at least partially present in the form of halides, and in particular the fluorides, or as oxides or as oxy-halides.

Abstract translation: 公开了一种催化剂，用于通过在气相中氟化或氯氟化反应来制备氟化或氯氟化烃，该催化剂包含含有少量锰，铬的氟化铝或氟化氧化铝，并且优选还含有以下列百分比的量存在的镍化合物： 基于总量的金属重量：Mn的0.05至5％，Cr的0.1至5％，以及至多5％的Ni。 锰，铬和（当存在时）镍至少部分以卤化物的形式存在，特别是氟化物，或作为氧化物或作为氧卤化物。