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公开(公告)号：US12134560B2
公开(公告)日：2024-11-05
申请号：US17420447
申请日：2020-01-16
Applicant: OHIO STATE INNOVATION FOUNDATION
Inventor： Liang-Shih Fan , Deven Baser , Andrew Tong , Sourabh G. Nadgouda , Fanhe Kong , Zhuo Cheng , Mandar Kathe
IPC: C01B3/40
Abstract: Systems and methods generally involve processing a gaseous reducing agent and a gaseous reforming agent to produce syngas in the presence of a stable-phase change metal-oxide based oxygen carrier. During operation, an oxygen content is measured for a reactor input stream and a reactor output stream. A percent oxygen depletion of the metal oxide is determined using an initial oxygen content of the metal oxide, the oxygen content of the input stream, and the oxygen content of the output stream. Based on the percent oxygen depletion, a mole ratio of reducing gas to oxidant in the input stream may be adjusted accordingly.
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公开(公告)号：US11767275B2
公开(公告)日：2023-09-26
申请号：US17952748
申请日：2022-09-26
Applicant: OHIO STATE INNOVATION FOUNDATION
Inventor： Liang-Shih Fan , Deven Baser , Sourabh Nadgouda , Anuj Joshi , Pinak Mohapatra
Abstract: Systems and methods include providing a gaseous alkane input stream and metal sulfide (MSx) particles that can react with an alkane in the gaseous alkane input stream to generate an alkene, a reduced metal sulfide (MSx−1) particle, and at least one of: hydrogen sulfide (H2S) and at least one sulfur containing compound selected from: S2, CS, and CS2. A product stream can be collected that includes the alkene and at least one of: hydrogen sulfide (H2S) and the at least one sulfur containing compound. A reduced metal sulfide (MSx−1) particle reacts with sulfur in a sulfur stream and can generate the metal sulfide (MSx) particle and hydrogen (H2).
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公开(公告)号：US20230009840A1
公开(公告)日：2023-01-12
申请号：US17952748
申请日：2022-09-26
Applicant: OHIO STATE INNOVATION FOUNDATION
Inventor： Liang-Shih Fan , Deven Baser , Sourabh Nadgouda , Anuj Joshi , Pinak Mohapatra
Abstract: Systems and methods include providing a gaseous alkane input stream and metal sulfide (MSx) particles that can react with an alkane in the gaseous alkane input stream to generate an alkene, a reduced metal sulfide (MSx-1) particle, and at least one of: hydrogen sulfide (H2S) and at least one sulfur containing compound selected from: S2, CS, and CS2. A product stream can be collected that includes the alkene and at least one of: hydrogen sulfide (H2S) and the at least one sulfur containing compound. A reduced metal sulfide (MSx-1) particle reacts with sulfur in a sulfur stream and can generate the metal sulfide (MSx) particle and hydrogen (H2).
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Patent Agency Ranking
公开(公告)号：US20220089511A1
公开(公告)日：2022-03-24
申请号：US17602889
申请日：2020-04-08
Applicant: OHIO STATE INNOVATION FOUNDATION
Inventor： Liang-Shih Fan , Deven Baser , Sourabh Nadgouda , Anuj Joshi , Pinak Mohapatra
Abstract: Systems and methods include providing a gaseous alkane input stream and metal sulfide (MSx) particles that can react with an alkane in the gaseous alkane input stream to generate an alkene, a reduced metal sulfide (MSx-1) particle, and at least one of: hydrogen sulfide (H2S) and at least one sulfur containing compound selected from: S2, CS, and CS2. A product stream can be collected that includes the alkene and at least one of: hydrogen sulfide (H2S) and the at least one sulfur containing compound. A reduced metal sulfide (MSx-1) particle reacts with sulfur in a sulfur stream and can generate the metal sulfide (MSx) particle and hydrogen (H2).
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公开(公告)号：US20220089438A1
公开(公告)日：2022-03-24
申请号：US17420447
申请日：2020-01-16
Applicant: OHIO STATE INNOVATION FOUNDATION
Inventor： Liang-Shih Fan , Deven Baser , Andrew Tong , Sourabh G. Nadgouda , Fanhe Kong , Zhuo Cheng , Mandar Kathe
IPC: C01B3/40
Abstract: Systems and methods generally involve processing a gaseous reducing agent and a gaseous reforming agent to produce syngas in the presence of a stable-phase change metal-oxide based oxygen carrier. During operation, an oxygen content is measured for a reactor input stream and a reactor output stream. A percent oxygen depletion of the metal oxide is determined using an initial oxygen content of the metal oxide, the oxygen content of the input stream, and the oxygen content of the output stream. Based on the percent oxygen depletion, a mole ratio of reducing gas to oxidant in the input stream may be adjusted accordingly.
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6.发明授权公开(公告)号：US12161969B2
公开(公告)日：2024-12-10
申请号：US17639884
申请日：2020-09-03
Applicant: OHIO STATE INNOVATION FOUNDATION
Inventor： Liang-Shih Fan , Deven Baser , Vedant Shah , Zhuo Cheng
Abstract: Exemplary reactor systems may include multiple reactors in fluid communication. Oxygen carrier particles comprising a support material and metal oxide can be provided to a first reactor along with flue gas comprising carbon dioxide (CO2). An output of the first reactor is free or substantially free of carbon dioxide (CO2). The oxygen carrier particles can then be provided to one or more reactors in the system along with a hydrocarbon stream and, in some instances, an oxidizing stream. Outlets from these one or more reactors may include hydrogen gas (H2), carbon monoxide (CO), and/or other species, depending upon the content of the hydrocarbon streams and the oxidizing streams.
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7.发明申请公开(公告)号：US20220331736A1
公开(公告)日：2022-10-20
申请号：US17639884
申请日：2020-09-03
Applicant: OHIO STATE INNOVATION FOUNDATION
Inventor： Liang-Shih Fan , Deven Baser , Vedant Shah , Zhuo Cheng
Abstract: Exemplary reactor systems may include multiple reactors in fluid communication. Oxygen carrier particles comprising a support material and metal oxide can be provided to a first reactor along with flue gas comprising carbon dioxide (CO2). An output of the first reactor is free or substantially free of carbon dioxide (CO2). The oxygen carrier particles can then be provided to one or more reactors in the system along with a hydrocarbon stream and, in some instances, an oxidizing stream. Outlets from these one or more reactors may include hydrogen gas (H2), carbon monoxide (CO), and/or other species, depending upon the content of the hydrocarbon streams and the oxidizing streams.
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公开(公告)号：US11453626B2
公开(公告)日：2022-09-27
申请号：US17602889
申请日：2020-04-08
Applicant: OHIO STATE INNOVATION FOUNDATION
Inventor： Liang-Shih Fan , Deven Baser , Sourabh Nadgouda , Anuj Joshi , Pinak Mohapatra
Abstract: Systems and methods include providing a gaseous alkane input stream and metal sulfide (MSx) particles that can react with an alkane in the gaseous alkane input stream to generate an alkene, a reduced metal sulfide (MSx-1) particle, and at least one of: hydrogen sulfide (H2S) and at least one sulfur containing compound selected from: S2, CS, and CS2. A product stream can be collected that includes the alkene and at least one of: hydrogen sulfide (H2S) and the at least one sulfur containing compound. A reduced metal sulfide (MSx-1) particle reacts with sulfur in a sulfur stream and can generate the metal sulfide (MSx) particle and hydrogen (H2).
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