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公开(公告)号：US3821324A
公开(公告)日：1974-06-28
申请号：US24538272
申请日：1972-04-19
Applicant: PHILLIPS PETROLEUM CO
Inventor： BERTUS B
Abstract: Organic compounds, particularly hydrocarbons, are oxidatively dehydrogenated to more unsaturated compounds by contact, under reaction conditions, with air, steam and a calcined solid catalyst composition comprising titanium, at least one component selected from the group consisting of tungsten or molybdenum, and at least one component selected from the group consisting of phosphorus, bismuth, lead, antimony or arsenic. Representative of such oxidative dehydrogenation processes is the conversion of butane to butenes and butadienes. Isopentenes are converted to isoprene using a catalyst comprising titanium, tungsten, bismuth and oxygen.
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公开(公告)号：US3852369A
公开(公告)日：1974-12-03
申请号：US36348573
申请日：1973-05-24
Applicant: PHILLIPS PETROLEUM CO
CPC classification number: B01J23/835 , B01J23/80 , B01J23/94 , B01J27/18 , C07C5/48 , Y02P20/584
Abstract: Organic compounds are dehydrogenated to compounds having a higher degree of unsaturation by contacting the feedstock in the vapor phase in the presence of an oxygen-containing gas with a catalyst comprising at least one of nickel, cobalt or iron in association with tin and phosphorus. Representative of such conversions is the oxidative dehydrogenation of butane to butenes and butadiene, isopentane to isoamylenes and isoprene, and butenes to butadiene. The conversion products are valuable compounds particularly useful as intermediates for the preparation of polymeric materials such as synthetic rubbers and the like.
Abstract translation: 通过在含氧气体存在下使气相中的原料与包含与锡和磷结合的镍，钴或铁中的至少一种的催化剂接触，将有机化合物脱氢为具有较高不饱和度的化合物。 这种转化的代表是将丁烷氧化成丁烯，丁二烯，异戊烷转化成异戊烯和异戊二烯，丁烯氧化成丁二烯。 转化产物是有价值的化合物，特别可用作制备聚合材料如合成橡胶等的中间体。
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公开(公告)号：US3856879A
公开(公告)日：1974-12-24
申请号：US30376672
申请日：1972-11-06
Applicant: PHILLIPS PETROLEUM CO
IPC: B01J27/053 , C07C5/48 , C07C5/18
CPC classification number: B01J27/053 , C07C5/48
Abstract: A dehydrogenatable feed is subjected to oxidative dehydrogenation conditions in the presence of an oxygencontaining gas and a catalyst consisting essentially of a metal sulfate containing from 0 to 30 mole percent excess metal in the form of free metal or metal oxide, the metal being nickel, cobalt, or iron.
Abstract translation: 在含氧气体和主要由含有0至30摩尔％的游离金属或金属氧化物形式的过量金属的金属硫酸盐组成的催化剂存在下，可脱氢的进料进行氧化脱氢条件，金属为镍 ，钴或铁。
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公开(公告)号：US3793391A
公开(公告)日：1974-02-19
申请号：US3793391D
申请日：1972-02-10
Applicant: PHILLIPS PETROLEUM CO
Inventor： BERTUS B
IPC: B01J23/835 , C07C5/48 , C07C3/28
CPC classification number: B01J23/835 , C07C5/48
Abstract: CATALYST COMPOSITIONS PREPARED FROM (I) A TRANSITION METAL COMPOUND, SUCH AS NICKEL OXIDE, (II) A TIN COMPOUND, AND (III) A GROUP II-A METAL COMPOUND, SUCH AS MAGNESIUM OXIDE, ARE EFFECTIVE IN A PROCESS TO CONVERT PARAFFINS OR MONOOLEFINS TO A GREATER DEGREE OF UNSATURATION.
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Patent Agency Ranking
公开(公告)号：US3810954A
公开(公告)日：1974-05-14
申请号：US24237372
申请日：1972-04-10
Applicant: PHILLIPS PETROLEUM CO
Inventor： BERTUS B
IPC: B01J23/888 , C07C5/48 , C07C5/18
CPC classification number: C07C5/48 , B01J23/888
Abstract: ORGANIC COMPOUNDS, PARTICULARLY HYDROCARBONS, ARE OXIDATIVELY DEHYDROGENATED TO MORE UNSATURATED COMPOUNDS BY CONTACT, UNDER REACTION CONDITIONS, WITH AIR, STEAM AND A CALCINED SOLID CATALYST COMPOSITION COMPRISING TUNGSTEN, TIN AND AT LEAST ONE METAL OF THE IRON SUBGROUP O GROUP VIII. IN ONE EMBODIMENT, ISOPENTENE IS COVERTED TO ISOPRENE OVER A NICKEL/TUNGSTEN/TIN/OXYGEN CATALYST AT A CONVERSION OF 36 PERCENT AND WITH A MODIVITY (MODIFIED SELECTIVITY) OF 72 PERCENT.
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公开(公告)号：US3793225A
公开(公告)日：1974-02-19
申请号：US3793225D
申请日：1971-05-06
Applicant: PHILLIPS PETROLEUM CO
CPC classification number: B01J27/18 , B01J23/8946 , C07C5/48 , Y10S585/906
Abstract: ORGANIC COMPOUNDS ARE DEHYDROGENATED TO COMPOUNDS HAVING A HIGHER DEGREE OF UNSATURATION BY CONTACTING THE FEEDSTOCK IN THE VAPOR PHASE AT AN ELEVATED TEMPERATURE IN THE PRESENCE OF AN OXYGEN-CONTAINING GAS WITH A CALCINED CATALYST CONTAINING A FERROUS GROUP METAL, E.G., NICKEL, IN COMBINATION WITH PHOSPHROUS, AT LEAST ONE GROUP IIA METAL AND OXYGEN. REPRESENTATIVE OF SUCH CONVERSIONS IS THE OXIDATIVE DEHYDROGENATION OF BUTANE TO 1,3-BUTADIENE. THE CONVERSION PRODUCTS ARE VALUABLE COMJPOUNDS PARTICULARYL USEFUL AS INTERMEDIATES FOR THE PREPARATION OF POLYMERIC MATERIALS SUCH AS SYNTHETIC RUBBERS AND THE LIKE.
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公开(公告)号：US3784627A
公开(公告)日：1974-01-08
申请号：US3784627D
申请日：1972-02-28
Applicant: PHILLIPS PETROLEUM CO
Inventor： BERTUS B
IPC: B01J27/02 , B01J27/057 , C07C5/48 , C07C3/28
CPC classification number: B01J27/02 , B01J27/0573 , B01J27/0576 , C07C5/48
Abstract: COMPOSITIONS PREPARED FROM (I) A TRANSITION METAL COMPOUND OF THE IRON GROUP, (II) A GROUP II-A METALCONTAINING COMPOUND, AND (III) GROUP VI-A ELEMENTCONTAINING COMPOUND, ARE EFFECTIVE IN A PROCESS TO CONVERT PARAFFINS OR MONOOLEFINS TO A GREATER DEGREE OF UNSATURATION.
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公开(公告)号：US3781223A
公开(公告)日：1973-12-25
申请号：US3781223D
申请日：1971-05-06
Applicant: PHILLIPS PETROLEUM CO
IPC: B01J23/80 , B01J23/835 , B01J23/94 , B01J27/18 , B01J27/185 , B01J11/82
CPC classification number: B01J23/835 , B01J23/80 , B01J23/94 , B01J27/18 , Y10S585/906
Abstract: ORGANIC COMPOUNDS ARE DEHYDROGENATED TO COMPOUNDS HAVING A HIGHER DEGREE OF UNSATURATION BY CONTACTING THE FEEDSTOCK IN THE VAPOR PHASE IN THE PRESENCE OF AN OXYGEN-CONTAINING GAS WITH A CATALYST COMPRISING AT LEAST ONE OF NICKEL, COBALT OR IRON IN ASSOCIATION WITH TIN AND PHOSPHORUS. REPRESENTATIVE OF SUCH CONVERSIONS IS THE OXIDATIVE DEHYDROGENATION OF BUTANE TO BUTENES AND BUTADIENE, ISOPENTANE TO ISOAMYLENES AND ISOPRENE, AND BUTENES TO BUTADIENE. THE CONVERSION PRODUCTS ARE VALUABLE COMPOUNDS PARTICULARLY USEFUL AS INTERMEDIATES FOR THE PREPARATION OF POLYMERIC MATERIALS SUCH AS SYNTHETIC RUBBERS AND THE LIKE.
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公开(公告)号：US3745194A
公开(公告)日：1973-07-10
申请号：US3745194D
申请日：1970-10-16
Applicant: PHILLIPS PETROLEUM CO
Inventor： BERTUS B , JOHNSTON H
IPC: B01J23/843 , C07C5/48 , C07C5/18
CPC classification number: B01J23/8437 , C07C5/48 , C07C11/12
Abstract: ORGANIC COMPOUNDS ARE DEHYDROGENATED TO COMPOUNDS HAVING A HIGHER DEGREE OF UNSATURATION BY CONTACTING THE FEEDSTOCKS IN THE VAPOR PHASE IN THE PRESENCE OF AN OXYGENCONTAINING GAS WITH A CATALYST CONTAINING TIN IN AN OXIDIZED STATE IN COMBINATION WITH AT LEAST ONE OF THE METALS BISMUTH, COBALT, OR NICKEL IN AN OXIDIZED STATE. REPRESENTATIVE OF SUCH CONVERSIONS IS THE OXIDATIVE DEHYDROGENATION OF BUTANE TO 1,3-BUTADIENE OVER A NICKEL STANNATE-CONTAINING CATALYST. THE CONVERSION PRODUCTS ARE VALUABLE COMPOUNDS PARTICULARLY USEFUL AS INTERMEDIATES FOR THE PREPATION OF POLYMERIC MATERIALS SUCH AS SYNTHETIC RUBBERS AND THE LIKEE.
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