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公开(公告)号:US12098244B2
公开(公告)日:2024-09-24
申请号:US17594169
申请日:2020-04-03
Applicant: ROQUETTE FRERES
Inventor: Nicolas Jacquel , Sarah Degras , Régis Mercier
CPC classification number: C08G65/405 , B01D71/522 , B01D71/68 , C08G65/4093 , C08G75/23 , C08G2650/26 , C08G2650/40 , C08G2650/64
Abstract: The invention relates to a process for producing semi-aromatic polyethers based on an aliphatic diol, to semi-aromatic polyethers based on an aliphatic diol obtained by said process, and to the use of said semi-aromatic polyethers based on an aliphatic diol for manufacturing membranes, manufactured parts and coatings.
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公开(公告)号:US10400062B2
公开(公告)日:2019-09-03
申请号:US15522726
申请日:2015-10-28
Applicant: Roquette Freres
Inventor: Nicolas Jacquel , René Saint-Loup , Françoise Fenouillot-Rimlinger , Jean-Pierre Pascault , Alain Rousseau
IPC: C08G63/02 , C08G63/54 , C08K3/22 , C08G63/672 , C08G63/84 , C08G63/86 , C08G63/127
Abstract: The invention concerns a method for producing a polyester containing at least one 1,4:3,6-dianhydrohexitol unit comprising: •a step of introducing, into a reactor, monomers comprising at least one monomer (A) that is a diacid or a diester and at least one monomer (B) that is a 1,4:3,6-dianhydrohexitol; •a step of introducing, into the reactor, a catalytic system comprising either a catalyst comprising the element germanium and a catalyst comprising the element aluminum, or a catalyst comprising the elements germanium and aluminum, or a mixture of said two catalysts; •a step of polymerizing said monomers to form the polyester; •a step of recovering a polyester composition comprising the polyester and the catalytic system. The invention also concerns a polyester composition containing a catalytic system comprising either a catalyst comprising the element germanium and a catalyst comprising the element aluminum, or a catalyst comprising the elements germanium and aluminum, or a mixture of said two catalysts, and the use of same to reduce the coloring of the polyester.
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3.
公开(公告)号:US20170335055A1
公开(公告)日:2017-11-23
申请号:US15522726
申请日:2015-10-28
Applicant: Roquette Freres
Inventor: Nicolas Jacquel , René Saint-Loup , Françoise Fenouillot-Rimlinger , Jean-Pierre Pascault , Alain Rousseau
IPC: C08G63/54 , C08G63/127 , C08G63/84 , C08G63/86
CPC classification number: C08G63/54 , C08G63/127 , C08G63/672 , C08G63/84 , C08G63/863 , C08K3/22 , C08L67/025
Abstract: The invention concerns a method for producing a polyester containing at least one 1,4:3,6-dianhydrohexitol unit comprising:·a step of introducing, into a reactor, monomers comprising at least one monomer (A) that is a diacid or a diester and at least one monomer (B) that is a 1,4:3,6-dianhydrohexitol;·a step of introducing, into the reactor, a catalytic system comprising either a catalyst comprising the element germanium and a catalyst comprising the element aluminum, or a catalyst comprising the elements germanium and aluminum, or a mixture of said two catalysts;·a step of polymerising said monomers to form the polyester;·a step of recovering a polyester composition comprising the polyester and the catalytic system. The invention also concerns a polyester composition containing a catalytic system comprising either a catalyst comprising the element germanium and a catalyst comprising the element aluminum, or a catalyst comprising the elements germanium and aluminum, or a mixture of said two catalysts, and the use of same to reduce the colouring of the polyester.
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公开(公告)号:US20140288239A1
公开(公告)日:2014-09-25
申请号:US14352370
申请日:2012-10-16
Applicant: ROQUETTE FRERES
Inventor: Nicolas Jacquel , Rene Saint-Loup , Francoise Fenouillot-Rimlinger , Jean-Pierre Pascault , Alain Rousseau
IPC: C08K3/36
CPC classification number: C08K3/36 , C08J3/201 , C08J5/18 , C08J2367/02 , C08L67/02
Abstract: The present invention relates to PBS- and silica-based composites, said composites having a high swelling ability. It also relates to a method of preparing said composites, a method of swelling said composites and films obtained by swelling said composites.
Abstract translation: 本发明涉及PBS-和二氧化硅基复合材料,所述复合材料具有高的溶胀能力。 它还涉及一种制备所述复合材料的方法,一种膨胀所述复合材料的方法和通过溶胀所述复合材料获得的薄膜。
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公开(公告)号:US12037453B2
公开(公告)日:2024-07-16
申请号:US17269637
申请日:2019-08-20
Applicant: ROQUETTE FRERES , UNIVERSITE CLAUDE BERNARD LYON 1 , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
Inventor: Nicolas Jacquel , Sarah Degras , Régis Mercier , Thierry Delaunay
CPC classification number: C08G65/4056 , B01D71/522 , C08G75/20 , B01D71/68 , C08G2650/48
Abstract: The present invention relates to a polymer of the aromatic polyether type, containing a biosourced furan diol, to a method for producing said polymer, and to the use of said polymer for producing membranes.
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公开(公告)号:US11859046B2
公开(公告)日:2024-01-02
申请号:US15576205
申请日:2016-05-20
Applicant: Roquette Freres
Inventor: Nicolas Jacquel , René Saint-Loup , Jean-Pierre Pascault , Françoise Fenouillot , Alain Rousseau
IPC: C08G63/80 , C08G63/672 , C08G63/78 , C08G63/183 , C08G63/91
CPC classification number: C08G63/80 , C08G63/183 , C08G63/672 , C08G63/78 , C08G63/916
Abstract: The invention relates to a thermoplastic polymer comprising at least one 1,4:3,6-dianhydrohexitol unit (A), at least one alicyclic diol unit (B) other than the 1,4:3,6-dianhydrohexitol units (A) and at least one high-viscosity terephthalic acid unit (C).
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7.
公开(公告)号:US20220267514A1
公开(公告)日:2022-08-25
申请号:US17059948
申请日:2019-05-29
Applicant: ROQUETTE FRERES
Inventor: Nicolas Jacquel , René Saint-Loup , Audrey Dausque , Sébastien Naudin , Nicolas Descamps
IPC: C08G63/80 , C08G63/672
Abstract: The invention relates to the field of polymers and concerns a method for the crystallization of polyester. More particularly, it relates to a crystallization method that comprises a step of providing a polyester comprising at least one 1,4:3,6-dianhydrohexitol unit, and a step of crystallizing said semi-crystalline polyester, said method being characterized in that the crystallization step is performed at a pressure of at least 600 mbar absolute. The method according to the invention makes it possible to strongly limit, or even eliminate, the phenomenon of polyester expansion during crystallization. Advantageously, the elimination of the expansion phenomenon through pressure conditions implemented according to the invention thus makes it possible to dispense with obtaining very fragile empty spheres that break when agitated and thus cause the formation of undesirable fine particles.
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公开(公告)号:US11130860B2
公开(公告)日:2021-09-28
申请号:US16608986
申请日:2018-05-07
Applicant: ROQUETTE FRERES
Inventor: Hélène Amedro , Jean-Marc Corpart , Nicolas Jacquel , René Saint-Loup
Abstract: A thermoplastic composite comprising a thermoplastic polymer matrix comprising an amorphous polyester containing 1,4: 3,6-dianhydrohexitol units, an alicyclic diol and terephthalic acid, wherein diol component comprises 1,4:3,6-dianhydrohexitol and alicyclic diol in ratio from 0.32 to 0.75; and thermoplastic fibers comprising a semi-crystalline polyester containing 1,4: 3,6-dianhydrohexitol units, an alicyclic diol and terephthalic acid, wherein diol component comprises 1,4:3,6-dianhydrohexitol and alicyclic diol in ratio from 0.05 to 0.30 are disclosed. Methods for producing the polymer composite are also disclosed.
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公开(公告)号:US09346937B2
公开(公告)日:2016-05-24
申请号:US14352370
申请日:2012-10-16
Applicant: ROQUETTE FRERES
Inventor: Nicolas Jacquel , Rene Saint-Loup , Francoise Fenouillot-Rimlinger , Jean-Pierre Pascault , Alain Rousseau
CPC classification number: C08K3/36 , C08J3/201 , C08J5/18 , C08J2367/02 , C08L67/02
Abstract: The present invention relates to PBS- and silica-based composites, said composites having a high swelling ability. It also relates to a method of preparing said composites, a method of swelling said composites and films obtained by swelling said composites.
Abstract translation: 本发明涉及PBS-和二氧化硅基复合材料,所述复合材料具有高的溶胀能力。 它还涉及一种制备所述复合材料的方法,一种膨胀所述复合材料的方法和通过溶胀所述复合材料获得的薄膜。
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10.
公开(公告)号:US12134680B2
公开(公告)日:2024-11-05
申请号:US17059948
申请日:2019-05-29
Applicant: ROQUETTE FRERES
Inventor: Nicolas Jacquel , René Saint-Loup , Audrey Dausque , Sébastien Naudin , Nicolas Descamps
IPC: C08G63/80 , C08G63/672
Abstract: A crystallization method that comprises a step of providing a polyester comprising at least one 1,4:3,6-dianhydrohexitol unit, and a step of crystallizing this semi-crystalline polyester at a pressure of at least 600 mbar absolute. The method according to the invention makes it possible to strongly limit, or even eliminate, the phenomenon of polyester expansion during crystallization. Advantageously, the elimination of the expansion phenomenon through pressure conditions implemented according to the invention thus makes it possible to dispense with obtaining very fragile empty spheres that break when agitated and thus cause the formation of undesirable fine particles.
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