公开(公告)号：US20230265221A1

公开(公告)日：2023-08-24

申请号：US18005175

申请日：2021-07-13

Applicant: SABIC Global Technologies B.V.

Inventor： Liheng WU ,  Dick NAGAKI ,  Jun WANG ,  Kaiwalya SABNIS ,  Xianghua YU ,  Travis CONANT ,  Paulette HAZIN

IPC: C08F4/80 ,  C08F8/04 ,  C08F4/02 ,  C08F12/08

CPC classification number: C08F4/80 ,  C08F8/04 ,  C08F4/025 ,  C08F12/08

Abstract: Catalysts for the hydrogenation of aromatic containing polymers are described. Such a catalyst can include, based on the total weight of the catalyst, 99.1 wt. % to 99.95 wt. % of a metal oxide support, and 0.05 wt. % to 0.9 wt. % of catalytic metal nanoparticles comprising platinum (Pt), palladium (Pd), ruthenium (Ru), any combination thereof, or alloy thereof. The catalyst can have a specific surface area of 5 m2/g to 80 m2/g, a pore volume of 0.01 cm3/g to 0.35 cm3/g, and a catalyst median particle size of less than 300 microns. Processes to produce the catalyst and methods of hydrogenating aromatic containing polymers are also described.

公开(公告)号：US20180362419A1

公开(公告)日：2018-12-20

申请号：US16062541

申请日：2017-01-05

Applicant: SABIC Global Technologies B.V.

Inventor： Xin LI ,  Jorge JIMENEZ ,  Paulette HAZIN ,  Reggie TENNYSON ,  Xiankuan ZHANG

IPC: C07C5/48 ,  C07C11/167 ,  B01J23/00 ,  B01J27/10

CPC classification number: C07C5/48 ,  B01J23/002 ,  B01J23/80 ,  B01J27/10 ,  B01J2523/00 ,  B01J2523/22 ,  B01J2523/23 ,  B01J2523/27 ,  B01J2523/842 ,  B01J2523/845 ,  C07C11/167 ,  C07C2523/02 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/80

Abstract: Methods for producing butadiene by the oxidative dehydrogenation of butene are provided. Methods for producing butadiene from a feed stream including oxygen and butene in a molar ratio of oxygen to butene (O2/C4H8) from about 0.9 to about 1.5 can include introducing the feed stream to a catalyst in the presence of steam. The molar ratio of steam to butene (H2O/C4H8) can be from about 10 to about 20. Methods can further include reacting the butene to generate a product stream therefrom comprising butadiene and water. Methods can further include separating water from the product stream to generate a butadiene stream including greater than about 85 wt-% butadiene.

公开(公告)号：US20250163193A1

公开(公告)日：2025-05-22

申请号：US18869578

申请日：2023-07-13

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Paulette HAZIN ,  Kaiwalya SABNIS ,  Reginald TENNYSON ,  Travis CONANT

IPC: C08F8/04 ,  C08F112/08

Abstract: Methods for the hydrogenation of aromatic-containing polymers are described. A method includes hydrogenation of polymers by contacting a polymer solution that includes an aromatic-containing polymer and a mixture of a non-polar solvent and a polar solvent having a dielectric constant greater than 7.6 at 25° C. and a non-polar solvent having a dielectric constant of 5 or less at 25° C. with a hydrogenation catalyst to produce polymer composition that includes at least one hydrogenated and/or at least one partially hydrogenated aromatic ring. The polar to non-polar solvent volume ratio ranges from 10:90 to 80:20.

公开(公告)号：US20240352159A1

公开(公告)日：2024-10-24

申请号：US18682304

申请日：2022-08-10

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Nicolaas Hendrika Friederichs ,  William GAUTHIER ,  Paulette HAZIN

IPC: C08F4/76 ,  C08F110/04 ,  C08F110/14

CPC classification number: C08F4/76 ,  C08F110/04 ,  C08F110/14

Abstract: The invention relates to a process for preparing polyalpha-olefins using a catalyst composition comprising a reaction product of an organometallic complex and a co-catalyst, wherein the comprising an organometallic complex is represented by the general formula: LMXn wherein: (i) ‘L’ is an organic ligand; (ii) ‘M’ is a transition metal having a valency of ‘p’, wherein the metal ‘M’ is selected from Ti, Zr, and Hf; (iii) ‘X’ is an anionic ligand to the metal ‘M’, and wherein ‘X’ is selected from the group consisting of halogens, alkyls, aralkyls, alkoxides, amides, and combinations thereof; (iv) ‘n’ is the number of ‘X’ groups and equals p-2.