公开(公告)号：US20150038758A1

公开(公告)日：2015-02-05

申请号：US14341917

申请日：2014-07-28

Applicant: SAMSUNG TOTAL PETROCHEMICALS CO., LTD.

Inventor： Gle PARK ,  Yeon Shick YOO ,  Jin Suk LEE ,  Ho Sik CHANG ,  Chang Hyun CHOI ,  In Kyu SONG ,  Hyun SEO ,  Jong Kwon LEE

IPC: B01J23/62 ,  B01J23/63 ,  C07C5/32

CPC classification number: B01J23/626 ,  B01J23/63 ,  B01J37/0207 ,  B01J37/0244 ,  C07C5/3337 ,  C07C2521/04 ,  C07C2523/62 ,  C07C2523/63 ,  C07C11/08

Abstract: The provided is a method for preparing a platinum-tin-metal-alumina catalyst by comprising: as an active ingredient, platinum which has a high activity in a direct dehydrogenation reaction of n-butane, tin which can increase the catalyst stability by preventing carbon deposition; additionally metal for reducing the level of catalyst inactivation over the reaction time; and an alumina carrier for supporting said components. Further, provided is a method for producing a high value product, C4 olefins from low cost n-butane by using the catalyst prepared by the method according to the present invention in a direct dehydrogenation reaction.

Abstract translation: 所提供的是一种铂 - 锡 - 金属 - 氧化铝催化剂的制备方法，其包括：作为活性成分，在正丁烷，锡的直接脱氢反应中具有高活性的铂，其可以通过防止碳增加催化剂的稳定性 沉积 额外的金属，用于在反应时间内降低催化剂失活水平; 和用于支撑所述组分的氧化铝载体。 此外，通过使用通过本发明的方法制备的催化剂在直接脱氢反应中提供了从低成本正丁烷制备高价值产物C4烯烃的方法。

公开(公告)号：US20140309470A1

公开(公告)日：2014-10-16

申请号：US14249955

申请日：2014-04-10

Applicant: SAMSUNG TOTAL PETROCHEMICALS CO., LTD.

Inventor： Gle PARK ,  Yeon Shick YOO ,  Young Jin CHO ,  Jin Suk LEE ,  Ho Sik CHANG ,  Chang Hyun CHOI ,  In Kyu SONG ,  Jong Kwon LEE ,  Hyun SEO

IPC: B01J23/62 ,  C07C5/32

CPC classification number: B01J23/626 ,  B01J37/0244 ,  C07C5/325 ,  C07C5/3337 ,  C07C2521/04 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/62 ,  C07C11/08

Abstract: The provided is a preparation method of a platinum/tin/alumina catalyst which comprises platinum as an active component having high activity to direct dehydrogenation of n-butane, tin capable of preventing platinum particles from being sintered and maintaining a size of the platinum particles to be small, thereby improving dispersibility and increasing an amount at an active site during the dehydrogenation and also capable of suppressing carbon deposition, thereby increasing stability of the catalyst, and as an support for supporting them, an alumina support which is known as being suitable for direct dehydrogenation of n-butane and is capable of maintaining high dispersibility of the platinum with high thermal and mechanical stability, and a method for producing high value-added C4 olefins through direct dehydrogenation of inexpensive n-butane by using the catalyst prepared by the preparation method.

Abstract translation: 提供了铂/锡/氧化铝催化剂的制备方法，其包括铂作为活性成分，具有高直接脱氢正丁烷的活性，能够防止铂颗粒烧结的锡和将铂颗粒的尺寸维持在 从而提高分散性，并且在脱氢过程中提高活性部位的分散性，并且还能够抑制碳沉积，从而提高催化剂的稳定性，并且作为支撑它们的载体，已知适合于 正丁烷的直接脱氢能够维持高的热和机械稳定性的铂的高分散性，以及通过使用制备的催化剂直接脱氢廉价的正丁烷来生产高附加值的C4烯烃的方法 方法。