Abstract:
The invention relates to a method of treating a hydrocarbon containing formation, comprising the following steps: a) providing a composition comprising a surfactant to at least a portion of the hydrocarbon containing formation, wherein the surfactant is a compound of the formula (I) R—O—[R′—O]x—X wherein R is a hydrocarbyl group, R′—O is an alkylene oxide group, x is the number of alkylene oxide groups R′—O, and X is a group comprising a carboxylate moiety; b) allowing the surfactant from the composition to interact with the hydrocarbons in the hydrocarbon containing formation; c) recovering from the hydrocarbon containing formation an emulsion comprising hydrocarbons, water and the surfactant; and d) adding an acid to the emulsion thus recovered.