Abstract:
A hydrocarbon recovery composition which comprises a first blend of C24-28 internal olefin sulfonates and an injectable fluid composition comprising the hydrocarbon recovery composition, water and/or brine wherein the hydrocarbon recovery composition is present in an amount of from 0.05 to 1.0 wt % of the total injectable fluid composition can be used for enhanced hydrocarbon recovery from a formation.
Abstract:
The invention relates to nonyl alcohols with a low degree of branching and derivatives produced using them. In particular the present invention relates to mixture of primary nonyl alcohols in which at least 80% of the alkyl chains are linear and at least 15% of the alkyl chains are branched at the 2-carbon position and its derivatives. The low degree of branching produces derivatives that are more elongated and less bulky that similar derivatives produced with more highly branched alcohols.
Abstract:
The present invention provides a method for predicting the optimal salinity of individual members of a class of internal olefin sulfonate compositions in a mixture containing the individual member, a brine and hydrocarbons, wherein the internal olefin sulfonate compositions comprise a mixture containing hydroxy alkane sulfonates and alkene sulfonates. The invention further provides use of the weight ratio of hydroxy alkane sulfonates to alkene sulfonates in an internal olefin sulfonate composition to predict the optimal salinity of the surfactant composition in a mixture of the surfactant composition, a brine and an oil.
Abstract:
The invention relates to a method of treating a hydrocarbon containing formation, comprising the following steps: a) preparing an internal olefin sulfonate, comprising sulfonating an internal olefin into sulfonated internal olefin followed by contacting sulfonated internal olefin with a base containing solution resulting in the internal olefin sulfonate, wherein sulfonated internal olefin is contacted with the base containing solution in the presence of a non-ionic surfactant, and/or after step a) but before step b), the internal olefin sulfonate and said non-ionic surfactant are combined; b) transporting an aqueous solution comprising the internal olefin sulfonate and the non-ionic surfactant to the location of the hydrocarbon containing formation; c) providing the internal olefin sulfonate and the non-ionic surfactant to at least a portion of the hydrocarbon containing formation; and d) allowing the internal olefin sulfonate and the non-ionic surfactant to interact with the hydrocarbons in the hydrocarbon containing formation.
Abstract:
The invention relates to a process for preparing an internal olefin sulfonate, comprising sulfonating an internal olefin into sulfonated internal olefin followed by contacting sulfonated internal olefin with a base containing solution, wherein the molar ratio of internal olefin to solvent for the base is higher than 0.06. Further, the invention relates to an internal olefin sulfonate obtainable by said process.
Abstract:
A surfactant composition, which comprises (i) an internal olefin sulfonate and (ii) an alkoxylated alcohol and/or alkoxylated alcohol derivative, wherein the alkoxylated alcohol and/or alkoxylated alcohol derivative is a compound of the formula (I) R—O—[PO]x[EO]y—X wherein R is a hydrocarbyl group which has a weight average carbon number of from 5 to 32, PO is a propylene oxide group, EO is an ethylene oxide group, x is the number of propylene oxide groups and is of from 0 to 40, y is the number of ethylene oxide groups and is of from 0 to 50, and the sum of x and y is of from 5 to 60; and wherein X is selected from the group consisting of: (i) a hydrogen atom; (ii) a group comprising a carboxylate moiety; (iii) a group comprising a sulfate moiety; and (iv) a group comprising a sulfonate moiety.
Abstract:
The invention relates to a process for preparing an internal olefin sulfonate, comprising sulfonating an internal olefin, having an average carbon number that is equal to or greater than 20, in a sulfonation reactor into sulfonated internal olefin followed by contacting sulfonated internal olefin with a base containing solution, wherein the sulfonation reactor is cooled with a cooling means having a temperature which is greater than 35° C. Further, the invention relates to an internal olefin sulfonate obtainable by said process, and to use of internal olefin sulfonates obtainable or obtained by said process as a surfactant, suitably as a surfactant in chemical Enhanced Oil Recovery.
Abstract:
The invention relates to a process for preparing an internal olefin sulfonate, comprising sulfonating an internal olefin into sulfonated internal olefin followed by contacting sulfonated internal olefin with a base containing solution, wherein the molar ratio of internal olefin to solvent for the base is higher than 0.06. Further, the invention relates to an internal olefin sulfonate obtainable by said process.
Abstract:
The present invention provides an internal olefin sulfonate composition, comprising water and an internal olefin sulfonate mixture having an average carbon number of at least 20, wherein the internal olefin sulfonate mixture comprises hydroxy sulfonates and alkene sulfonates in a weight ratio of hydroxy sulfonates to alkene sulfonates of at least 3.25. The invention further provides a method of treating a crude oil containing formation.
Abstract:
The invention relates to a process for preparing an internal olefin sulfonate, comprising sulfonating an internal olefin, having an average carbon number that is equal to or greater than 20, in a sulfonation reactor into sulfonated internal olefin followed by contacting sulfonated internal olefin with a base containing solution, wherein the sulfonation reactor is cooled with a cooling means having a temperature which is greater than 35° C. Further, the invention relates to an internal olefin sulfonate obtainable by said process, and to use of internal olefin sulfonates obtainable or obtained by said process as a surfactant, suitably as a surfactant in chemical Enhanced Oil Recovery.