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公开(公告)号:US10221370B2
公开(公告)日:2019-03-05
申请号:US14207736
申请日:2014-03-13
Applicant: SHELL OIL COMPANY
Inventor: Pen-Chung Wang , Paul Richard Weider , Robert Lawrence Blackbourn
Abstract: A novel method of separating bio oil (pyrolysis oil) into oxygenated rich species and lignin/phenolic based species in a highly efficient manner is provided. Lignin and phenolic fractions can be separated from light oxygenates from bio oil by use of reversible α-hydroxysulfonic acid.
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公开(公告)号:US08900833B2
公开(公告)日:2014-12-02
申请号:US13687806
申请日:2012-11-28
Applicant: Shell Oil Company
Inventor: Pen-Chung Wang , Joseph James Alishusky , Robert Lawrence Blackbourn , Paul Richard Weider
Abstract: A method of obtaining lipids from microbial biomass such as algae is provided by treating microbial biomass with a solution containing at least one α-hydroxysulfonic acid to extract and recover liposoluble components. The α-hydroxysulfonic acid can be easily removed from the product containing liposoluble components and recycled.
Abstract translation: 通过用含有至少一种α-羟基磺酸的溶液处理微生物生物质来提取和回收脂溶性组分,提供从微生物生物质如藻类获得脂质的方法。 α-羟基磺酸可以容易地从含有脂溶性组分的产物中除去并再循环。
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公开(公告)号:US10920131B2
公开(公告)日:2021-02-16
申请号:US15754428
申请日:2016-08-29
Applicant: SHELL OIL COMPANY
Inventor: Robert Lawrence Blackbourn , Jonathan Joseph Brege , Paul Richard Weider , Allen Dale Gabrysch , Andrew James Murphy , Lorna Beatriz Ortiz-Soto , Ryan Matthew Van Zanten
Abstract: A weighted acid composition comprising an acid, a brine, and an amino acid and associated methods.
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公开(公告)号:US10787606B2
公开(公告)日:2020-09-29
申请号:US16564448
申请日:2019-09-09
Applicant: SHELL OIL COMPANY
Inventor: Paul Richard Weider , Robert Lawrence Blackbourn , Jonathan Joseph Brege , Allen Dale Gabrysch , Andrew James Murphy , Lorna Beatriz Ortiz-Soto , Ryan Matthew Van Zanten
Abstract: A weighted acid composition comprising an acid, a brine, and an amino acid and associated methods.
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公开(公告)号:US10138218B2
公开(公告)日:2018-11-27
申请号:US15502897
申请日:2015-08-13
Applicant: SHELL OIL COMPANY
Inventor: Juben Nemchand Chheda , Paul Richard Weider , Robert Lawrence Blackbourn , Jean Paul Andre Marie Joseph Ghislain Lange
IPC: C07D307/50
Abstract: Furfural is produced from biomass material containing pentosan, in high yields, in a production process comprising treating the biomass with a solution containing at least one α-hydroxysulfonic acid thereby hydrolyzing the biomass to produce a product stream containing at least one C5-carbohydrate compound in monomeric and/or oligomeric form, and dehydrating the C5-carbohydrate compound in the presence of a heterogeneous solid acid catalyst, in a biphasic reaction medium comprising an aqueous phase and a water-immiscible organic phase, at a temperature in the range of from about 100° C. to about 250° C. to produce a dehydration product stream containing furfural. An aqueous stream is separated from the dehydration product, which can be optionally recycled to the hydrolysis step.
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公开(公告)号:US09428816B2
公开(公告)日:2016-08-30
申请号:US13715311
申请日:2012-12-14
Applicant: SHELL OIL COMPANY
CPC classification number: C13K13/00 , C12P7/06 , C12P7/08 , C12P7/10 , C12P7/14 , C12P2201/00 , C12P2203/00 , C13K1/02 , C13K13/002 , Y02E50/16 , Y02E50/17
Abstract: A method of treating ethanol production byproduct is provided by treating wet distillers grain or stillage with a solution containing at least one α-hydroxysulfonic acid to produce at least one fermentable sugar containing product. Fermentable sugar useful for the production of biofuels or ethanol can be produced from such methods. The α-hydroxysulfonic acid can be easily removed from the product and recycled.
Abstract translation: 一种处理乙醇生产副产物的方法是通过用含有至少一种α-羟基磺酸的溶液处理湿蒸馏器谷物或釜馏塔以产生至少一种可发酵的含糖产品来提供的。 可以通过这些方法生产用于生产生物燃料或乙醇的发酵糖。 α-羟基磺酸可以容易地从产品中除去并再循环。
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公开(公告)号:US09212401B2
公开(公告)日:2015-12-15
申请号:US13804845
申请日:2013-03-14
Applicant: SHELL OIL COMPANY
Inventor: Paul Richard Weider , Robert Lawrence Blackbourn
CPC classification number: C13K13/002 , C08H8/00 , C13K1/02 , C13K1/04
Abstract: Fermentable sugar useful for the production of biofuels can be produced from biomass by contacting the biomass with a solution containing at least one α-hydroxysulfonic acid. The α-hydroxysulfonic acid can be easily removed from the product and recycled.
Abstract translation: 通过使生物质与含有至少一种α-羟基磺酸的溶液接触,可以通过生物质生产用于生产生物燃料的发酵糖。 α-羟基磺酸可以容易地从产品中除去并再循环。
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公开(公告)号:US12049659B2
公开(公告)日:2024-07-30
申请号:US17297225
申请日:2019-11-26
Applicant: SHELL OIL COMPANY
Inventor: Carolina Botella-Franco , Sivakumar Sadasivan Vijayakumari , Robert Lawrence Blackbourn , Paul Richard Weider , Ye-Mon Chen , Yi Liang , Daniel Gagne , Ashley Villarreal Baugh
CPC classification number: C12P7/10
Abstract: Methods for production of ethanol, distiller's corn oil, and enhanced co-products are disclosed. Methods include obtaining a mixture of one or more co-products of an alcohol production process, which may include wet cake, performing hydrolysis of polysaccharides in the mixture to generate fermentable sugars, fermenting the fermentable sugars in the mixture to produce alcohol, distilling the mixture to remove alcohol from the mixture thereby producing alcohol-containing distillate and enhanced whole stillage, removing released oil from the fermented mixture before distillation and/or from the enhanced whole stillage after distillation, and recovering enhanced wet distiller's grains, enhanced thin stillage, and/or enhanced dried distiller's grains. Compositions disclosed herein include enhanced dried distiller's grains having a crude protein content of at least 45% on a dry weight basis and having a total fat content of less than 10% on a dry weight basis.
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公开(公告)号:US11156074B2
公开(公告)日:2021-10-26
申请号:US16561646
申请日:2019-09-05
Applicant: SHELL OIL COMPANY
Inventor: Paul Richard Weider , Robert Lawrence Blackbourn , Ying Zhang , Lee Nicky Morgenthaler , Ryan Matthew Van Zanten
Abstract: An acid-generating fluid includes a thermally activated strong acid precursor. The thermally activated strong acid precursor can include a component selected from aldehydes, ketones, and combinations thereof, in combination with a precursor of a compound adapted to react to liberate sulfur dioxide; or it can include sulfur dioxide in combination with a precursor of a compound adapted to react to liberate a component selected from aldehydes, ketones, and combinations thereof.
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公开(公告)号:US10961595B2
公开(公告)日:2021-03-30
申请号:US14993453
申请日:2016-01-12
Applicant: SHELL OIL COMPANY
Inventor: Paul Richard Weider , Robert Lawrence Blackbourn
Abstract: Fermentable sugar useful for the production of biofuels can be produced from biomass by contacting the biomass with a solution containing at least one α-hydroxysulfonic acid. The α-hydroxysulfonic acid can be easily removed from the product and recycled.
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