公开(公告)号：US20160090429A1

公开(公告)日：2016-03-31

申请号：US14786196

申请日：2014-04-16

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Vito TORTELLI ,  Cristiano MONZANI ,  Claudio OLDANI ,  Luca MERLO

IPC: C08F214/26 ,  C08L27/18

CPC classification number: C08F214/262 ,  C08F2216/1475 ,  C08L27/18 ,  C08F2216/1491

Abstract: The present invention pertains a fluoropolymer [polymer (F)] comprising: —recurring units derived from at least one ethylenically unsaturated fluorinated monomer [monomer (FM)]; —from 5% to 60% by moles [with respect to the total moles of recurring units of polymer (F)] of recurring units derived at least one ethylenically unsaturated fluorinated monomer containing at least one —SO2F functional group [monomer (IO)]; and —from 0.01% to 10% by moles [with respect to the total moles of recurring units of polymer (F)] of recurring units derived from at least one monomer comprising an azide group [monomer (Az)], to a process for its manufacture, to a cross-linkable composition comprising the same, to a process for cross-linking the same and to articles comprising the cross-linked polymer.

Abstract translation: 本发明涉及含氟聚合物[聚合物（F）]，其包含： - 由至少一种烯键式不饱和氟化单体[单体（FM）]衍生的重复单元; - 至少一种含有至少一个-SO 2 F官能团的烯键式不饱和氟化单体[单体（I）]的5％至60％摩尔[相对于聚合物（F）的重复单元的总摩尔数）]的重复单元 ; 和相对于衍生自包含叠氮化物基团[单体（Az）]的至少一种单体的重复单元的相对于聚合物（F）的重复单元的总摩尔数）为0.01〜10摩尔％ 其制造方法涉及含有该组合物的可交联组合物，涉及其交联方法和包含交联聚合物的制品。

公开(公告)号：US20170198065A1

公开(公告)日：2017-07-13

申请号：US15245868

申请日：2016-08-24

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Alessandro VENERONI ,  Claudio OLDANI ,  Martina CORASANITI ,  Alessandro GHIELMI

IPC: C08F6/22 ,  C08J5/22 ,  C08J5/18 ,  C08F214/26

CPC classification number: C08F6/22 ,  C08F2/22 ,  C08F14/18 ,  C08F214/18 ,  C08F214/26 ,  C08J5/18 ,  C08J5/225 ,  C08J2327/12 ,  C08J2327/18 ,  C08L27/12 ,  C08F2/04

Abstract: The invention relates to a process for the isolation of (per)fluorinated polymers containing sulfonyl fluoride functional groups from a polymerization latex. The process comprises adding the polymerization latex to an aqueous electrolyte solution under high shear stirring at a temperature equal to or lower than the glass transition temperature of the polymer. The invention further relates to the (per)fluorinated polymers containing sulfonyl fluoride functional groups isolated by the process and characterised by a loss of weight at 200° C. lower than 1% as determined by thermogravimetric analysis.

公开(公告)号：US20200017621A1

公开(公告)日：2020-01-16

申请号：US16495094

申请日：2018-03-15

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Luca MERLO ,  Claudio OLDANI

IPC: C08F259/08 ,  C08F14/18 ,  C08F2/22

Abstract: The invention pertains to a method of making fluoropolymer dispersions using certain polymeric derivatives including a plurality of ionisable groups selected from the group consisting of —SO3Xa, —PO3Xa and —COOXa, whereas Xa is H, an ammonium group or a monovalent metal, and to fluoropolymer dispersions therefrom.

公开(公告)号：US20210380741A1

公开(公告)日：2021-12-09

申请号：US17284010

申请日：2019-11-04

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Luca MERLO ,  Claudio OLDANI

IPC: C08F216/14 ,  C09D129/10

Abstract: The present invention relates to certain dispersible ionomer powders made of particles consisting in quasi-spherical hollow agglomerates of elementary particles, to a method for their manufacture involving spray-drying of a latex of said ionomer, and to methods of using the same, notably for coating applications.

公开(公告)号：US20190273287A1

公开(公告)日：2019-09-05

申请号：US16334731

申请日：2017-09-12

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.p.A.

Inventor： Luca MERLO ,  Christine HAMON ,  Claudio OLDANI

IPC: H01M10/42 ,  H01M10/0525 ,  H01M4/36 ,  H01M4/1395 ,  H01M4/134 ,  C08F214/18 ,  C09D127/12

Abstract: The present invention provides a multilayer assembly comprising a metallic layer, that is coated at least on one side with a polymeric composition, a method for the preparation of said assembly and an electrochemical cell comprising said multilayer assembly.

公开(公告)号：US20200017620A1

公开(公告)日：2020-01-16

申请号：US16495093

申请日：2018-03-15

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Luca MERLO ,  Claudio OLDANI ,  Alessio MARRANI ,  Fiorenza D'APRILE ,  Valeriy KAPELYUSHKO

IPC: C08F259/08

Abstract: The invention pertains to a method of making fluoropolymer dispersions using certain reactive oligomeric dispersing agents, of given molecular weight, comprising I and/or Br, and a plurality of ionisable groups selected from the group consisting of —SO3Xa, —PO3Xa and —COOXa, whereas Xa is H, an ammonium group or a monovalent metal, and to fluoropolymer dispersions therefrom.

公开(公告)号：US20190256631A1

公开(公告)日：2019-08-22

申请号：US16345674

申请日：2017-10-17

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Stefano BOSSOLO ,  Claudio OLDANI ,  Claudia MANZONI

IPC: C08F214/26 ,  C08F228/02 ,  C08K5/3432 ,  C08K5/31 ,  C08F8/26

Abstract: The invention relates to a method for manufacturing a cross-linked polymer comprising reacting at least one polymer having at least one —SO2X group, with X being F or Cl, a basic compound, and certain salts including a ring-quaternized pyridinium-type nitrogen, and possessing at least two groups in ortho or para position thereto comprising reactive hydrogen atoms; cross-linking has been proven to proceed effectively, delivering cross-linked polymers possessing improved chemical resistance and mechanical performances.

公开(公告)号：US20170320789A1

公开(公告)日：2017-11-09

申请号：US15528338

申请日：2015-11-16

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Claudio OLDANI ,  Luca MERLO ,  Pierluigi BARBARO ,  Carmen MORENO-MARRODAN ,  Francesca LIGUORI

IPC: C07B31/00 ,  C07D307/33 ,  C07C29/17 ,  B01J31/06 ,  B01J31/28 ,  C07C2601/14

CPC classification number: C07B31/00 ,  B01J31/06 ,  B01J31/28 ,  B01J2231/52 ,  B01J2231/643 ,  C07C29/175 ,  C07C2601/14 ,  C07D307/33 ,  C07C35/12

Abstract: The present invention relates to a process for the one-pot hydrogenation and dehydration or isomerization of an organic compound, and to a catalyst composition for this process comprising transition metal particles having particle size below 50 nm supported on a material comprising at least one fluorinated polymer (P), wherein polymer (P) bears —SO2X functional groups, X being selected from X′ and OM, X′ being selected from the groups consisting of F, Cl, Br and I; and M being selected from the group consisting of H, and alkaline metal and NH4.

公开(公告)号：US20170317369A1

公开(公告)日：2017-11-02

申请号：US15520767

申请日：2015-10-14

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Luca MERLO ,  Stefano TONELLA ,  Martina CORASANITI ,  Claudio OLDANI

IPC: H01M8/1044 ,  C08L27/12 ,  C08J5/22 ,  H01M8/1081 ,  C09D127/12

CPC classification number: H01M8/1044 ,  C08J5/225 ,  C08J5/2281 ,  C08J2327/22 ,  C08J2427/12 ,  C08L27/12 ,  C08L2205/02 ,  C08L2205/025 ,  C09D127/12 ,  C09D127/18 ,  H01M8/1081 ,  Y02P70/56 ,  C08L27/18

Abstract: The present invention relates to a liquid composition comprising a polymer bearing —SO3H groups and a perfluoroelastomer, a method for manufacturing said liquid composition and an article manufactured by using said composition. Preferably, said article is a proton exchange membrane, which shows at the same time good mechanical resistance and electrochemical properties and is useful for example as separator in fuel cells.

公开(公告)号：US20150197589A1

公开(公告)日：2015-07-16

申请号：US14574758

申请日：2014-12-18

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Luca MERLO ,  Alessandro VENERONI ,  Elvira PAGANO ,  Claudio OLDANI

IPC: C08F116/14 ,  C08F261/06

CPC classification number: C08F116/14 ,  B01D71/32 ,  B01D71/68 ,  C08F128/02 ,  C08F214/182 ,  C08F228/02 ,  C08F261/06 ,  C08J5/18 ,  C08J5/2237 ,  C08J2327/18 ,  H01M8/1027 ,  H01M2300/0082

Abstract: A process for reducing the amount of soluble polymeric fractions in a sulfonyl fluoride polymer. The process comprises contacting the sulfonyl fluoride polymer with a fluorinated fluid followed by separation of the polymer from the fluid. The fluorinated fluid is selected from hydrofluoroethers and hydrofluoropolyethers. The invention further relates to sulfonyl fluoride polymers obtainable by the process and having a heat of fusion not exceeding 4 J/g and containing less than 15% by weight of polymeric fractions having an average content of monomeric units comprising a sulfonyl functional group exceeding 24 mole %. The sulfonyl fluoride polymers so obtained are particularly suitable for the preparation of ionomeric membranes for use in electrochemical devices.

Abstract translation: 用于减少磺酰氟聚合物中可溶性聚合物级分的量的方法。 该方法包括使磺酰氟聚合物与氟化流体接触，然后将聚合物与流体分离。 氟化流体选自氢氟醚和氢氟聚醚。 本发明还涉及通过该方法获得的磺化氟化物聚合物，其熔融热不超过4J / g，并且含有少于15％重量的具有包含超过24摩尔的磺酰基官能团的单体单元的平均含量的聚合物部分 ％。 如此获得的磺酰氟聚合物特别适用于制备用于电化学装置的离聚物膜。