Method for starting up a reforming process employing a catalyst containing a group viii metal, rhenium, and selenium
    1.
    发明授权
    Method for starting up a reforming process employing a catalyst containing a group viii metal, rhenium, and selenium 失效
    启动使用含有第VIII族金属,铑和硒的催化剂的改性方法

    公开(公告)号:US3793183A

    公开(公告)日:1974-02-19

    申请号:US3793183D

    申请日:1972-12-11

    Inventor: MAHONEY J NEVITT T

    CPC classification number: C10G35/09 C10G35/22

    Abstract: The method comprises treating the catalyst in a reforming zone with a first oxygen-containing gas at a temperature of at least 880*F.; subsequently treating the catalyst with a second oxygencontaining gas; after purging the reforming zone with an inert gas, treating the catalyst with a hydrogen-containing gas while cooling the average catalyst temperature to a temperature of about 700*F.; introducing the petroleum hydrocarbon stream to be reformed into the reforming zone at one-half to one of the weight hourly space velocity to be employed during the reforming process; increasing the average catalyst temperature to a temperature of 850*F. at a selected rate; increasing the weight hourly space velocity to that desired for the process; and replacing the hydrogen-containing gas with hydrogen-containing recycle gas. The first oxygen-containing gas may be air while the second oxygen-containing gas may be essentially pure oxygen.

    Abstract translation: 该方法包括在至少880°F的温度下用第一含氧气体处理重整区中的催化剂; 随后用第二含氧气体处理催化剂; 在用惰性气体吹扫重整区之后,用含氢气体处理催化剂,同时将平均催化剂温度降至约700°F的温度; 将石油烃流重新引入重整区,以重整过程中所采用的重时空速的一半; 以选定的速率将平均催化剂温度提高到850°F的温度; 将小时空间速度增加到该过程所需的重量; 并用含氢循环气体代替含氢气体。

    Reforming with rhenium promoted chromia catalysts
    2.
    发明授权
    Reforming with rhenium promoted chromia catalysts 失效
    用铑促进的CHROMIA催化剂进行改造

    公开(公告)号:US3763035A

    公开(公告)日:1973-10-02

    申请号:US3763035D

    申请日:1970-08-25

    CPC classification number: B01J23/36 C10G35/06

    Abstract: The catalyst comprises a small amount of rhenium and the oxides of chromium on a catalytically active alumina. The catalyst may be promoted by an oxide of an alkali metal, an oxide of an alkaline earth metal, or mixtures thereof. The catalyst is very efficient for the dehydrocyclization of paraffins and may be used in a process for reforming a petroleum hydrocarbon feedstock containing a substantial amount of paraffins, which process comprises contacting the hydrocarbon feedstock in a reforming reaction zone under reforming conditions and in the presence of hydrogen with the catalyst of the present invention.

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