公开(公告)号：US20240026494A1

公开(公告)日：2024-01-25

申请号：US18255166

申请日：2021-12-09

Applicant: SUNRESIN NEW MATERIALS CO. LTD.

Inventor： Suidang LI ,  Hudao YAN ,  Jia YU ,  Lili FAN ,  Fumin GUO ,  Junlin GAO ,  Weiqiang LYU ,  Yuyun WEI ,  Qiong LIU ,  Xiaokang KOU

IPC: C22B26/12 ,  C22B7/00

CPC classification number: C22B26/12 ,  C22B7/006

Abstract: A method for recovering lithium from a lithium precipitation mother liquor, the method using the following cycle steps including adsorption, displacement, desorption and transformation: a. mounting a lithium-sodium separation resin in a resin column, and adding the lithium precipitation mother liquor to the resin column for adsorption, wherein the adsorption rate can reach 90% or more; b. after adsorption, washing the resin with water, displacing the resin with a lithium-salt-containing solution to wash out residual sodium from the resin; c. after displacement, desorbing the resin by means of an acid solution to obtain a solution with a high lithium content and a low sodium content, which solution has passed desorption criteria; and d. after desorption, carrying out reverse transformation on the resin by means of a transformation solution in order to ensure that no bubbles appear and then reduce the adsorption effect during the adsorption process. During the cycle, the lithium in the lithium precipitation mother liquor is separated from the solution with a high lithium-to-sodium ratio to obtain the solution with the high lithium-to-sodium ratio.

公开(公告)号：US20250153141A1

公开(公告)日：2025-05-15

申请号：US18936689

申请日：2024-11-04

Applicant: SUNRESIN NEW MATERIALS CO. LTD.

Inventor： Heng LIU ,  Qiong LIU ,  Suidang LI ,  Xiaokang KOU

IPC: B01J20/30 ,  B01J20/04

Abstract: Disclosed are a lithium adsorbent, and a preparation method and an application thereof, which relate to the technical of extraction of lithium. The method of the disclosure includes obtaining a lithium adsorbent intermediate by mixing an oil phase with an aqueous phase; and obtaining the lithium adsorbent by mixing the lithium adsorbent intermediate with an organic auxiliary agent; where the oil phase includes a lithium source, an aluminum source, an oil-phase matrix, and an oil-phase auxiliary agent, and the oil-phase matrix includes a high-molecular polymer and vinylidene fluoride; the mixing an oil phase with an aqueous phase includes performing gradient stirring on a mixture of the oil phase and the aqueous phase. According to the disclosure, the high-stability lithium adsorbent can be prepared by optimizing and screening the high-temperature resistant oil-phase matrix and a specific preparation process. Compared with an existing lithium adsorbent, the lithium adsorbent prepared through the disclosure has less degradation, better mechanical strength, and stronger corrosion resistance in a high-temperature environment, and therefore a way of effectively extracting lithium resources from high-temperature and high-salt brine is provided.

公开(公告)号：US20250128251A1

公开(公告)日：2025-04-24

申请号：US18695772

申请日：2024-01-23

Applicant: SUNRESIN NEW MATERIALS CO. LTD.

Inventor： Suidang LI ,  Gang WANG ,  Qiong LIU ,  Xiaokang KOU

IPC: B01J47/018 ,  B01J39/02 ,  B01J39/09 ,  B01J49/53 ,  C02F1/42 ,  C02F101/10

Abstract: A method for preparing an adsorption unit for lithium recovery and use of the adsorption unit. The method includes preparation of an adsorption unit by performing extrusion forming on pulverized lithium adsorbent resin or a lithium adsorbent precursor and an adhesive, the adsorption unit has both high selectivity and adsorption amount of the lithium adsorbent resin and can achieve high-efficiency adsorption of lithium in water with an ultra-low lithium content, and when the adsorption unit is used for adsorbing lithium in the water with the ultra-low lithium content, the entire adsorption process is simple, the desorption efficiency is high and the cost is low.

公开(公告)号：US20250041830A1

公开(公告)日：2025-02-06

申请号：US18473474

申请日：2023-09-25

Applicant: SUNRESIN NEW MATERIALS CO. LTD.

Inventor： Xiaokang KOU ,  Suidang LI ,  Wenjin GAO ,  Huan ZHANG ,  Qiong LIU

IPC: B01J20/30 ,  B01J20/02 ,  B01J20/10 ,  B01J20/26 ,  B01J20/28

Abstract: Provided are a lithium adsorbent and a preparation method therefor. A raw material for preparing the lithium adsorbent includes a lithium adsorbent active material and an auxiliary material, where the auxiliary material includes a hydrophilic binder and reinforcing fibers, and the use of the reinforcing fibers and the hydrophilic binder strongly prevents the propagation of brittle cracks caused by volume expansion and contraction of the lithium adsorbent active material during use, significantly increasing the strength and cycle life of the lithium adsorbent, while the use of the hydrophilic binder increases the adsorption rate and capacity of the lithium adsorbent.

公开(公告)号：US20230017362A1

公开(公告)日：2023-01-19

申请号：US17792624

申请日：2020-12-16

Applicant: SUNRESIN NEW MATERIALS CO., LTD.

Inventor： Jia YU ,  Fumin GUO ,  Suidang LI ,  Qiong LIU ,  Xiaokang KOU

IPC: C22B26/12 ,  C01D15/00 ,  B01J39/04 ,  B01J39/18 ,  B01J47/02 ,  B01J49/60 ,  B01J49/53 ,  C22B3/42

Abstract: Disclosed is a new continuous lithium-sodium separation method. A lithium-sodium separation mother solution, a first leacheate, a desorption solution, a second leacheate and a lithium-sodium separation adsorption tail solution respectively pass through a lithium-sodium separation mother solution feeding pipe (2), a first leacheate feeding pipe (3), a desorption solution feeding pipe (4), a second leacheate feeding pipe (5) and an adsorption tail solution top desorption solution feeding pipe (6) that are located above and below a rotary disc of a multi-way change-over valve system (1), respectively enter corresponding resin columns (7) by means of pore channels and channels in the multi-way change-over valve system (1), and then are discharged from an adsorption tail solution discharging pipe (8), a first leacheate discharging pipe (9), a qualified liquid discharging pipe (10), a second leacheate discharging pipe (11) and an adsorption tail solution top desorption solution discharging pipe (12), so as to complete the whole technological process, wherein the resin columns (7) are connected in series or in parallel by means of the channels located in the multi-way change-over valve system (1). The method is simple and easy to operate, the resin utilization rate is improved by 20% or more, the efficiency is improved by 40% or more, and the production cost can be reduced by 30-50%. The production reliability is improved, and all-year continuous operation can be realized.

公开(公告)号：US20240183002A1

公开(公告)日：2024-06-06

申请号：US18563129

申请日：2022-08-12

Applicant: SUNRESIN NEW MATERIALS CO. LTD.

Inventor： Suidang LI ,  Fumin GUO ,  Wenjin GAO ,  Pengwei JIAO ,  Qiong LIU ,  Jia YU ,  Weina BIAN ,  Kaile CHU ,  Yao WANG ,  Xiaokang KOU

IPC: C22B3/24 ,  B01J20/18 ,  B01J20/28 ,  B01J20/30

CPC classification number: C22B3/24 ,  B01J20/183 ,  B01J20/28026 ,  B01J20/3071 ,  B01J20/3078

Abstract: A method for lithium adsorption in a carbonate- and/or sulfate-containing solution, comprising using an aluminum-based lithium adsorbent for adsorption of lithium ions in the carbonate- and/or sulfate-containing solution, after the adsorption is saturated, using a weakly acidic high-concentration salt solution to transform the adsorbent, desorbing the transformed adsorbent by means of a low-concentration salt solution or water, and entering the next cycle for operation.

公开(公告)号：US20240010774A1

公开(公告)日：2024-01-11

申请号：US18043940

申请日：2021-02-02

Applicant: SUNRESIN NEW MATERIALS CO. LTD.

Inventor： Chaoyang WANG ,  Cheng ZHANG ,  Dan WU ,  Weijie ZHAO ,  Yanjun LI ,  Qiong LIU ,  Xiaokang KOU

IPC: C08F212/12 ,  C08F212/08 ,  C08F212/14 ,  C08F220/44 ,  C08F220/56 ,  C08J9/28 ,  C08J9/36

CPC classification number: C08F212/12 ,  C08F212/08 ,  C08F212/18 ,  C08F220/44 ,  C08F220/56 ,  C08J9/286 ,  C08J9/36 ,  C08J2201/05 ,  C08J2325/12 ,  C08J2205/042

Abstract: A solid-phase synthesis carrier, a preparation method therefor and the use thereof, wherein a diene cross-linking agent with a similar reactivity ratio to styrene and two vinyl groups thereof not on the same benzene ring is selected as a cross-linking monomer, and is subjected to suspension polymerization to obtain a porous resin. The porous resin is then functionalized to obtain a porous resin with an amino or hydroxyl functional group. Compared with existing preparation methods, the reactivity ratio of the cross-linking agent and styrene is similar, which is beneficial to improving the uniformity of the chemical structure in the resin, forming uniformly distributed active sites and channels, and is beneficial to improving the reaction efficiency and reducing the mass transfer resistance. The preparation of oligonucleotides by using such a carrier as a solid-phase synthesis carrier can improve the yield and purity of the oligonucleotides.

公开(公告)号：US20230331591A1

公开(公告)日：2023-10-19

申请号：US18044321

申请日：2021-12-22

Applicant: SUNRESIN NEW MATERIALS CO. LTD.

Inventor： Heng LIU ,  Wenjin GAO ,  Suidang LI ,  Qiong LIU ,  Xiaokang KOU

IPC: C02F1/42 ,  C02F1/00 ,  C08F212/08 ,  B01J39/20 ,  B01J39/07 ,  B01J47/02 ,  B01J47/14 ,  B01J49/53 ,  B01J49/60

CPC classification number: C02F1/42 ,  C02F1/008 ,  C08F212/08 ,  B01J39/20 ,  B01J39/07 ,  B01J47/02 ,  B01J47/14 ,  B01J49/53 ,  B01J49/60 ,  C02F2101/105

Abstract: A resin for removing phosphorus from water body, and a preparation method therefor and an application thereof. The particle size of the resin is 0.5-0.8 mm; the resin has a porous structure, the specific surface area is 8-25 m2/g, and the pore size distribution is 3-15 nm, the wet apparent density is 0.68-0.74 g/cm3; the wet true density is 1.12-1.18 g/cm3: and the water content of the resin is 43-57% in percentage by weight. The resin is loaded with a functional group having a lanthanum-oxygen bond, so that the resin can selectively adsorb phosphate radicals in the water body. The resin can selectively remove phosphorus in the water body by using a mode of loading lanthanum on weak acid cation resin and utilizing high selectivity of the lanthanum-oxygen bond to phosphate radicals, is easy to resolve and low in synthesis cost, and can be repeatedly used. Phosphorus in eutrophicated water and waste water can be effectively removed, the content of phosphate radicals in the water body can be controlled within 20 ppm, the phosphorus removal cost of the water body is reduced and the resin has great advantages compared with conventional disposable phosphorus adsorbents.

公开(公告)号：US20230002854A1

公开(公告)日：2023-01-05

申请号：US17778776

申请日：2020-12-16

Applicant: SUNRESIN NEW MATERIALS CO. LTD. ,  MINMETALS SALT LAKE CO., LTD.

Inventor： Jia YU ,  Zengrong LI ,  Dayi ZHANG ,  Fumin GUO ,  Zhaofei HOU ,  Faman TANG ,  Mian WANG ,  Zhibo LUO ,  Chao ZAN ,  Suidang LI ,  Qiong LIU ,  Yongxiao SONG ,  Yun WANG ,  Xiaokang KOU

IPC: C22B26/12 ,  C22B3/24

Abstract: A new method for extracting lithium from salt lake brine, comprising the following steps: a salt lake old brine raw material, desorption liquid, low-magnesium water, and adsorption tail liquid pass through an old brine feeding pipe (2), a desorption liquid feeding pipe (4), a low-magnesium water top desorption liquid feeding pipe (3), and an adsorption tail liquid top desorption liquid feeding pipe (11), respectively, which are located above and below a rotary disc of a multi-way valve system (1); and after respectively entering corresponding adsorption columns (6) by means of a duct and channel within the multi-way valve system (1), the entire process procedure is completed from an adsorption tail liquid discharge pipe (7), a qualified desorption liquid discharge pipe (10), a lithium-containing old brine discharge pipe (8), and an adsorption tail liquid top desorption liquid discharge pipe (5); and the adsorption columns (6) are connected in series or in parallel by means of channels located in the multi-way valve system (1). The feature in which a multi-way valve device is simple and easy to operate is utilized, and in comparison with a fixed bed operating system, the utilization rate of lithium adsorbent may be increased by over 20%, the utilization efficiency of the lithium adsorbent may be increased by over 40%, and production costs may be reduced by 30-50%. Therefore, the stability of a qualified desorption liquid is improved, stable production is guaranteed, and year-round constant operation may be achieved.

公开(公告)号：US20250136458A1

公开(公告)日：2025-05-01

申请号：US18928921

申请日：2024-10-28

Applicant: SUNRESIN NEW MATERIALS CO. LTD.

Inventor： Heng LIU ,  Qiong LIU ,  Suidang LI ,  Xiaokang KOU

IPC: C01D15/00 ,  B01J20/08

Abstract: Disclosed are a method for extracting lithium from brine, and an application. The method includes performing extraction on the brine through a continuous ion exchange process, where according to the continuous ion exchange process, in an adsorption section, adsorption is performed on the brine with an aluminum-based lithium adsorbent; in a water-pushing-material section, a resin column is washed with a solution; in a desorption section, desorption is performed with pure water, and a desorption solution is collected in segments; and in a material-pushing-water section, a solution in a resin column is replaced by spent brine. The solution used in the water-pushing-material section is a front-segment collected liquid in the desorption section, and the front-segment collected liquid satisfies the following parameter: 520 us*cm−1