公开(公告)号：US20040192973A1

公开(公告)日：2004-09-30

申请号：US10403213

申请日：2003-03-31

Applicant: Saudi Basic Industries Corporation

Inventor： Wugeng Liang ,  Scott A. Stevenson ,  James W. Kauffman ,  John S. Ledford ,  Joseph R. Linzer

IPC: B01J023/31 ,  C07C045/28

CPC classification number: B01J23/002 ,  B01J23/8876 ,  B01J2523/00 ,  C07C45/34 ,  C07C45/35 ,  C07C47/22 ,  B01J2523/15 ,  B01J2523/22 ,  B01J2523/53 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/27 ,  B01J2523/845 ,  B01J2523/69

Abstract: A catalyst for production of unsaturated aldehydes, such as methacrolein, by gas phase catalytic oxidation of olefins, such as isobutylene contains oxides of molybdenum, bismuth, iron, cesium and, optionally, other metals, such as tungsten, cobalt, nickel, antimony, magnesium, zinc and phosphorus. The catalyst has a certain relative amount ratio of cesium to bismuth, a certain relative amount ratio of iron to bismuth and a certain relative amount ratio of bismuth, iron and cesium to molybdenum. For a catalyst of the formula:Mo12BiaWbFecCodNieSbfCsgMghZniPjOxwherein a is 0.1 to 1.5, b is 0 to 4, c is 0.2 to 5.0, d is 0 to 9, e is 0 to 9, f is 0 to 2.0, g is from 0.4 to 1.5, h is 0 to 1.5, i is 0 to 2.0, j is 0 to 0.5 and x is determined by the valences of the other components, c:gnull3.3-5.0, c:anull2.0-6.0 and (3anull3cnull2dnull2enullgnull2hnull2i)/(2x12null2b)null0.90-1.10.

Abstract translation: 用于通过气相催化氧化烯烃（例如异丁烯）来生产不饱和醛如甲基丙烯醛的催化剂包含钼，铋，铁，铯和任选的其它金属如钨，钴，镍，锑， 镁，锌和磷。 催化剂具有一定的铯与铋的相对量比例，铁与铋的一定相对量比和铋，铁和铯与钼的一定相对量比。 对于下式的催化剂：Mo12BiaWbFecCodNieSbfCsgMghZniPjOx其中a为0.1至1.5，b为0至4，c为0.2至5.0，d为0至9，e为0至9，f为0至2.0，g为0.4至 1.5，h为0至1.5，i为0至2.0，j为0至0.5，x由其他组分的化合价决定，c：g = 3.3-5.0，c：a = 2.0-6.0和（3a + 3c + 2d + 2e + g + 2h + 2i）/（2×12 + 2b）= 0.90-1.10。