公开(公告)号：US3910987A

公开(公告)日：1975-10-07

申请号：US43030574

申请日：1974-01-02

Applicant: TEXACO INC

Inventor： CUMMINGS WILLIAM M

IPC: C07C205/40 ,  C07C409/40 ,  C10L1/23 ,  C07C77/02 ,  C07C79/18

CPC classification number: C10L1/231 ,  C07C205/40 ,  C07C409/40 ,  C10M2215/16 ,  C10M2215/202

Abstract: Nitroalkyl nitrate and peroxynitrates characterized by the formula:

where R and R1 are hydrogen or alkyl of from 1 to 10 carbons, where X is R2O-, -CN, Cl, phenyl, -ONO2,

where R2 is alkyl of from 1 to 10 carbons or phenyl and R3 is hydrogen, phenyl or alkyl of from 1 to 10 carbons, and where Y is -OONO2 or -ONO2, said nitroalkyl nitrates being prepared by first contacting a substituted alkene of the formula:

where R, R1 and X are as heretofore defined with a mixture of dinitrogen tetroxide and oxygen to form substituted nitroalkyl peroxynitrate of the formula:

where R, R1 and X are as heretofore defined and second contacting said peroxynitrate with a reducing agent to form said substituted nitroalkyl nitrate, the first and second contacting being conducted in the presence of inert liquid. The nitroalkyl nitrate final products of the invention are useful as fuel additives to increase power output of petroleum distillates such as gasoline and kerosene. Further, they are useful as intermediates in the preparation of surfactants, fuel and lubricant additives, insecticides, fungicides (e.g. controlling early blight in bean plants), pharmaceuticals and polymers.

Abstract translation: 硝基硝基硝酸盐和过氧硝酸盐，其特征在于以下结构式：Y | R-CH-C-CH 2 -NO 2 || XR1其中R和R 1是氢或1至10个碳的烷基，其中X是R 2 O-，-CN，Cl，苯基 ，其中R 2是1至10个碳的烷基或苯基且R 3是氢，苯基或1至10个碳的烷基，并且其中Y是-OONO 2 或-ONO 2，所述硝基烷基硝酸盐是通过首先使下式的取代烯与R-CH-C = CH 2 || XR1接触而制备的，其中R，R 1和X如前面所定义，与四氧化二氮和氧的混合物形成取代的 硝基烷基过氧化硝酸盐，其具有下式：OONO 2 | R-CH-C-CH 2 NO 2 || XR1其中R，R 1和X如前所定义，并且使所述过硝酸盐与还原剂接触以形成所述取代的硝基烷基硝酸盐，第一和第二接触是 在惰性液体存在下进行。 本发明硝酸烷基硝酸盐最终产品可用作燃料添加剂以增加石油馏出物如汽油和煤油的功率输出。 此外，它们可用作制备表面活性剂，燃料和润滑剂添加剂，杀虫剂，杀真菌剂（例如控制豆类植物中的早疫病），药物和聚合物的中间体。

公开(公告)号：US3926578A

公开(公告)日：1975-12-16

申请号：US53390974

申请日：1974-12-18

Applicant: TEXACO INC

Inventor： CUMMINGS WILLIAM M

IPC: C10L1/222 ,  C10L1/22

CPC classification number: C10L1/2222

Abstract: Hydrocarbylamine substituted propionic esters represented by the formula: RR''NCH2CH2COOR'''' in which R is an aliphatic hydrocarbon radical having from 12 to 22 carbon atoms, R'' is hydrogen or a lower alkyl radical having from 1 to 2 carbon atoms and R'''' is a hydrocarbon radical having from about 8 to 22 carbon atoms, and a motor fuel composition containing said esters.

公开(公告)号：US3910981A

公开(公告)日：1975-10-07

申请号：US43030674

申请日：1974-01-02

Applicant: TEXACO INC

Inventor： CUMMINGS WILLIAM M

IPC: C07C205/40 ,  C07C409/40 ,  C10L1/23 ,  C07C77/02

CPC classification number: C07C255/00 ,  C07C205/40 ,  C07C409/40 ,  C10L1/231 ,  C10M2215/16 ,  C10M2215/202

Abstract: Nitroalkyl nitrate and peroxynitrates characterized by the formula:

where R and R1 are hydrogen or alkyl of from 1 to 10 carbons, where X is R2O-CN, Cl, phenyl, -ONO2,

where R2 is alkyl of from 1 to 10 carbons or phenyl and R3 is hydrogen, phenyl or alkyl of from 1 to 10 carbons, and where Y is -OONO2 or -ONO2, said nitroalkyl nitrates being prepared by first contacting a substituted alkene of the formula:

where R, R1 and X are as heretofore defined with a mixture of dinitrogen tetroxide and oxygen to form substituted nitroalkyl peroxynitrate of the formula:

D R A W I N G
where R, R1 and X are as heretofore defined and second contacting said peroxynitrate with a reducing agent to form said substituted nitroalkyl nitrate, the first and second contacting being conducted in the presence of inert liquid. The nitroalkyl nitrate final products of the invention are useful as fuel additives to increase power output of petroleum distillates such as gasoline and kerosene. Further, they are useful as intermediates in the preparation of surfactants, fuel and lubricant additives, insecticides, fungicides (e.g. controlling early blight in bean plants), pharmaceuticals and polymers.

Abstract translation: 硝基硝基硝酸盐和过氧硝酸盐，其特征在于下式：Y | R-CH-C-CH2-NO2 || XR1其中R和R1是氢或1至10个碳的烷基，其中X是R2O + 13，-CN，Cl， 苯基，-ONO 2，O并原-OC-CF 3，-OC-R 3，其中R 2是1至10个碳的烷基或苯基且R 3是氢，苯基或1至10个碳的烷基，其中Y是 - OONO 2或-ONO 2，所述硝基烷基硝酸盐通过首先使下式的取代烯与R-CH-C = CH 2 || XR1接触而制备，其中R，R 1和X如上文所定义，与四氧化二氮和氧气混合形成 取代的硝基烷基过氧化硝酸盐，其具有下式：OONO 2 | R-CH-C-CH 2 -NO 2 || XR1其中R，R 1和X如前所定义，并且使所述过硝酸盐与还原剂接触以形成所述取代的硝基烷基硝酸盐，第一和 第二次接触在惰性液体存在下进行。 本发明硝酸烷基硝酸盐最终产品可用作燃料添加剂以增加石油馏出物如汽油和煤油的功率输出。 此外，它们可用作制备表面活性剂，燃料和润滑剂添加剂，杀虫剂，杀真菌剂（例如控制豆类植物中的早疫病），药物和聚合物的中间体。