公开(公告)号：US20240229304A9

公开(公告)日：2024-07-11

申请号：US18573812

申请日：2022-07-20

Applicant: TORAY INDUSTRIES, INC.

Inventor： Kiminori ONO ,  Yuki SADO ,  Fumihiko TANAKA ,  Masahiro MATSUMOTO

IPC: D01F9/22

CPC classification number: D01F9/22 ,  D10B2101/12

Abstract: To provide a carbon fiber bundle capable of suppressing winding due to ring-shaped fuzzes, which occurs when the carbon fiber bundle is rolled out for advanced processing, and a production method for producing the same. Disclosed is a carbon fiber bundle wherein an average single-fiber diameter B is 6.9 to 11.0 μm, a tensile modulus E of resin-impregnated strands is 230 to 310 GPa, the number of fuzzes inherent in the carbon fiber bundle is 40 fuzzes/m or less, and a proportion of fuzzes with a structure having a difference between skin and core is 1 to 25% of fuzzes inherent in the carbon fiber bundle. Such a carbon fiber bundle is preferably obtained by a method including, in a process of heat-treating a polyacrylonitrile-based precursor fiber bundle with a single-fiber fineness of 0.9 to 2.2 dtex in an oxidizing atmosphere at 200 to 300° C., heat-treating the polyacrylonitrile-based precursor fiber bundle so that a heat generation rate Q, which is the left side of the formula (3), is 150 to 500 J/m2/s until the density is 1.22 to 1.24 g/cm3, when q (J/g/s) is the heat generation rate of the single fiber, N is the number of filaments, d (dtex) is a single-fiber fineness of the stabilized fiber bundle and W (mm) is a yarn width, heat-treating the fiber bundle while applying a tension of 1.6 to 4.0 mN/dtex until the density is 1.38 to 1.50 g/cm3 to obtain a stabilized fiber bundle, and heat-treating the stabilized fiber bundle in an inert atmosphere at 1,200 to 1,600° C.


Q=q×N×d/W/10  (3)

公开(公告)号：US20240133081A1

公开(公告)日：2024-04-25

申请号：US18573812

申请日：2022-07-19

Applicant: TORAY INDUSTRIES, INC.

Inventor： Kiminori ONO ,  Yuki SADO ,  Fumihiko TANAKA ,  Masahiro MATSUMOTO

IPC: D01F9/22

CPC classification number: D01F9/22 ,  D10B2101/12

Abstract: To provide a carbon fiber bundle capable of suppressing winding due to ring-shaped fuzzes, which occurs when the carbon fiber bundle is rolled out for advanced processing, and a production method for producing the same. Disclosed is a carbon fiber bundle wherein an average single-fiber diameter B is 6.9 to 11.0 μm, a tensile modulus E of resin-impregnated strands is 230 to 310 GPa, the number of fuzzes inherent in the carbon fiber bundle is 40 fuzzes/m or less, and a proportion of fuzzes with a structure having a difference between skin and core is 1 to 25% of fuzzes inherent in the carbon fiber bundle. Such a carbon fiber bundle is preferably obtained by a method including, in a process of heat-treating a polyacrylonitrile-based precursor fiber bundle with a single-fiber fineness of 0.9 to 2.2 dtex in an oxidizing atmosphere at 200 to 300° C., heat-treating the polyacrylonitrile-based precursor fiber bundle so that a heat generation rate Q, which is the left side of the formula (3), is 150 to 500 J/m2/s until the density is 1.22 to 1.24 g/cm3, when q (J/g/s) is the heat generation rate of the single fiber, N is the number of filaments, d (dtex) is a single-fiber fineness of the stabilized fiber bundle and W (mm) is a yarn width, heat-treating the fiber bundle while applying a tension of 1.6 to 4.0 mN/dtex until the density is 1.38 to 1.50 g/cm3 to obtain a stabilized fiber bundle, and heat-treating the stabilized fiber bundle in an inert atmosphere at 1,200 to 1,600° C.


Q=q×N×d/W/10  (3)