Abstract:
The present invention relates to a composite semipermeable membrane including: a substrate; a porous support layer disposed on the substrate; and a separation functional layer disposed on the porous support layer, in which the separation functional layer includes: a first layer including a crosslinked aromatic polyamide; and a coating layer existing on the first layer and including an aliphatic polyamide including a fluorine atom, and the composite semipermeable membrane has a proportion of the number of fluorine atoms to the total number of atoms of all elements of 0.5% or more and 8% or less, and has a ratio (N/O ratio) of the number of nitrogen atoms to the number of oxygen atoms of 0.8 or more and 1.3 or less.
Abstract:
An object of the present invention is to provide a composite semipermeable membrane which has a high permeation rate and high salt removal performance and is excellent in terms of performance stability during long-term operation. The composite semipermeable membrane of the present invention includes: a supporting membrane including a substrate and a porous supporting layer; and a separation functional layer disposed on the porous supporting layer, the separation functional layer includes a crosslinked polyamide and a hydrophilic polymer having an acidic group, and in the separation functional layer, a ratio of (molar equivalent of amino groups)/(molar equivalent of amide groups) is 0.18 or less.
Abstract:
The present invention provides a composite semipermeable membrane achieving high permeate amount and having high capability to inhibit adhesion of foulants to the membrane surface. The present invention relates to a composite semipermeable membrane including: a supporting membrane which includes a substrate and a porous supporting layer; and a polyamide separation functional layer formed on the porous supporting layer, in which an acidic group-containing hydrophilic polymer is introduced onto the surface of the separation functional layer via amide linkage, and relates to a method for producing such a composite semipermeable membrane.