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    Fischer-Tropsch Processes with Modified Product Selectivity
    2.
    发明公开
    Fischer-Tropsch Processes with Modified Product Selectivity 审中-公开

    公开(公告)号：US20240002734A1

    公开(公告)日：2024-01-04

    申请号：US18252685

    申请日：2021-12-17

    Applicant: BP P.L.C.

    Inventor： Alexander James Paterson

    IPC: C10G2/00 ,  B01J23/889 ,  C07C29/156 ,  C07C29/151

    CPC classification number: C10G2/332 ,  B01J23/8892 ,  C07C29/156 ,  C07C29/1512 ,  B01J2523/72 ,  B01J2523/845 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4025

    Abstract: The present disclosure relates generally to compositions and processes for modifying Fischer-Tropsch product selectivity. In particular, the disclosure provides for a for converting a mixture of hydrogen and carbon monoxide gases to a product composition comprising alcohols and liquid hydrocarbons via Fischer-Tropsch synthesis in the presence of a supported cobalt-manganese Fischer-Tropsch synthesis catalyst, the process comprising: contacting the catalyst with a first gaseous feed comprising carbon monoxide and hydrogen for at least 12 hours to provide via Fischer-Tropsch synthesis a first product composition comprising C5+ hydrocarbons and alcohol; then contacting the catalyst with a first selectivity gaseous composition comprising at least 35 vol % H2 and a H2:CO molar ratio of at least 2; and then contacting the catalyst with a second gaseous feed comprising carbon monoxide and hydrogen to provide a second product composition comprising C5+ hydrocarbons, with a selectivity of no more than 5% for alcohols. Optionally, the catalyst selectivity to alcohols can be reversed by contacting the catalyst with a second selectivity gaseous composition comprising CO or a H2:CO molar ratio of at below 1.5.

    Process for dehydrating alcohols to ethers
    5.
    发明授权
    Process for dehydrating alcohols to ethers 有权

    公开(公告)号：US11578026B2

    公开(公告)日：2023-02-14

    申请号：US17433122

    申请日：2020-02-14

    Applicant: BP P.L.C.

    Inventor： Benjamin James Dennis-Smither ,  John Glenn Sunley ,  Fiona Jackson

    IPC: C07C41/09

    Abstract: A process for dehydrating C2+ alcohols to ether products in the presence of a catalyst and promoter, wherein the catalyst is at least one aluminosilicate zeolite catalyst which is a medium pore zeolite having a 3-dimensional framework structure, and the promoter is one or more organic carbonyl compounds or derivatives thereof, and wherein and the molar ratio of promoter to C2+ alcohols is maintained at less than 1.

    Etherification process
    6.
    发明授权
    Etherification process 有权

    公开(公告)号：US11472759B2

    公开(公告)日：2022-10-18

    申请号：US16757414

    申请日：2018-10-19

    Applicant: BP P.L.C.

    Inventor： Jon Deeley ,  Gareth Armitage

    IPC: C07C41/06 ,  C07C41/20 ,  C07C41/28 ,  C07C41/56 ,  C07C43/04 ,  C07C43/303 ,  C10M105/18

    Abstract: The present invention relates to a process for preparing ethers, particularly unsymmetrical ethers, and preferably ethers suitable for use as base stocks for lubricant compositions. In particular, the process involves the reaction of an α,β-unsaturated aldehyde with a trihydrocarbyl orthoester to form an α,β-unsaturated acetal and conversion of the α,β-unsaturated acetal to an ether through hydrogenation and hydrogenolysis.

    PROCESS
    7.
    发明申请
    PROCESS 有权

    公开(公告)号：US20220144739A1

    公开(公告)日：2022-05-12

    申请号：US17433122

    申请日：2020-02-14

    Applicant: BP P.L.C.

    Inventor： Benjamin James DENNIS-SMITHER ,  John Glenn SUNLEY ,  Fiona JACKSON

    IPC: C07C41/09

    Abstract: A process for dehydrating C2+ alcohols to ether products in the presence of a catalyst and promoter, wherein the catalyst is at least one aluminosilicate zeolite catalyst which is a medium pore zeolite having a 3-dimensional framework structure, and the promoter is one or more organic carbonyl compounds or derivatives thereof, and wherein and the molar ratio of promoter to C2+ alcohols is maintained at less than 1.

    Fischer-Tropsch process, supported Fischer-Tropsch synthesis catalyst and uses thereof
    9.
    发明授权
    Fischer-Tropsch process, supported Fischer-Tropsch synthesis catalyst and uses thereof 有权

    公开(公告)号：US11203717B2

    公开(公告)日：2021-12-21

    申请号：US16968777

    申请日：2019-02-06

    Applicant: BP P.L.C.

    Inventor： Alexander James Paterson

    IPC: C10G2/00 ,  B01J23/889 ,  B01J35/00 ,  B01J37/02 ,  B01J21/06

    Abstract: A process for converting a mixture of hydrogen and carbon monoxide gases to a composition comprising alcohols and liquid hydrocarbons by means of a Fischer-Tropsch synthesis reaction, said process comprising contacting a mixture of hydrogen and carbon monoxide gases, preferably in the form of synthesis gas mixture, with a supported Co—Mn Fischer-Tropsch synthesis catalyst, wherein: the support material of the supported Co—Mn Fischer-Tropsch synthesis catalyst comprises a material selected from titania, zinc oxide, zirconia, and ceria; the supported synthesis catalyst comprises at least 2.5 wt % of manganese, on an elemental basis, based on the total weight of the supported synthesis catalyst; the weight ratio of manganese to cobalt, on an elemental basis, is 0.2 or greater; the molar ratio of hydrogen to carbon monoxide is at least 1; and, the Fischer-Tropsch synthesis reaction is conducted at a pressure in the range of from 1.0 to 10.0 MPa absolute.

    Selective Hydrogenation of Polyunsaturates
    10.
    发明申请
    Selective Hydrogenation of Polyunsaturates 有权

    公开(公告)号：US20210253496A1

    公开(公告)日：2021-08-19

    申请号：US16972996

    申请日：2019-06-03

    Applicant: BP P.L.C.

    Inventor： Rolf BEERTHUIS ,  Krijn DE JONG ,  Petra DE JONGH ,  John Glenn SUNLEY

    IPC: C07C5/09 ,  B01J23/72 ,  B01J35/00 ,  B01J37/02 ,  B01J37/08 ,  B01J37/16 ,  B01J21/18 ,  B01J35/02

    Abstract: The present invention provides a process for the hydrogenation of polyunsaturated hydrocarbon compounds, in particular di-olefins and alkynes, more particularly di-olefins, said process comprising contacting a feed comprising one or more polyunsaturated hydrocarbon compounds with a catalyst comprising copper and carbon in the presence of hydrogen, preferably wherein the catalyst is a copper catalyst on a carbon-containing support. The present invention also provides a process for producing a copper catalyst on a carbon-containing support and the use of a copper catalyst on a carbon-containing support to increase the selectivity towards di-olefin hydrogenation over mono-olefin hydrogenation in a process for hydrogenation of one or more di-olefins.

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