Method for purifying lactams
    2.
    发明授权
    Method for purifying lactams 失效
    内酰胺纯化方法

    公开(公告)号:US3960846A

    公开(公告)日:1976-06-01

    申请号:US508020

    申请日:1974-09-20

    CPC classification number: C07D201/16

    Abstract: The instant invention relates to a method for purifying lactams wherein the lactam to be purified is contacted in the fused state with inorganic adsorption agents.The said method comprises contacting the lactam to be purified in the fused state with an inorganic adsorbent, then separating the lactam from the adsorbent and regenerating said adsorbent if desired, wherein said adsorbent is impregnated with at least one impregnation compound selected from the group consisting of an acid and the alkali metal salts which are thermally stable and exert no action on the lactam at temperatures lower tha 250.degree.C.

    Abstract translation: 本发明涉及纯化内酰胺的方法,其中待纯化的内酰胺以熔融状态与无机吸附剂接触。

    Process for the preparation of an organomagnesium compound
    6.
    发明授权
    Process for the preparation of an organomagnesium compound 失效
    制备有机镁化合物的方法

    公开(公告)号:US4683344A

    公开(公告)日:1987-07-28

    申请号:US690443

    申请日:1985-01-11

    CPC classification number: C07D201/14 C07F3/003

    Abstract: A process for the preparation of a pulverulent organomagnesium compound involves bringing together into intimate admixture a particulate hydroxyl functional material with an organomagnesium-containing material. The process is conducted at a temperature below the melting point of the hydroxyl functional material but at a temperature sufficient to convert at least a portion of the hydroxyl functional material to the pulverulent organomagnesium compound. The aforesaid organomagnesium compounds are useful as intermediates in generating anionic sites for anionic polymerization.

    Abstract translation: 用于制备粉状有机镁化合物的方法包括将颗粒状羟基官能材料与含有机镁的材料紧密混合在一起。 该方法在低于羟基官能材料的熔点的温度下进行,但在足以将至少一部分羟基官能材料转化为有机镁化合物的温度下进行。 上述有机镁化合物可用作产生用于阴离子聚合的阴离子位点的中间体。

    Process for preparing lactam magnesium halides
    8.
    发明授权
    Process for preparing lactam magnesium halides 失效
    制备内酰胺卤化镁的方法

    公开(公告)号:US4438034A

    公开(公告)日:1984-03-20

    申请号:US456702

    申请日:1983-01-10

    Inventor: Albert Y. Garner

    CPC classification number: C07D201/14 C07F3/003

    Abstract: A method of preparing a lactam magnesium halide comprising the steps of:a. reactively admixing magnesium, hydrocarbon halide and lactam in the presence of cyclic ether solvent, wherein the halide is either chloride or bromide; andb. removing the cyclic ether and the hydrocarbon residue.

    Abstract translation: 一种制备内酰胺卤化镁的方法,包括以下步骤:a。 在环醚溶剂存在下反应性混合镁,卤化烃和内酰胺,其中卤化物是氯化物或溴化物; 和b。 除去环醚和烃残余物。

    Low molecular weight substituted phenol-lactam-substituted phenol
complexes from lactams and substituted monohydroxy phenolic compounds
    9.
    发明授权
    Low molecular weight substituted phenol-lactam-substituted phenol complexes from lactams and substituted monohydroxy phenolic compounds 失效
    来自内酰胺和取代的单羟基酚类化合物的低分子量取代的苯酚 - 内酰胺取代的苯酚络合物

    公开(公告)号:US3988350A

    公开(公告)日:1976-10-26

    申请号:US513874

    申请日:1974-10-10

    CPC classification number: C07D207/267 C07D201/14

    Abstract: A low molecular weight complex of a lactam and a substituted phenolic compound having the formula ##SPC1##Wherein n is an integer of 3 to 5; W is hydrogen or alkyl having from 1 to 8 carbon atoms including cycloalkyl substituents; each R and R', R.sub.2 and R'.sub.2 is alkoxy of from 1 to 3 carbon atoms, nitro, cyano, hydrogen, halogen or alkyl having from 1 to 12 carbon atoms and at least one R, R', R.sub.2 and R'.sub.2 is a substituent other than hydrogen, and wherein R.sub.2 and R'.sub.2 can also be alaninyl.

    Abstract translation: 具有下式的内酰胺和取代的酚类化合物的低分子量复合物,其中N为3至5的整数; W是氢或具有1至8个碳原子的烷基,包括环烷基取代基; 每个R和R',R 2和R'2是具有1至3个碳原子的烷氧基,硝基,氰基,氢,卤素或具有1至12个碳原子的烷基和至少一个R,R',R 2和R' 2是除氢以外的取代基,其中R2和R'2也可以是丙烯酰基。

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