PROCESS FOR FORMING SYNTHETIC FIBERS AND FIBERS, YARNS AND CARPETS PRODUCED THEREBY
    12.
    发明申请
    PROCESS FOR FORMING SYNTHETIC FIBERS AND FIBERS, YARNS AND CARPETS PRODUCED THEREBY 审中-公开
    形成合成纤维和纤维的方法,生产的纱线和地毯

    公开(公告)号:WO2016168807A1

    公开(公告)日:2016-10-20

    申请号:PCT/US2016/028065

    申请日:2016-04-18

    CPC classification number: D01F6/90 D01D5/08 D01F1/04 D01F1/10 D01F6/905

    Abstract: Processes for forming synthetic fibers from polymer melts containing a first fiber forming polymer, a spin assist additive, and optionally a pigment additive are provided. Also provided are synthetic fibers of a first fiber forming polymer, a spin assist additive, and optionally a pigment additive, as well as articles of manufacture such as yarns, carpets and fabrics made up of these synthetic fibers.

    Abstract translation: 提供了由含有第一纤维形成聚合物,自旋助剂和任选的颜料添加剂的聚合物熔体形成合成纤维的方法。 还提供了第一纤维形成聚合物,自旋助剂和任选的颜料添加剂的合成纤维,以及由这些合成纤维制成的纱线,地毯和织物等制品。

    METHODS AND SYSTEMS FOR THE RECOVERY OF WATER FROM A POLYAMIDE SYNTHESIS PROCESS
    14.
    发明申请
    METHODS AND SYSTEMS FOR THE RECOVERY OF WATER FROM A POLYAMIDE SYNTHESIS PROCESS 审中-公开
    从聚酰胺合成过程中回收水的方法和系统

    公开(公告)号:WO2014179029A1

    公开(公告)日:2014-11-06

    申请号:PCT/US2014/034086

    申请日:2014-04-15

    CPC classification number: C08G69/28 B01J19/2415

    Abstract: The present disclosure relates to systems and methods for recovering water from a condensation reaction of at least one carboxylic acid and at least one diamine to make polyamide. The method can include obtaining, from an evaporator, an aqueous mixture comprising a partially polymerized polyamide and at least one of a carboxylic acid and diamine; passing the aqueous mixture through a tubular reactor comprising subjecting the aqueous mixture to a temperature and pressure sufficient to further polymerize the partially polymerized polyamide by condensation of the carboxylic acid and diamine, thereby producing water having a substantially gaseous phase; passing the water having a substantially gaseous phase into a rectification column thereby removing one or more of a diamine, a carboxylic acid and polyamide to provide purified water having a substantially gaseous phase; and condensing the purified water having a substantially gaseous phase into purified water having a substantially liquid phase. The system can include, among other things, a tubular reactor, a rectification column, a condensation assembly, and a conduit network.

    Abstract translation: 本公开涉及从至少一种羧酸和至少一种二胺的缩合反应中回收水以制备聚酰胺的系统和方法。 该方法可以包括从蒸发器获得包含部分聚合的聚酰胺和至少一种羧酸和二胺的含水混合物; 使含水混合物通过管式反应器,包括使含水混合物经受足以通过羧酸和二胺的缩合进一步聚合部分聚合的聚酰胺的温度和压力,从而产生具有基本气相的水; 将具有基本气相的水通入精馏塔中,从而除去二胺,羧酸和聚酰胺中的一种或多种,​​以提供具有基本上气相的净化水; 并将具有基本气相的净化水冷凝成具有基本上液相的纯净水。 该系统可以包括管式反应器,精馏塔,冷凝组件和导管网络。

    METHODS OF PRODUCING 7-CARBON CHEMICALS VIA METHYL-ESTER SHIELDED CARBON CHAIN ELONGATION
    15.
    发明申请
    METHODS OF PRODUCING 7-CARBON CHEMICALS VIA METHYL-ESTER SHIELDED CARBON CHAIN ELONGATION 审中-公开
    通过甲基酯保护的碳链延长生产7-碳化合物的方法

    公开(公告)号:WO2014105794A2

    公开(公告)日:2014-07-03

    申请号:PCT/US2013/077420

    申请日:2013-12-23

    Abstract: This document describes biochemical pathways for producing pimelic acid, 7-aminoheptanoic acid, 7-hydroxyheptanoic acid, heptamethylenediamine or 1,7-heptanediol by forming two terminal functional groups, comprised of carboxyl, amine or hydroxyl group, in a C7 aliphatic backbone substrate. These pathways, metabolic engineering and cultivation strategies described herein rely on enzymes or homologs accepting methyl ester shielded dicarboxylic acid substrates.

    Abstract translation: 该文献描述了通过形成由羧基,胺或羟基组成的两个末端官能团来生产庚二酸,7-氨基庚酸,7-羟基庚酸,七亚甲基二胺或1,7-庚二醇的生物化学途径 在C7脂肪族主链底物中。 本文描述的这些途径,代谢工程和培养策略依赖于接受甲酯保护的二羧酸底物的酶或同系物。

    METHODS OF PRODUCING 7-CARBON CHEMICALS FROM LONG CHAIN FATTY ACIDS VIA OXIDATIVE CLEAVAGE
    16.
    发明申请
    METHODS OF PRODUCING 7-CARBON CHEMICALS FROM LONG CHAIN FATTY ACIDS VIA OXIDATIVE CLEAVAGE 审中-公开
    通过氧气消毒从长链脂肪酸生产7碳化合物的方法

    公开(公告)号:WO2014105793A1

    公开(公告)日:2014-07-03

    申请号:PCT/US2013/077419

    申请日:2013-12-23

    Abstract: This document describes biochemical pathways for producing pimelic acid, 7-aminoheptanoic acid, 7-hydroxyheptanoic acid, heptamethylenediamine or 1,7-heptanediol by forming two terminal functional groups, comprised of carboxyl, amine or hydroxyl group, in a C7 aliphatic backbone substrate. These pathways, metabolic engineering and cultivation strategies described herein rely on the fatty acid synthesis pathway and oxidative cleavage of long chain acyl-[acp] intermediates by a monooxgenase (e.g., cytochrome P450) such as that encoded by BioI from microorganisms such as Bacillus subtillis .

    Abstract translation: 该文献描述了通过在C7脂肪族主链基质中形成由羧基,胺或羟基组成的两个末端官能团来生产庚二酸,7-氨基庚酸,7-羟基庚酸,七亚甲基二胺或1,7-庚二醇的生化途径。 本文描述的这些途径,代谢工程和培养策略依赖于脂肪酸合成途径以及通过单氧酶(例如细胞色素P450)如长链酰基 - [acp]中间体的氧化裂解,例如由BioI从微生物如枯草芽孢杆菌 。

    COMPOSITION FOR IMPROVED NICKEL-LIGAND SOLUBILITY
    19.
    发明申请
    COMPOSITION FOR IMPROVED NICKEL-LIGAND SOLUBILITY 审中-公开
    用于改善镍基配体溶解性的组合物

    公开(公告)号:WO2014089492A1

    公开(公告)日:2014-06-12

    申请号:PCT/US2013/073688

    申请日:2013-12-06

    Inventor: VOS, Thomas E.

    Abstract: In the hydrocyanation reaction of butadiene proceeding through pentenenitriles to adiponitrile, catalysis by complexes of zerovalent nickel with bidentate phosphorus-based ligands of the NiL 2 A type wherein L 2 is a bidentate ligand and A is an unsaturated compound, can be rate-limited by the solubility of the catalytic complex. The present invention concerns solvent compositions for the nickel-ligand complex comprising mixtures of unsaturated nitriles that provide for increased metal solubility, particularly in the absence of a Lewis acid promoter, resulting in higher hydrocyanation reaction rates in an industrial-scale process for production of important nylon manufacturing intermediates. The mixed nitrile solvent compositions can include mixtures of pentenenitriles and/or methylbutenenitriles. The mixtures of mixed unsaturated nitriles can be, at least in part, from recycle streams from the hydrocyanation reaction for which the nickel-bidentate ligand complexes are used as catalysts.

    Abstract translation: 在通过戊烯腈进行己二腈的丁二烯的氢化反应中,通过与零价镍的络合物与NiL2A型的二齿磷系配体的催化作用,其中L2是二齿配体,A是不饱和化合物,可以通过溶解度 催化复合物。 本发明涉及用于镍 - 配体络合物的溶剂组合物,其包括提供金属溶解度增加的不饱和腈的混合物,特别是在不存在路易斯酸促进剂的情况下,导致在工业规模生产过程中较高的氢氰化反应速率 尼龙制造中间体。 混合的腈溶剂组合物可以包括戊烯腈和/或甲基丁烯腈的混合物。 混合的不饱和腈的混合物可以至少部分地来自使用镍二齿配位体配合物作为催化剂的氢化氰化反应的再循环流。

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