METHODS AND SYSTEMS FOR THE RECOVERY OF WATER FROM A POLYAMIDE SYNTHESIS PROCESS
    32.
    发明申请
    METHODS AND SYSTEMS FOR THE RECOVERY OF WATER FROM A POLYAMIDE SYNTHESIS PROCESS 审中-公开
    从聚酰胺合成过程中回收水的方法和系统

    公开(公告)号:WO2014179029A1

    公开(公告)日:2014-11-06

    申请号:PCT/US2014/034086

    申请日:2014-04-15

    CPC classification number: C08G69/28 B01J19/2415

    Abstract: The present disclosure relates to systems and methods for recovering water from a condensation reaction of at least one carboxylic acid and at least one diamine to make polyamide. The method can include obtaining, from an evaporator, an aqueous mixture comprising a partially polymerized polyamide and at least one of a carboxylic acid and diamine; passing the aqueous mixture through a tubular reactor comprising subjecting the aqueous mixture to a temperature and pressure sufficient to further polymerize the partially polymerized polyamide by condensation of the carboxylic acid and diamine, thereby producing water having a substantially gaseous phase; passing the water having a substantially gaseous phase into a rectification column thereby removing one or more of a diamine, a carboxylic acid and polyamide to provide purified water having a substantially gaseous phase; and condensing the purified water having a substantially gaseous phase into purified water having a substantially liquid phase. The system can include, among other things, a tubular reactor, a rectification column, a condensation assembly, and a conduit network.

    Abstract translation: 本公开涉及从至少一种羧酸和至少一种二胺的缩合反应中回收水以制备聚酰胺的系统和方法。 该方法可以包括从蒸发器获得包含部分聚合的聚酰胺和至少一种羧酸和二胺的含水混合物; 使含水混合物通过管式反应器,包括使含水混合物经受足以通过羧酸和二胺的缩合进一步聚合部分聚合的聚酰胺的温度和压力,从而产生具有基本气相的水; 将具有基本气相的水通入精馏塔中,从而除去二胺,羧酸和聚酰胺中的一种或多种,​​以提供具有基本上气相的净化水; 并将具有基本气相的净化水冷凝成具有基本上液相的纯净水。 该系统可以包括管式反应器,精馏塔,冷凝组件和导管网络。

    METHODS OF PRODUCING 6-CARBON CHEMICALS VIA CoA-DEPENDENT CARBON CHAIN ELONGATION ASSOCIATED WITH CARBON STORAGE
    35.
    发明申请
    METHODS OF PRODUCING 6-CARBON CHEMICALS VIA CoA-DEPENDENT CARBON CHAIN ELONGATION ASSOCIATED WITH CARBON STORAGE 审中-公开
    通过与碳存储相关的依赖于CoA的碳链延长生产6-碳化合物的方法

    公开(公告)号:WO2014093865A3

    公开(公告)日:2014-09-25

    申请号:PCT/US2013075087

    申请日:2013-12-13

    Abstract: This document describes biochemical pathways for producing adipic acid, caprolactam, 6-aminohexanoic acid, 6-hydroxyhexanoic acid, hexamethylenediamine or 1,6-hexanediol by forming two terminal functional groups, comprised of carboxyl, amine or hydroxyl groups, in a C6 aliphatic backbone substrate. These pathways, metabolic engineering and cultivation strategies described herein rely on CoA-dependent elongation enzymes or analogues enzymes associated with the carbon storage pathways from polyhydroxyalkanoate accumulating bacteria.

    Abstract translation: 该文献描述了通过在C 6脂族骨架中形成由羧基,胺或羟基组成的两个末端官能团来生产己二酸,己内酰胺,6-氨基己酸,6-羟基己酸,六亚甲基二胺或1,6-己二醇的生物化学途径 基质。 本文描述的这些途径,代谢工程和培养策略依赖于与来自聚羟基链烷酸酯积累细菌的碳存储途径相关的CoA依赖性延伸酶或类似物酶。

    METHODS OF PRODUCING 7-CARBON CHEMICALS VIA METHYL-ESTER SHIELDED CARBON CHAIN ELONGATION
    36.
    发明申请
    METHODS OF PRODUCING 7-CARBON CHEMICALS VIA METHYL-ESTER SHIELDED CARBON CHAIN ELONGATION 审中-公开
    通过甲基酯保护的碳链延长生产7-碳化合物的方法

    公开(公告)号:WO2014105794A2

    公开(公告)日:2014-07-03

    申请号:PCT/US2013/077420

    申请日:2013-12-23

    Abstract: This document describes biochemical pathways for producing pimelic acid, 7-aminoheptanoic acid, 7-hydroxyheptanoic acid, heptamethylenediamine or 1,7-heptanediol by forming two terminal functional groups, comprised of carboxyl, amine or hydroxyl group, in a C7 aliphatic backbone substrate. These pathways, metabolic engineering and cultivation strategies described herein rely on enzymes or homologs accepting methyl ester shielded dicarboxylic acid substrates.

    Abstract translation: 该文献描述了通过形成由羧基,胺或羟基组成的两个末端官能团来生产庚二酸,7-氨基庚酸,7-羟基庚酸,七亚甲基二胺或1,7-庚二醇的生物化学途径 在C7脂肪族主链底物中。 本文描述的这些途径,代谢工程和培养策略依赖于接受甲酯保护的二羧酸底物的酶或同系物。

    METHODS OF PRODUCING 7-CARBON CHEMICALS FROM LONG CHAIN FATTY ACIDS VIA OXIDATIVE CLEAVAGE
    37.
    发明申请
    METHODS OF PRODUCING 7-CARBON CHEMICALS FROM LONG CHAIN FATTY ACIDS VIA OXIDATIVE CLEAVAGE 审中-公开
    通过氧气消毒从长链脂肪酸生产7碳化合物的方法

    公开(公告)号:WO2014105793A1

    公开(公告)日:2014-07-03

    申请号:PCT/US2013/077419

    申请日:2013-12-23

    Abstract: This document describes biochemical pathways for producing pimelic acid, 7-aminoheptanoic acid, 7-hydroxyheptanoic acid, heptamethylenediamine or 1,7-heptanediol by forming two terminal functional groups, comprised of carboxyl, amine or hydroxyl group, in a C7 aliphatic backbone substrate. These pathways, metabolic engineering and cultivation strategies described herein rely on the fatty acid synthesis pathway and oxidative cleavage of long chain acyl-[acp] intermediates by a monooxgenase (e.g., cytochrome P450) such as that encoded by BioI from microorganisms such as Bacillus subtillis .

    Abstract translation: 该文献描述了通过在C7脂肪族主链基质中形成由羧基,胺或羟基组成的两个末端官能团来生产庚二酸,7-氨基庚酸,7-羟基庚酸,七亚甲基二胺或1,7-庚二醇的生化途径。 本文描述的这些途径,代谢工程和培养策略依赖于脂肪酸合成途径以及通过单氧酶(例如细胞色素P450)如长链酰基 - [acp]中间体的氧化裂解,例如由BioI从微生物如枯草芽孢杆菌 。

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