PROCESS FOR STABILIZING HEAT EXCHANGER TUBES IN ANDRUSSOW PROCESS
    82.
    发明申请
    PROCESS FOR STABILIZING HEAT EXCHANGER TUBES IN ANDRUSSOW PROCESS 审中-公开
    在安捷伦工艺中稳定换热器管的方法

    公开(公告)号:WO2014099601A1

    公开(公告)日:2014-06-26

    申请号:PCT/US2013/074642

    申请日:2013-12-12

    Abstract: The present invention relates to an improved process for producing hydrogen cyanide involving a heat exchanger comprising a plurality of tubes, wherein each of the plurality of tubes comprises a ceramic ferrule extending through the entrance of the tube, each ferrule comprising an insulation layer surrounding at least a portion of the ferrule, and one or more washers, wherein at least one of the one or more washers surrounds the ferrule above the entrance of the tube, wherein the ceramic ferrule is spaced apart from the tube. It further relates to a reaction apparatus for producing hydrogen cyanide involving a heat exchanger comprising a plurality of tubes, wherein each of the plurality of tubes comprises a ceramic ferrule extending through the entrance of the tube, each ferrule comprising an insulation layer surrounding at least a portion of the ferrule, and one or more washers, wherein at least one of the one or more washers surrounds the ferrule above the entrance of the tube, wherein the ceramic ferrule is spaced apart from the tube. It further relates to the heat exchanger for use in this improved process and reaction apparatus.

    Abstract translation: 本发明涉及一种生产氰化氢的改进方法,涉及包括多个管的热交换器,其中多个管中的每一个包括延伸穿过管入口的陶瓷套圈,每个套圈包括至少包围绝缘层 所述套圈的一部分和一个或多个垫圈,其中所述一个或多个垫圈中的至少一个围绕所述管的入口上方的所述套圈,其中所述陶瓷套圈与所述管间隔开。 它还涉及一种用于生产含有多个管的热交换器的氰化氢的反应装置,其中多个管中的每个管包括延伸穿过管的入口的陶瓷套圈,每个套圈包括至少一个 所述套圈的一部分以及一个或多个垫圈,其中所述一个或多个垫圈中的至少一个围绕所述管的入口上方的所述套圈,其中所述陶瓷套圈与所述管间隔开。 它还涉及用于该改进的方法和反应装置的热交换器。

    ENHANCED METHANE CONTROL FOR ANDRUSSOW PROCESS
    83.
    发明申请
    ENHANCED METHANE CONTROL FOR ANDRUSSOW PROCESS 审中-公开
    安捷伦加强甲烷控制

    公开(公告)号:WO2014099568A1

    公开(公告)日:2014-06-26

    申请号:PCT/US2013/074538

    申请日:2013-12-12

    Inventor: CATON, John C.

    CPC classification number: C01C3/0225 C01C3/0216

    Abstract: The present invention relates to a process for producing hydrogen cyanide and more particularly, to a process for producing a crude hydrogen cyanide product comprising from 0.05 to 1 vol.% methane. The present invention also relates to a reactor for producing a crude hydrogen cyanide product having a catalyst bed that is supported by an annular shelf that provides a pass-through area of at least 90% of the area of the cross-sectional area of the reactor and the annular shelf substantially prevents catalyst bed bypass. The present invention also relates to a crude hydrogen cyanide product comprising from 0.05 to 1 vol.% methane.

    Abstract translation: 本发明涉及一种生产氰化氢的方法,更具体地说,涉及一种生产含有0.05至1体积%甲烷的粗制氰化氢产品的方法。 本发明还涉及一种用于生产粗制氰化氢产物的反应器,其具有由环形架支撑的催化剂床,其提供至少90%反应器横截面面积面积的通过面积 并且环形搁架基本上防止催化剂床旁路。 本发明还涉及包含0.05至1体积%甲烷的粗制氰化氢产物。

    YARN PACKAGING AND DELIVERY SYSTEM
    84.
    发明申请
    YARN PACKAGING AND DELIVERY SYSTEM 审中-公开
    纱线包装和送货系统

    公开(公告)号:WO2014028438A1

    公开(公告)日:2014-02-20

    申请号:PCT/US2013/054649

    申请日:2013-08-13

    Abstract: Included are apparatus and methods for preparing a yarn package for a small portion of yarn that provides substantially uniform tension on removal. The method includes providing an amount of yarn up to two pounds which is introduced to a small package with vacuum applied at the bottom of the container and vibration to assist yarn uniform packing of the yarn.

    Abstract translation: 包括用于制备用于小部分纱线的纱线卷装的设备和方法,其在移除时提供基本均匀的张力。 该方法包括提供高达2磅的纱线,其被引入到小包装件中,真空施加在容器的底部并进行振动以辅助纱线的纱线均匀包装。

    ON-LINE CONTROL OF MOLECULAR WEIGHT IN CONTINUOUS SOLID STATE POLYMERIZATION PROCESSES
    85.
    发明申请
    ON-LINE CONTROL OF MOLECULAR WEIGHT IN CONTINUOUS SOLID STATE POLYMERIZATION PROCESSES 审中-公开
    在连续固态聚合过程中分子量的在线控制

    公开(公告)号:WO2013130833A1

    公开(公告)日:2013-09-06

    申请号:PCT/US2013/028357

    申请日:2013-02-28

    CPC classification number: C08G63/80 C08G69/06 C08G69/30

    Abstract: The invention relates to the on-line control of the molecular weight in continuous solid state polymerization processes. In particular it is directed to a polyester process or to a polyamide process, and more specifically to a poly (ethylene terephthalate) (PET) or a poly (butylene terephthalate) (PBT) or a nylon 6,6 continuous solid-state polymerization (SSP) process. An in-line viscometer melts and measures the molecular weight of the SSP resin and adjusts one or more of the process variables, i.e. reactor time, inert gas purity and inert gas temperature to maintain a constant resin molecular weight.

    Abstract translation: 本发明涉及连续固态聚合方法中分子量的在线控制。 特别涉及聚酯工艺或聚酰胺工艺,更具体地涉及聚对苯二甲酸乙二醇酯(PET)或聚对苯二甲酸丁二醇酯(PBT)或尼龙6,6连续固态聚合( SSP)过程。 在线粘度计熔融并测量SSP树脂的分子量,并调节一个或多个工艺参数,即反应器时间,惰性气体纯度和惰性气体温度,以保持树脂分子量恒定。

    ALIPHATIC POLYESTER POLYOLS FROM CYCLOHEXANE OXIDATION BYPRODUCT STREAMS AS PRECURSORS FOR POLYURETHANE AND POLYISOCYANURATE POLYMERS
    86.
    发明申请
    ALIPHATIC POLYESTER POLYOLS FROM CYCLOHEXANE OXIDATION BYPRODUCT STREAMS AS PRECURSORS FOR POLYURETHANE AND POLYISOCYANURATE POLYMERS 审中-公开
    作为聚氨酯和聚异氰酸酯聚合物前驱体的产品流程的环氧化合物氧化的聚氨酯聚合物

    公开(公告)号:WO2012173938A1

    公开(公告)日:2012-12-20

    申请号:PCT/US2012/041951

    申请日:2012-06-11

    Abstract: The invention provides polyester polyol compositions, useful as components of polyurethane and polyisocyanurate polymers, prduced from cyclohexane oxidation reaction byproducts, such as water extracts and non-volatile distillation residues from the reaction. Such byproducts of industrial processes for preparation of adipic acid and caprolactam, important intermediates in the production of various types of nylon, have hitherto largely been used only as fuels. The present invention provides value-added products, methods for making, and methods for using the byproduct-derived polyester polyol compositions. For example, the invention provides polyurethane (PU) and/or polyisocyanurate (PIR) polymers made using the polyol compositions and polyfunctional isocyanates. The PU and PIR polymers can be used as adhesives, binders (e.g., for wood fibers), coatings (e.g., for controlled release fertilizers), and foams.

    Abstract translation: 本发明提供了聚酯多元醇组合物,其可用作聚氨酯和聚异氰脲酸酯聚合物的组分,其由环己烷氧化反应副产物如水提取物和来自反应的非挥发性蒸馏残余物生成。 用于制备己二酸和己内酰胺的工业方法的这种副产物,各种类型的尼龙的生产中的重要中间体迄今为止主要仅用作燃料。 本发明提供增值产品,制备方法和使用副产物衍生的聚酯多元醇组合物的方法。 例如,本发明提供使用多元醇组合物和多官能异氰酸酯制备的聚氨酯(PU)和/或聚异氰脲酸酯(PIR)聚合物。 PU和PIR聚合物可用作粘合剂,粘合剂(例如木纤维),涂层(例如用于控释肥料)和泡沫。

    PROCESSES TO MAKE WATER AND OIL REPELLENT BCF YARN
    87.
    发明申请
    PROCESSES TO MAKE WATER AND OIL REPELLENT BCF YARN 审中-公开
    生产防水防油BCF纱线的工艺

    公开(公告)号:WO2012125777A2

    公开(公告)日:2012-09-20

    申请号:PCT/US2012/029151

    申请日:2012-03-15

    Abstract: Disclosed are processes for applying anti-soil compositions onto BCF yarns during cable or air twisting processes prior to weaving, knitting or tufting into finished carpet. The process foregoes the need for downstream environmentally unfavorable dyeing and low pH chemical treatment processes on the finished carpet. The anti-soil composition can be comprised of a high specific surface energy chemical or other material, for example a fluorochemical. Further, the anti-soil composition can further comprise an anti-stain component. Also disclosed are systems, BCF yarns, and carpets made from the BCF yarn treated by the disclosed process.

    Abstract translation: 公开了在编织,编织或簇绒成最终地毯之前,在电缆或空气加捻过程中将防污组合物施加到BCF纱线上的方法。 该工艺不需要在成品地毯上进行下游环境不利染色和低pH化学处理工艺。 防污组合物可以包含高比表面能化学品或其他材料,例如含氟化合物。 此外,防污组合物可以进一步包含防污组分。 还公开了系统,BCF纱线和由通过所公开的方法处理的BCF纱线制成的地毯。

    PROCESS FOR MAKING NITRILES
    88.
    发明申请
    PROCESS FOR MAKING NITRILES 审中-公开
    制造NITRILES的工艺

    公开(公告)号:WO2012005918A1

    公开(公告)日:2012-01-12

    申请号:PCT/US2011/040676

    申请日:2011-06-16

    CPC classification number: C07C253/10 Y02P20/584 C07C255/04

    Abstract: A hydrocyanation reaction is used to react 1,3-butadiene with hydrogen cyanide in the presence of a catalyst to produce pentenenitrles, as well as reaction byproducts, such as methylglutaronitrile (MGN). The effluent from the hydrocyanation reaction is distilled in a particular manner to produce a pentenenitrile-enriched stream, a catalyst- enriched stream and a stream enriched in methylglutaronitrile (MGN). At least a portion of the catalyst enriched stream may be recycled to the hydrocyanation reaction, 3- pentenenitrile may be recovered and, optionally, further reacted with HCN to make adiponitrile (ADN).

    Abstract translation: 使用氢氰化反应在催化剂存在下使1,3-丁二烯与氰化氢反应以产生戊烯腈,以及反应副产物如甲基戊二腈(MGN)。 来自氢氰化反应的流出物以特定的方式蒸馏以产生富腈过程,富含催化剂的料流和富含甲基戊二腈(MGN)的料流。 可以将至少一部分富含催化剂的物流再循环到氢化氰化反应中,可以回收3-戊腈,并任选地进一步与HCN反应以制备己二腈(ADN)。

    INTEGRATED COPOLYETHER GLYCOL MANUFACTURING PROCESS
    90.
    发明申请
    INTEGRATED COPOLYETHER GLYCOL MANUFACTURING PROCESS 审中-公开
    一体化聚乙二醇制造工艺

    公开(公告)号:WO2011075177A1

    公开(公告)日:2011-06-23

    申请号:PCT/US2010/020699

    申请日:2010-01-12

    Abstract: The present invention relates to an improved, fully-integrated continuous process of enhanced process operability for manufacturing copolyether glycols having enhanced physical properties by polymerization of a reaction mixture comprising tetrahydrofuran and at least one alkylene oxide in the presence of an acid catalyst and at least one compound containing reactive hydrogen atoms. The copolyether glycols manufactured by the present process have enhanced physical properties of increased alkylene oxide incorporation, average molecular weight and polydispersity, as well as reduced crystallinity, color, oligomeric cyclic ether content, and linear oligomer having an average molecular weight of up to about 400 dalton content.

    Abstract translation: 本发明涉及一种改进的,完全一体化的连续方法,其增强了制备具有增强的物理性能的共聚醚二醇的工艺可操作性,所述共聚醚二醇在酸催化剂存在下通过聚合包含四氢呋喃和至少一种烯化氧的反应混合物和至少一种 含有活性氢原子的化合物。 通过本方法制备的共聚醚二醇具有增加的烯化氧掺入,平均分子量和多分散性以及降低的结晶度,颜色,低聚环醚含量和平均分子量高达约400的线性低聚物的物理性能 达尔顿内容

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